Issue

Vol. 13 (2021)

Non-Magnetic Bimetallic MOF-Derived Porous Carbon-Wrapped TiO2/ZrTiO4 Composites for Efficient Electromagnetic Wave Absorption

https://doi.org/10.1007/s40820-021-00606-6
Jing Qiao
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Xue Zhang
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Chang Liu
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Longfei Lyu
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Yunfei Yang
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Zhou Wang
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Lili Wu
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Wei Liu
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, People’s Republic of China
Fenglong Wang
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China
Jiurong Liu
School of Materials Science and Engineering, Shandong University, Jinan 250061, People’s Republic of China

Corresponding Author: Jiurong Liu

jrliu@sdu.edu.cn

Nano-Micro Letters, Vol. 13 (2021), Article Number: 75

Abstract

Modern communication technologies put forward higher requirements for electromagnetic wave (EMW) absorption materials. Metal–organic framework (MOF) derivatives have been widely concerned with its diverse advantages. To break the mindset of magnetic-derivative design, and make up the shortage of monometallic non-magnetic derivatives, we first try non-magnetic bimetallic MOFs derivatives to achieve efficient EMW absorption. The porous carbon-wrapped TiO2/ZrTiO4 composites derived from PCN-415 (TiZr-MOFs) are qualified with a minimum reflection loss of − 67.8 dB (2.16 mm, 13.0 GHz), and a maximum effective absorption bandwidth of 5.9 GHz (2.70 mm). Through in-depth discussions, the synergy of enhanced interfacial polarization and other attenuation mechanisms in the composites is revealed. Therefore, this work confirms the huge potentials of non-magnetic bimetallic MOFs derivatives in EMW absorption applications.


Highlights:


1 Non-magnetic bimetallic MOF-derived porous carbon-wrapped TiO2/ZrTiO4 composites are firstly used for efficient electromagnetic wave absorption.
2 The electromagnetic wave absorption mechanisms including enhanced interfacial polarization and essential conductivity are intensively discussed.

Keywords

Bimetallic metal–organic framework PCN-415 MOF derivatives TiO2/ZrTiO4/C composites Electromagnetic wave absorption
Qiao, Jing, Xue Zhang, Chang Liu, Longfei Lyu, Yunfei Yang, Zhou Wang, Lili Wu, Wei Liu, Fenglong Wang, and Jiurong Liu. 2021. “Non-Magnetic Bimetallic MOF-Derived Porous Carbon-Wrapped TiO2/ZrTiO4 Composites for Efficient Electromagnetic Wave Absorption”. Nano-Micro Letters 13 (February):75. https://doi.org/10.1007/s40820-021-00606-6.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. H. Chen, W. Ma, Z. Huang, Y. Zhang, Y. Huang et al., Graphene-based materials toward microwave and terahertz absorbing stealth technologies. Adv. Opt. Mater. 7, 1801318 (2019). https://doi.org/10.1002/adom.201801318
  2. Q. Li, Z. Zhang, L. Qi, Q. Liao, Z. Kang et al., Toward the application of high frequency electromagnetic wave absorption by carbon nanostructures. Adv. Sci. 6, 1801057 (2019). https://doi.org/10.1002/advs.201801057
  3. Y. Li, X. Liu, X. Nie, W. Yang, Y. Wang et al., Multifunctional organic-inorganic hybrid aerogel for self-cleaning, heat-insulating, and highly efficient microwave absorbing material. Adv. Funct. Mater. 29, 1807624 (2019). https://doi.org/10.1002/adfm.201807624
  4. Y. Zhang, Y. Huang, T. Zhang, H. Chang, P. Xiao et al., Broadband and tunable high-performance microwave absorption of an ultralight and highly compressible graphene foam. Adv. Mater. 27, 2049–2053 (2015). https://doi.org/10.1002/adma.201405788
  5. W.T. Koo, S. Yu, S.J. Choi, J.S. Jang, J.Y. Cheong et al., Nanoscale PdO catalyst functionalized Co3O4 hollow nanocages using MOF templates for selective detection of acetone molecules in exhaled breath. ACS Appl. Mater. Interfaces 9, 8201–8210 (2017). https://doi.org/10.1021/acsami.7b01284
  6. Q. Liao, M. He, Y. Zhou, S. Nie, Y. Wang et al., Highly cuboid-shaped heterobimetallic metal-organic frameworks derived from porous Co/Zno/C microrods with improved electromagnetic wave absorption capabilities. ACS Appl. Mater. Interfaces 10, 29136–29144 (2018). https://doi.org/10.1021/acsami.8b09093
  7. S. Dang, Q.-L. Zhu, Q. Xu, Nanomaterials derived from metal-organic frameworks. Nat. Rev. Mater. 3, 17075 (2017). https://doi.org/10.1038/natrevmats.2017.75
  8. K. Wang, Y. Chen, R. Tian, H. Li, Y. Zhou et al., Porous Co-C core-shell nanocomposites derived from Co-MOF-74 with enhanced electromagnetic wave absorption performance. ACS Appl. Mater. Interfaces 10, 11333–11342 (2018). https://doi.org/10.1021/acsami.8b00965
  9. N. Wu, D. Xu, Z. Wang, F. Wang, J. Liu et al., Achieving superior electromagnetic wave absorbers through the novel metal-organic frameworks derived magnetic porous carbon nanorods. Carbon 145, 433–444 (2019). https://doi.org/10.1016/j.carbon.2019.01.028
  10. N. Wu, H. Lv, J. Liu, Y. Liu, S. Wang et al., Improved electromagnetic wave absorption of Co nanoparticles decorated carbon nanotubes derived from synergistic magnetic and dielectric losses. Phys. Chem. Chem. Phys. 18, 31542–31550 (2016). https://doi.org/10.1039/c6cp06066h
  11. X. Li, J. Feng, Y. Du, J. Bai, H. Fan et al., One-pot synthesis of CoFe2O4/graphene oxide hybrids and their conversion into FeCo/graphene hybrids for lightweight and highly efficient microwave absorber. J. Mater. Chem. A 3, 5535–5546 (2015). https://doi.org/10.1039/c4ta05718j
  12. L. Liu, N. He, T. Wu, P. Hu, G. Tong, Co/C/Fe/F hierarchical flowers with strawberry-like surface as surface plasmon for enhanced permittivity, permeability, and microwave absorption properties. Chem. Eng. J. 355, 103–108 (2019). https://doi.org/10.1016/j.cej.2018.08.131
  13. B. Zhao, Y. Li, Q. Zeng, L. Wang, J. Ding et al., Galvanic replacement reaction involving core-shell magnetic chains and orientation-tunable microwave absorption properties. Small 16, 2003502 (2020). https://doi.org/10.1002/smll.202003502
  14. Q. Liu, Q. Cao, H. Bi, C. Liang, K. Yuan et al., CoNi@SiO2@TiO2 and CoNi@air@TiO2 microspheres with strong wideband microwave absorption. Adv. Mater. 28, 486–490 (2016). https://doi.org/10.1002/adma.201503149
  15. Q. Wu, H. Jin, W. Chen, S. Huo, X. Chen et al., Graphitized nitrogen-doped porous carbon composites derived from ZIF-8 as efficient microwave absorption materials. Mater. Res. Express 5, 065602 (2018). https://doi.org/10.1088/2053-1591/aac67e
  16. X. Zhang, J. Qiao, C. Liu, F. Wang, Y. Jiang et al., A MOF-derived ZrO2/C nanocomposite for efficient electromagnetic wave absorption. Inorg. Chem. Front. 7, 385–393 (2020). https://doi.org/10.1039/c9qi01259a
  17. J. Qiao, X. Zhang, D. Xu, L. Kong, L. Lv et al., Design and synthesis of TiO2/Co/carbon nanofibers with tunable and efficient electromagnetic absorption. Chem. Eng. J. 380, 122591 (2020). https://doi.org/10.1016/j.cej.2019.122591
  18. N. Zhang, Y. Huang, M. Wang, Synthesis of graphene/thorns-like polyaniline/alpha-Fe2O3@SiO2 nanocomposites for lightweight and highly efficient electromagnetic wave absorber. J. Colloid Interface Sci. 530, 212–222 (2018). https://doi.org/10.1016/j.jcis.2018.06.088
  19. S. Yuan, J.S. Qin, H.Q. Xu, J. Su, D. Rossi et al., [Ti8Zr2O12(COO)16] cluster: an ideal inorganic building unit for photoactive metal-organic frameworks. ACS Cent. Sci. 4, 105–111 (2018). https://doi.org/10.1021/acscentsci.7b00497
  20. O. Secundino-Sánchez, J. Diaz-Reyes, J. Aguila-López, J.F. Sánchez-Ramírez, Crystalline phase transformation of electrospinning TiO2 nanofibres carried out by high temperature annealing. J. Mol. Struct. 1194, 163–170 (2019). https://doi.org/10.1016/j.molstruc.2019.05.092
  21. J. Qiao, X. Zhang, C. Liu, L. Lyu, Z. Wang et al., Facile fabrication of Ni embedded TiO2/C core-shell ternary nanofibers with multicomponent functional synergy for efficient electromagnetic wave absorption. Compos. B: Eng. (2020). https://doi.org/10.1016/j.compositesb.2020.108343
  22. A.C. Ferrari, S.E. Rodil, J. Robertson, Interpretation of Raman spectra of disordered and amorphous carbon. Phys. Rev. B 61, 14095–14107 (2000). https://doi.org/10.1103/PhysRevB.67.155306
  23. F. Tuinstra, J.L. Koenig, Raman spectrum of graphite. J. Chem. Phys. 53, 1126–1130 (1970). https://doi.org/10.1063/1.1674108
  24. R.J. Nemanich, S.A. Solin, First- and second-order Raman scattering from finite-size crystals of graphite. Phys. Rev. B 20, 392–401 (1979). https://doi.org/10.1103/PhysRevB.20.392
  25. X. Xu, F. Ran, Z. Fan, Z. Cheng, T. Lv et al., Bimetallic metal-organic framework-derived pomegranate-like nanoclusters coupled with CoNi-doped graphene for strong wideband microwave absorption. ACS Appl. Mater. Interfaces 12, 17882–17892 (2020). https://doi.org/10.1021/acsami.0c01572
  26. H. Xu, X. Yin, M. Li, F. Ye, M. Han et al., Mesoporous carbon hollow microspheres with red blood cell like morphology for efficient microwave absorption at elevated temperature. Carbon 132, 343–351 (2018). https://doi.org/10.1016/j.carbon.2018.02.040
  27. X. Zhang, J. Qiao, F. Wang, L. Lv, D. Xu et al., Tailoring electromagnetic absorption performances of TiO2/Co/carbon nanofibers through tuning graphitization degrees. Ceram. Int. 46, 4754–4761 (2020). https://doi.org/10.1016/j.ceramint.2019.10.207
  28. B. Zhao, X. Guo, W. Zhao, J. Deng, B. Fan et al., Facile synthesis of yolk–shell Ni@void@SnO2(Ni3Sn2) ternary composites via galvanic replacement/Kirkendall effect and their enhanced microwave absorption properties. Nano Res. 10, 331–343 (2017). https://doi.org/10.1007/s12274-016-1295-3
  29. T.Y. Hiroyuki Ikawa, K. Kojima, S. Matsumoto, X-ray photoelectron spectroscopy study of high- and low-temperature forms of zirconium titanate. J. Am. Ceram. Soc. (1991). https://doi.org/10.1111/j.1151-2916.1991.tb04131.x
  30. Y. Yin, X. Liu, X. Wei, R. Yu, J. Shui, Porous CNTs/Co composite derived from zeolitic imidazolate framework: a lightweight, ultrathin, and highly efficient electromagnetic wave absorber. ACS Appl. Mater. Interfaces 8, 34686–34698 (2016). https://doi.org/10.1021/acsami.6b12178
  31. F. Ran, X. Xu, D. Pan, Y. Liu, Y. Bai et al., Ultrathin 2D metal–organic framework nanosheets in situ interpenetrated by functional CNTs for hybrid energy storage device. Nano-Micro Lett. 12, 46 (2020). https://doi.org/10.1007/s40820-020-0382-x
  32. M. Chi, X. Sun, A. Sujan, Z. Davis, B.J. Tatarchuk, A quantitative XPS examination of UV induced surface modification of TiO2 sorbents for the increased saturation capacity of sulfur heterocycles. Fuel 238, 454–461 (2019). https://doi.org/10.1016/j.fuel.2018.10.114
  33. F. Ran, T. Wang, S. Chen, Y. Liu, L. Shao, Constructing expanded ion transport channels in flexible MXene film for pseudocapacitive energy storage. Appl. Surface Sci. 511, 145627 (2020). https://doi.org/10.1016/j.apsusc.2020.145627
  34. L. Wang, M. Huang, X. Yu, W. You, J. Zhang et al., MOF-derived Ni1−xCox@carbon with tunable nano-microstructure as lightweight and highly efficient electromagnetic wave absorber. Nano-Micro Lett. 12, 150 (2020). https://doi.org/10.1007/s40820-020-00488-0
  35. D. Zhang, T. Liu, J. Cheng, Q. Cao, G. Zheng et al., Lightweight and high-performance microwave absorber based on 2D WS2-RGO heterostructures. Nano-Micro Lett. 11, 38 (2019). https://doi.org/10.1007/s40820-019-0270-4
  36. J. Ma, W. Liu, X. Liang, B. Quan, Y. Cheng et al., Nanoporous TiO2/C composites synthesized from directly pyrolysis of a ti-based MOFs MIL-125(Ti) for efficient microwave absorption. J. Alloys Compd. 728, 138–144 (2017). https://doi.org/10.1016/j.jallcom.2017.08.274
  37. J. Wang, L. Liu, S. Jiao, K. Ma, J. Lv et al., Hierarchical carbon fiber@MXene@MoS2 core-sheath synergistic microstructure for tunable and efficient microwave absorption. Adv. Funct. Mater. (2020). https://doi.org/10.1002/adfm.202002595
  38. K. Sun, J. Dong, Z. Wang, Z. Wang, G. Fan et al., Tunable negative permittivity in flexible graphene/PDMS metacomposites. J. Phys. Chem. C 123(38), 23635–23642 (2019). https://doi.org/10.1021/acs.jpcc.9b06753
  39. M. Ning, B. Kuang, Z. Hou, L. Wang, J. Li et al., Layer by layer 2D MoS2/rGO hybrids: an optimized microwave absorber for high-efficient microwave absorption. Appl. Surface Sci. 470, 899–907 (2019). https://doi.org/10.1016/j.apsusc.2018.11.195
  40. J. Liu, W.-Q. Cao, H.-B. Jin, J. Yuan, D.-Q. Zhang et al., Enhanced permittivity and multi-region microwave absorption of nanoneedle-like ZnO in the X-band at elevated temperature. J. Mater. Chem. C 3, 4670–4677 (2015). https://doi.org/10.1039/c5tc00426h
  41. M.-S. Cao, W.-L. Song, Z.-L. Hou, B. Wen, J. Yuan, The effects of temperature and frequency on the dielectric properties, electromagnetic interference shielding and microwave-absorption of short carbon fiber/silica composites. Carbon 48, 788–796 (2010). https://doi.org/10.1016/j.carbon.2009.10.028
  42. W. Liu, S. Tan, Z. Yang, G. Ji, Hollow graphite spheres embedded in porous amorphous carbon matrices as lightweight and low-frequency microwave absorbing material through modulating dielectric loss. Carbon 138, 143–153 (2018). https://doi.org/10.1016/j.carbon.2018.06.009
  43. W. Liu, L. Liu, G. Ji, D. Li, Y. Zhang et al., Composition design and structural characterization of MOF-derived composites with controllable electromagnetic properties. ACS Sustain. Chem. Eng. 5, 7961–7971 (2017). https://doi.org/10.1021/acssuschemeng.7b01514
  44. Z. Wu, K. Tian, T. Huang, W. Hu, F. Xie et al., Hierarchically porous carbons derived from biomasses with excellent microwave absorption performance. ACS Appl. Mater. Interfaces 10, 11108–11115 (2018). https://doi.org/10.1021/acsami.7b17264
  45. J. Xiang, J. Li, X. Zhang, Q. Ye, J. Xu et al., Magnetic carbon nanofibers containing uniformly dispersed Fe/Co/Ni nanoparticles as stable and high-performance electromagnetic wave absorbers. J. Mater. Chem. A 2, 16905–16914 (2014). https://doi.org/10.1039/c4ta03732d
  46. R. Shu, W. Li, Y. Wu, J. Zhang, G. Zhang, Nitrogen-doped Co-C/MWCNTs nanocomposites derived from bimetallic metal-organic frameworks for electromagnetic wave absorption in the x-band. Chem. Eng. J. 362, 513–524 (2019). https://doi.org/10.1016/j.cej.2019.01.090
  47. K. Ren, Y. Wang, C. Ye, Z. Du, J. Bian et al., Realizing significant dielectric dispersion of composites based on highly conducting silver-coated glass microspheres for wide-band non-magnetic microwave absorbers. J. Mater. Chem. C 7, 528–542 (2019). https://doi.org/10.1039/c8tc03594f
  48. Z. Ma, C.-T. Cao, Q.-F. Liu, J.-B. Wang, A new method to calculate the degree of electromagnetic impedance matching in one-layer microwave absorbers. Chinese Phys. Lett. 29, 038401 (2012). https://doi.org/10.1088/0256-307x/29/3/038401
Read More
Author biographies are not available.
Download this PDF file
PDF SUPPLEMENTARY MATERIAL
Statistic
Read Counter : 9565 Download : 7186

Most read articles by the same author(s)

1 2 > >>