Issue

Vol. 11 (2019)

All Binder-Free Electrodes for High-Performance Wearable Aqueous Rechargeable Sodium-Ion Batteries

https://doi.org/10.1007/s40820-019-0332-7
Bing He
Division of Advanced Nanomaterials, Key Laboratory of Nanodevices and Applications, Joint Key Laboratory of Functional Nanomaterials and Devices, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano‑Tech and Nano‑Bionics, Chinese Academy of Sciences, Suzhou 215123, People’s Republic of China
Ping Man
Division of Advanced Nanomaterials, Key Laboratory of Nanodevices and Applications, Joint Key Laboratory of Functional Nanomaterials and Devices, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano‑Tech and Nano‑Bionics, Chinese Academy of Sciences, Suzhou 215123, People’s Republic of China
Qichong Zhang
School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Avenue, Jurong West 639798, Singapore
Huili Fu
Division of Advanced Nanomaterials, Key Laboratory of Nanodevices and Applications, Joint Key Laboratory of Functional Nanomaterials and Devices, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano‑Tech and Nano‑Bionics, Chinese Academy of Sciences, Suzhou 215123, People’s Republic of China
Zhenyu Zhou
Division of Advanced Nanomaterials, Key Laboratory of Nanodevices and Applications, Joint Key Laboratory of Functional Nanomaterials and Devices, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano‑Tech and Nano‑Bionics, Chinese Academy of Sciences, Suzhou 215123, People’s Republic of China
Chaowei Li
Division of Advanced Nanomaterials, Key Laboratory of Nanodevices and Applications, Joint Key Laboratory of Functional Nanomaterials and Devices, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano‑Tech and Nano‑Bionics, Chinese Academy of Sciences, Suzhou 215123, People’s Republic of China
Qiulong Li
Division of Advanced Nanomaterials, Key Laboratory of Nanodevices and Applications, Joint Key Laboratory of Functional Nanomaterials and Devices, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano‑Tech and Nano‑Bionics, Chinese Academy of Sciences, Suzhou 215123, People’s Republic of China
Lei Wei
School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Avenue, Jurong West 639798, Singapore
Yagang Yao
Division of Advanced Nanomaterials, Key Laboratory of Nanodevices and Applications, Joint Key Laboratory of Functional Nanomaterials and Devices, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano‑Tech and Nano‑Bionics, Chinese Academy of Sciences, Suzhou 215123, People’s Republic of China

Corresponding Author: Yagang Yao

ygyao2018@nju.edu.cn

Nano-Micro Letters, Vol. 11 (2019), Article Number: 101

Abstract

Extensive efforts have recently been devoted to the construction of aqueous rechargeable sodium-ion batteries (ARSIBs) for large-scale energy-storage applications due to their desired properties of abundant sodium resources and inherently safer aqueous electrolytes. However, it is still a significant challenge to develop highly flexible ARSIBs ascribing to the lack of flexible electrode materials. In this work, nanocube-like KNiFe(CN)6 (KNHCF) and rugby ball-like NaTi2(PO4)3 (NTP) are grown on carbon nanotube fibers via simple and mild methods as the flexible binder-free cathode (KNHCF@CNTF) and anode (NTP@CNTF), respectively. Taking advantage of their high conductivity, fast charge transport paths, and large accessible surface area, the as-fabricated binder-free electrodes display admirable electrochemical performance. Inspired by the remarkable flexibility of the binder-free electrodes and the synergy of KNHCF@CNTF and NTP@CNTF, a high-performance quasi-solid-state fiber-shaped ARSIB (FARSIB) is successfully assembled for the first time. Significantly, the as-assembled FARSIB possesses a high capacity of 34.21 mAh cm−3 and impressive energy density of 39.32 mWh cm−3. More encouragingly, our FARSIB delivers superior mechanical flexibility with only 5.7% of initial capacity loss after bending at 90° for over 3000 cycles. Thus, this work opens up an avenue to design ultraflexible ARSIBs based on all binder-free electrodes for powering wearable and portable electronics.


Highlights:


1 Nanocube-like KNiFe(CN)6 and rugby ball-like NaTi2(PO4)3 are grown on carbon nanotube fibers via simple and mild methods.
2 A quasi-solid-state fiber-shaped aqueous rechargeable sodium-ion battery based on all binder-free electrodes is successfully assembled for the first time, delivering a high volumetric capacity of 34.21 mAh cm−3 and impressive volumetric energy density of 39.32 mWh cm−3.
3 The device delivers superior mechanical flexibility with only 5.7% of initial capacity loss after bending at 90° for over 3000 cycles.

Keywords

Carbon nanotube fiber Binder-free electrode Flexibility Aqueous rechargeable energy-storage device Sodium-ion battery
He, Bing, Ping Man, Qichong Zhang, Huili Fu, Zhenyu Zhou, Chaowei Li, Qiulong Li, Lei Wei, and Yagang Yao. 2019. “All Binder-Free Electrodes for High-Performance Wearable Aqueous Rechargeable Sodium-Ion Batteries”. Nano-Micro Letters 11 (November):101. https://doi.org/10.1007/s40820-019-0332-7.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. F. Mo, G. Liang, Q. Meng, Z. Liu, H. Li, J. Fan, C. Zhi, A flexible rechargeable aqueous zinc manganese-dioxide battery working at − 20°C. Energy Environ. Sci. 12(2), 706–715 (2019). https://doi.org/10.1039/C8EE02892C
  2. H. Li, C. Han, Y. Huang, Y. Huang, M. Zhu et al., An extremely safe and wearable solid-state zinc ion battery based on a hierarchical structured polymer electrolyte. Energy Environ. Sci. 11(4), 941–951 (2018). https://doi.org/10.1039/C7EE03232C
  3. Q. Xue, J. Sun, Y. Huang, M. Zhu, Z. Pei et al., Recent progress on flexible and wearable supercapacitors. Small 13(45), 1701827 (2017). https://doi.org/10.1002/smll.201701827
  4. C. Yang, X. Ji, X. Fan, T. Gao, L. Suo et al., Flexible aqueous Li-ion battery with high energy and power densities. Adv. Mater. 29(44), 1701972 (2017). https://doi.org/10.1002/adma.201701972
  5. Z. Guo, Y. Zhao, Y. Ding, X. Dong, L. Chen et al., Multi-functional flexible aqueous sodium-ion batteries with high safety. Chem 3(2), 348–362 (2017). https://doi.org/10.1016/j.chempr.2017.05.004
  6. Y. Zhang, Y. Jiao, L. Lu, L. Wang, T. Chen, H. Peng, An ultraflexible silicon–oxygen battery fiber with high energy density. Angew. Chem. Int. Ed. 56(44), 13741–13746 (2017). https://doi.org/10.1002/anie.201707840
  7. Q. Zhang, W. Xu, J. Sun, Z. Pan, J. Zhao et al., Constructing ultrahigh-capacity zinc–nickel–cobalt oxide@Ni(OH)2 core–shell nanowire arrays for high-performance coaxial fiber-shaped asymmetric supercapacitors. Nano Lett. 17(12), 7552–7560 (2017). https://doi.org/10.1021/acs.nanolett.7b03507
  8. Q. Zhang, C. Li, Q. Li, Z. Pan, J. Sun et al., Flexible and high-voltage coaxial-fiber aqueous rechargeable zinc-ion battery. Nano Lett. 19(6), 4035–4042 (2019). https://doi.org/10.1021/acs.nanolett.9b01403
  9. Q. Zhang, X. Wang, Z. Pan, J. Sun, J. Zhao et al., Wrapping aligned carbon nanotube composite sheets around vanadium nitride nanowire arrays for asymmetric coaxial fiber-shaped supercapacitors with ultrahigh energy density. Nano Lett. 17(4), 2719–2726 (2017). https://doi.org/10.1021/acs.nanolett.7b00854
  10. Q. Zhang, L. Li, H. Li, L. Tang, B. He et al., Ultra-endurance coaxial-fiber stretchable sensing systems fully powered by sunlight. Nano Energy 60, 267–274 (2019). https://doi.org/10.1016/j.nanoen.2019.03.049
  11. Y. Zeng, Y. Meng, Z. Lai, X. Zhang, M. Yu, P. Fang, M. Wu, Y. Tong, X. Lu, An ultrastable and high-performance flexible fiber-shaped Ni–Zn battery based on a Ni–NiO heterostructured nanosheet cathode. Adv. Mater. 29(44), 1702698 (2017). https://doi.org/10.1002/adma.201702698
  12. M. Yao, R. Wang, Z. Zhao, Y. Liu, Z. Niu, J. Chen, A flexible all-in-one lithium-sulfur battery. ACS Nano 12(12), 12503–12511 (2018). https://doi.org/10.1021/acsnano.8b06936
  13. M. Li, J. Meng, Q. Li, M. Huang, X. Liu, K.A. Owusu, Z. Liu, L. Mai, Finely crafted 3D electrodes for dendrite-free and high-performance flexible fiber-shaped Zn–Co batteries. Adv. Funct. Mater. 28(32), 1802016 (2018). https://doi.org/10.1002/adfm.201802016
  14. Y.-H. Zhu, X. Yang, D. Bao, X.-F. Bie, T. Sun et al., High-energy-density flexible potassium-ion battery based on patterned electrodes. Joule 2(4), 736–746 (2018). https://doi.org/10.1016/j.joule.2018.01.010
  15. Y. Shao, J. Li, Y. Li, H. Wang, Q. Zhang, R.B. Kaner, Flexible quasi-solid-state planar micro-supercapacitor based on cellular graphene films. Mater. Horiz. 4(6), 1145–1150 (2017). https://doi.org/10.1039/C7MH00441A
  16. J. Xu, J. Chen, S. Zhou, C. Han, M. Xu, N. Zhao, C.-P. Wong, Sequentially-processed Na3V2(PO4)3 for cathode material of aprotic sodium ion battery. Nano Energy 50, 323–330 (2018). https://doi.org/10.1016/j.nanoen.2018.05.015
  17. X. Xiang, K. Zhang, J. Chen, Recent advances and prospects of cathode materials for sodium-ion batteries. Adv. Mater. 27(36), 5343–5364 (2015). https://doi.org/10.1002/adma.201501527
  18. M. Lao, Y. Zhang, W. Luo, Q. Yan, W. Sun, S.X. Dou, Alloy-based anode materials toward advanced sodium-ion batteries. Adv. Mater. 29(48), 1700622 (2017). https://doi.org/10.1002/adma.201700622
  19. H. Xia, X. Zhu, J. Liu, Q. Liu, S. Lan et al., A monoclinic polymorph of sodium birnessite for ultrafast and ultrastable sodium ion storage. Nat. Commun. 9(1), 5100 (2018). https://doi.org/10.1038/s41467-018-07595-y
  20. H.-G. Wang, W. Li, D.-P. Liu, X.-L. Feng, J. Wang et al., Flexible electrodes for sodium-ion batteries: recent progress and perspectives. Adv. Mater. 29(45), 1703012 (2017). https://doi.org/10.1002/adma.201703012
  21. J.-Y. Hwang, H.-L. Du, B.-N. Yun, M.-G. Jeong, J.-S. Kim, H. Kim, H.-G. Jung, Y.-K. Sun, Carbon-free TiO2 microspheres as anode materials for sodium ion batteries. ACS Energy Lett. 4(2), 494–501 (2019). https://doi.org/10.1021/acsenergylett.8b02510
  22. H. Long, W. Zeng, H. Wang, M. Qian, Y. Liang, Z. Wang, Self-assembled biomolecular 1d nanostructures for aqueous sodium-ion battery. Adv. Sci. 5(3), 1700634 (2018). https://doi.org/10.1002/advs.201700634
  23. Y. Liu, Y. Qiao, W. Zhang, H. Xu, Z. Li et al., High-performance aqueous sodium-ion batteries with K0.27MnO2 cathode and their sodium storage mechanism. Nano Energy 5, 97–104 (2014). https://doi.org/10.1016/j.nanoen.2014.02.010
  24. H. Gao, J.B. Goodenough, An aqueous symmetric sodium-ion battery with NASICON-structured Na3MnTi(PO4)3. Angew. Chem. Int. Ed. 55(41), 12768–12772 (2016). https://doi.org/10.1002/anie.201606508
  25. L. Suo, O. Borodin, Y. Wang, X. Rong, W. Sun et al., “Water-in-salt” electrolyte makes aqueous sodium-ion battery safe, green, and long-lasting. Adv. Energy Mater. 7(21), 1701189 (2017). https://doi.org/10.1002/aenm.201701189
  26. M.H. Lee, S.J. Kim, D. Chang, J. Kim, S. Moon et al., Toward a low-cost high-voltage sodium aqueous rechargeable battery. Mater. Today (2019). https://doi.org/10.1016/j.mattod.2019.02.004
  27. X. Dong, L. Chen, J. Liu, S. Haller, Y. Wang, Y. Xia, Environmentally-friendly aqueous Li (or Na)-ion battery with fast electrode kinetics and super-long life. Sci. Adv. 2(1), 1501038 (2016). https://doi.org/10.1126/sciadv.1501038
  28. T. Jin, Q. Han, L. Jiao, Binder-free electrodes for advanced sodium-ion batteries. Adv. Mater. (2018). https://doi.org/10.1002/adma.201806304
  29. L. Xue, Q. Zhang, X. Zhu, L. Gu, J. Yue et al., 3D LiCoO2 nanosheets assembled nanorod arrays via confined dissolution-recrystallization for advanced aqueous lithium-ion batteries. Nano Energy 56, 463–472 (2019). https://doi.org/10.1016/j.nanoen.2018.11.085
  30. C. Guan, X. Liu, W. Ren, X. Li, C. Cheng, J. Wang, Rational design of metal-organic framework derived hollow NiCo2O4 arrays for flexible supercapacitor and electrocatalysis. Adv. Energy Mater. 7(12), 1602391 (2017). https://doi.org/10.1002/aenm.201602391
  31. L. Xue, S.V. Savilov, V.V. Lunin, H. Xia, Self-standing porous LiCoO2 nanosheet arrays as 3D cathodes for flexible Li-ion batteries. Adv. Funct. Mater. 28(7), 1705836 (2018). https://doi.org/10.1002/adfm.201705836
  32. Q. Zhang, Z. Zhou, Z. Pan, J. Sun, B. He et al., All-metal-organic framework-derived battery materials on carbon nanotube fibers for wearable energy-storage device. Adv. Sci. 5(12), 1801462 (2018). https://doi.org/10.1002/advs.201801462
  33. J. Han, H. Zhang, A. Varzi, S. Passerini, Fluorine-free water-in-salt electrolyte for green and low-cost aqueous sodium-ion batteries. ChemSusChem 11(21), 3704–3707 (2018). https://doi.org/10.1002/cssc.201801930
  34. K. Nakamoto, R. Sakamoto, Y. Sawada, M. Ito, S. Okada, Over 2 V aqueous sodium-ion battery with Prussian blue-type electrodes. Small Methods 3(4), 1800220 (2019). https://doi.org/10.1002/smtd.201800220
  35. Z. Li, D. Young, K. Xiang, W.C. Carter, Y.-M. Chiang, Towards high power high energy aqueous sodium-ion batteries: the NaTi2(PO4)3/Na0.44MnO2 system. Adv. Energy Mater. 3(3), 290–294 (2013). https://doi.org/10.1002/aenm.201200598
  36. W. Ren, M. Qin, Z. Zhu, M. Yan, Q. Li, L. Zhang, D. Liu, L. Mai, Activation of sodium storage sites in Prussian blue analogues via surface etching. Nano Lett. 17(8), 4713–4718 (2017). https://doi.org/10.1021/acs.nanolett.7b01366
  37. P. Ge, S. Li, H. Shuai, W. Xu, Y. Tian, L. Yang, G. Zou, H. Hou, X. Ji, Ultrafast sodium full batteries derived from xFe (x = Co, Ni, Mn) Prussian blue analogs. Adv. Mater. 31(3), 1806092 (2019). https://doi.org/10.1002/adma.201806092
  38. J. Qian, C. Wu, Y. Cao, Z. Ma, Y. Huang, X. Ai, H. Yang, Prussian blue cathode materials for sodium-ion batteries and other ion batteries. Adv. Energy Mater. 8(17), 1702619 (2018). https://doi.org/10.1002/aenm.201702619
  39. M. Pasta, C.D. Wessells, N. Liu, J. Nelson, M.T. McDowell, R.A. Huggins, M.F. Toney, Y. Cui, Full open-framework batteries for stationary energy storage. Nat. Commun. 5, 3007 (2014). https://doi.org/10.1038/ncomms4007
  40. P. Wei, Y. Liu, Z. Wang, Y. Huang, Y. Jin et al., Porous NaTi2(PO4)3/C hierarchical nanofibers for ultrafast electrochemical energy storage. ACS Appl. Mater. Interfaces 10(32), 27039–27046 (2018). https://doi.org/10.1021/acsami.8b08415
  41. L. Wang, Z. Huang, B. Wang, G. Liu, M. Cheng et al., Purifying the phase of NaTi2(PO4)3 for enhanced Na+ storage properties. ACS Appl. Mater. Interfaces 11(11), 10663–10671 (2019). https://doi.org/10.1021/acsami.9b00116
  42. Q. Yang, S. Cui, Y. Ge, Z. Tang, Z. Liu et al., Porous single-crystal NaTi2(PO4)3 via liquid transformation of TiO2 nanosheets for flexible aqueous Na-ion capacitor. Nano Energy 50, 623–631 (2018). https://doi.org/10.1016/j.nanoen.2018.06.017
  43. C. Wu, P. Kopold, Y.-L. Ding, P.A. van Aken, J. Maier, Y. Yu, Synthesizing porous NaTi2(PO4)3 nanoparticles embedded in 3D graphene networks for high-rate and long cycle-life sodium electrodes. ACS Nano 9(6), 6610–6618 (2015). https://doi.org/10.1021/acsnano.5b02787
  44. Q. Hu, J.-Y. Liao, C.-T. Li, X.-D. He, X. Ding, C.-H. Chen, Synthesis of porous carbon-coated NaTi2(PO4)3 nanocubes with a high-yield and superior rate properties. J. Mater. Chem. A 6(47), 24503–24508 (2018). https://doi.org/10.1039/C8TA10182E
  45. B. Zhao, B. Lin, S. Zhang, C. Deng, A frogspawn-inspired hierarchical porous NaTi2(PO4)3–C array for high-rate and long-life aqueous rechargeable sodium batteries. Nanoscale 7(44), 18552–18560 (2015). https://doi.org/10.1039/C5NR06505D
  46. F.-C. Zhou, Y.-H. Sun, J.-Q. Li, J.-M. Nan, K1−xMn1+x/2[Fe(CN)6]·yH2O Prussian blue analogues as an anode material for lithium-ion batteries. Appl. Surf. Sci. 444, 650–660 (2018). https://doi.org/10.1016/j.apsusc.2018.03.102
  47. Y. Zhang, Y. Wang, L. Wang, C.-M. Lo, Y. Zhao, Y. Jiao, G. Zheng, H. Peng, A fiber-shaped aqueous lithium ion battery with high power density. J. Mater. Chem. A 4(23), 9002–9008 (2016). https://doi.org/10.1039/C6TA03477B
  48. Y. Song, T. Liu, B. Yao, M. Li, T. Kou et al., Ostwald ripening improves rate capability of high mass loading manganese oxide for supercapacitors. ACS Energy Lett. 2(8), 1752–1759 (2017). https://doi.org/10.1021/acsenergylett.7b00405
  49. C. Xia, J. Guo, Y. Lei, H. Liang, C. Zhao, H.N. Alshareef, Rechargeable aqueous zinc-ion battery based on porous framework zinc pyrovanadate intercalation cathode. Adv. Mater. 30(5), 1705580 (2018). https://doi.org/10.1002/adma.201705580
  50. B. Tang, G. Fang, J. Zhou, L. Wang, Y. Lei, C. Wang, T. Lin, Y. Tang, S. Liang, Potassium vanadates with stable structure and fast ion diffusion channel as cathode for rechargeable aqueous zinc-ion batteries. Nano Energy 51, 579–587 (2018). https://doi.org/10.1016/j.nanoen.2018.07.014
  51. D. Chao, C. Zhu, M. Song, P. Liang, X. Zhang et al., A high-rate and stable quasi-solid-state zinc-ion battery with novel 2D layered zinc orthovanadate array. Adv. Mater. 30(32), 1803181 (2018). https://doi.org/10.1002/adma.201803181
  52. Y. Li, Z. Huang, P.K. Kalambate, Y. Zhong, Z. Huang, M. Xie, Y. Shen, Y. Huang, V2O5 nanopaper as a cathode material with high capacity and long cycle life for rechargeable aqueous zinc-ion battery. Nano Energy 60, 752–759 (2019). https://doi.org/10.1016/j.nanoen.2019.04.009
  53. M.S. Chae, J.W. Heo, H.H. Kwak, H. Lee, S.-T. Hong, Organic electrolyte-based rechargeable zinc-ion batteries using potassium nickel hexacyanoferrate as a cathode material. J. Power Sources 337, 204–211 (2017). https://doi.org/10.1016/j.jpowsour.2016.10.083
  54. G. Pang, P. Nie, C. Yuan, L. Shen, X. Zhang, J. Zhu, B. Ding, Enhanced performance of aqueous sodium-ion batteries using electrodes based on the NaTi2(PO4)3/MWNTs–Na0.44MnO2 system. Energy Technol. 2(8), 705–712 (2014). https://doi.org/10.1002/ente.201402045
  55. G. Sun, X. Zhang, R. Lin, J. Yang, H. Zhang, P. Chen, Hybrid fibers made of molybdenum disulfide, reduced graphene oxide, and multi-walled carbon nanotubes for solid-state, flexible, asymmetric supercapacitors. Angew. Chem. Int. Ed. 54(15), 4651–4656 (2015). https://doi.org/10.1002/anie.201411533
  56. Y. Huang, W.S. Ip, Y.Y. Lau, J. Sun, J. Zeng et al., Weavable, conductive yarn-based NiCo//Zn textile battery with high energy density and rate capability. ACS Nano 11(9), 8953–8961 (2017). https://doi.org/10.1021/acsnano.7b03322
  57. X. Wang, B. Liu, R. Liu, Q. Wang, X. Hou, D. Chen, R. Wang, G. Shen, Fiber-based flexible all-solid-state asymmetric supercapacitors for integrated photodetecting system. Angew. Chem. Int. Ed. 53(7), 1849–1853 (2014). https://doi.org/10.1002/anie.201307581
Read More
Author biographies are not available.
Download this PDF file
PDF
Statistic
Read Counter : 5487 Download : 4162

Most read articles by the same author(s)