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Vol. 13 (2021)

Non-Magnetic Bimetallic MOF-Derived Porous Carbon-Wrapped TiO2/ZrTiO4 Composites for Efficient Electromagnetic Wave Absorption

https://doi.org/10.1007/s40820-021-00606-6
Jing Qiao
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Xue Zhang
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Chang Liu
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Longfei Lyu
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Yunfei Yang
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Zhou Wang
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Lili Wu
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Wei Liu
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, People’s Republic of China
Fenglong Wang
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Jiurong Liu
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China

Corresponding Author: Jiurong Liu

jrliu@sdu.edu.cn

Nano-Micro Letters, Vol. 13 (2021), Article Number: 75

Abstract

Modern communication technologies put forward higher requirements for electromagnetic wave (EMW) absorption materials. Metal–organic framework (MOF) derivatives have been widely concerned with its diverse advantages. To break the mindset of magnetic-derivative design, and make up the shortage of monometallic non-magnetic derivatives, we first try non-magnetic bimetallic MOFs derivatives to achieve efficient EMW absorption. The porous carbon-wrapped TiO2/ZrTiO4 composites derived from PCN-415 (TiZr-MOFs) are qualified with a minimum reflection loss of − 67.8 dB (2.16 mm, 13.0 GHz), and a maximum effective absorption bandwidth of 5.9 GHz (2.70 mm). Through in-depth discussions, the synergy of enhanced interfacial polarization and other attenuation mechanisms in the composites is revealed. Therefore, this work confirms the huge potentials of non-magnetic bimetallic MOFs derivatives in EMW absorption applications.


Highlights:


1 Non-magnetic bimetallic MOF-derived porous carbon-wrapped TiO2/ZrTiO4 composites are firstly used for efficient electromagnetic wave absorption.
2 The electromagnetic wave absorption mechanisms including enhanced interfacial polarization and essential conductivity are intensively discussed.

Keywords

Bimetallic metal–organic framework PCN-415 MOF derivatives TiO2/ZrTiO4/C composites Electromagnetic wave absorption
Qiao, Jing, Xue Zhang, Chang Liu, Longfei Lyu, Yunfei Yang, Zhou Wang, Lili Wu, Wei Liu, Fenglong Wang, and Jiurong Liu. 2021. “Non-Magnetic Bimetallic MOF-Derived Porous Carbon-Wrapped TiO2/ZrTiO4 Composites for Efficient Electromagnetic Wave Absorption”. Nano-Micro Letters 13 (February):75. https://doi.org/10.1007/s40820-021-00606-6.
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