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Vol. 13 (2021)

Atomic Modulation of 3D Conductive Frameworks Boost Performance of MnO2 for Coaxial Fiber-Shaped Supercapacitors

https://doi.org/10.1007/s40820-020-00529-8
Xiaona Wang
Division of Advanced Nanomaterials, Key Laboratory of Nanodevices and Applications, Joint Key Laboratory of Functional Nanomaterials and Devices, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano‑Tech and Nano‑Bionics, Chinese Academy of Sciences, Suzhou 215123, People’s Republic of China
Zhenyu Zhou
Division of Advanced Nanomaterials, Key Laboratory of Nanodevices and Applications, Joint Key Laboratory of Functional Nanomaterials and Devices, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano‑Tech and Nano‑Bionics, Chinese Academy of Sciences, Suzhou 215123, People’s Republic of China
Zhijian Sun
School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA
Jinho Hah
School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA
Yagang Yao
Division of Advanced Nanomaterials, Key Laboratory of Nanodevices and Applications, Joint Key Laboratory of Functional Nanomaterials and Devices, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano‑Tech and Nano‑Bionics, Chinese Academy of Sciences, Suzhou 215123, People’s Republic of China
Kyoung‑Sik Moon
School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA
Jiangtao Di
Division of Advanced Nanomaterials, Key Laboratory of Nanodevices and Applications, Joint Key Laboratory of Functional Nanomaterials and Devices, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano‑Tech and Nano‑Bionics, Chinese Academy of Sciences, Suzhou 215123, People’s Republic of China
Qingwen Li
Division of Advanced Nanomaterials, Key Laboratory of Nanodevices and Applications, Joint Key Laboratory of Functional Nanomaterials and Devices, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano‑Tech and Nano‑Bionics, Chinese Academy of Sciences, Suzhou 215123, People’s Republic of China
Ching‑ping Wong
School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA

Corresponding Author: Ching‑ping Wong

cp.wong@mse.gatech.edu

Nano-Micro Letters, Vol. 13 (2021), Article Number: 4

Abstract

Coaxial fiber-shaped supercapacitors are a promising class of energy storage devices requiring high performance for flexible and miniature electronic devices. Yet, they are still struggling from inferior energy density, which comes from the limited choices in materials and structure used. Here, Zn-doped CuO nanowires were designed as 3D framework for aligned distributing high mass loading of MnO2 nanosheets. Zn could be introduced into the CuO crystal lattice to tune the covalency character and thus improve charge transport. The Zn–CuO@MnO2 as positive electrode obtained superior performance without sacrificing its areal and gravimetric capacitances with the increasing of mass loading of MnO2 due to 3D Zn–CuO framework enabling efficient electron transport. A novel category of free-standing asymmetric coaxial fiber-shaped supercapacitor based on Zn0.11CuO@MnO2 core electrode possesses superior specific capacitance and enhanced cell potential window. This asymmetric coaxial structure provides superior performance including higher capacity and better stability under deformation because of sufficient contact between the electrodes and electrolyte. Based on these advantages, the as-prepared asymmetric coaxial fiber-shaped supercapacitor exhibits a high specific capacitance of 296.6 mF cm−2 and energy density of 133.47 μWh cm−2. In addition, its capacitance retention reaches 76.57% after bending 10,000 times, which demonstrates as-prepared device’s excellent flexibility and long-term cycling stability.


Highlights:


1 3D Zn-doped CuO framework was designed for aligned distributing high mass loading of MnO2 nanosheets.
2 Zn could be introduced into the CuO crystal lattice to tune the covalency character and thus improve charge transport.
3 A free-standing asymmetric coaxial fiber-shaped supercapacitor based on Zn–CuO@MnO2 core electrode possesses superior performance including higher capacity and better stability under deformation.

Keywords

Coaxial fiber-shaped supercapacitors 3D framework Zn–CuO nanowires Zn–CuO@MnO2 core–shell structure
Wang, Xiaona, Zhenyu Zhou, Zhijian Sun, Jinho Hah, Yagang Yao, Kyoung‑Sik Moon, Jiangtao Di, Qingwen Li, and Ching‑ping Wong. 2020. “Atomic Modulation of 3D Conductive Frameworks Boost Performance of MnO2 for Coaxial Fiber-Shaped Supercapacitors”. Nano-Micro Letters 13 (October):4. https://doi.org/10.1007/s40820-020-00529-8.
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References
  1. A.M. Zamarayeva, A.E. Ostfeld, M. Wang, J.K. Duey, I. Deckman et al., Flexible and stretchable power sources for wearable electronics. Sci. Adv. 3, e1602051 (2017). https://doi.org/10.1126/sciadv.1602051
  2. C. Choi, K.M. Kim, K.J. Kim, X. Lepró, G.M. Spinks, R.H. Baughman, S.J. Kim, Improvement of system capacitance via weavable superelastic biscrolled yarn supercapacitors. Nat. Commun. 7, 13811 (2016). https://doi.org/10.1038/ncomms13811
  3. V. Strauss, K. Marsh, M.D. Kowal, M. El-Kady, R.B. Kaner, A simple route to porous graphene from carbon nanodots for supercapacitor applications. Adv. Mater. 30, 1704449 (2018). https://doi.org/10.1002/adma.201704449
  4. D. Son, J. Kang, O. Vardoulis, Y. Kim, N. Matsuhisa et al., An integrated self-healable electronic skin system fabricated via dynamic reconstruction of a nanostructured conducting network. Nat. Nanotechnol. 13, 1057–1065 (2018). https://doi.org/10.1038/s41565-018-0244-6
  5. X. Wang, Q. Zhang, J. Sun, Z. Zhou, Q. Li et al., Facile synthesis of hierarchical porous manganese nickel cobalt sulfide nanotube arrays with enhanced electrochemical performance for ultrahigh energy density fiber-shaped asymmetric supercapacitors. J. Mater. Chem. A 6, 8030–8038 (2018). https://doi.org/10.1039/C8TA01440J
  6. G. Sun, X. Zhang, R. Lin, J. Yang, H. Zhang, P. Chen, Hybrid fibers made of molybdenum disulfide, reduced graphene oxide, and multi-walled carbon nanotubes for solid-state, flexible, asymmetric supercapacitors. Angew. Chem. Int. Ed. 54, 4651–4656 (2015). https://doi.org/10.1002/anie.201411533
  7. T. Chen, L. Qiu, Z. Yang, Z. Cai, J. Ren et al., An integrated “energy wire” for both photoelectric conversion and energy storage. Angew. Chem. Int. Ed. 51, 11977–11980 (2012). https://doi.org/10.1002/anie.201207023
  8. J. Bae, M.K. Song, Y.J. Park, J.M. Kim, M. Liu, Z.L. Wang, Fiber supercapacitors made of nanowire-fiber hybrid structures for wearable/flexible energy storage. Angew. Chem. Int. Ed. 50, 1683–1687 (2011). https://doi.org/10.1002/anie.201006062
  9. X. Lu, Y. Bai, R. Wang, J. Sun, A high-performance flexible and weavable asymmetric fiber-shaped solid-state supercapacitor enhanced by surface modifications of carbon fibers with carbon nanotubes. J. Mater. Chem. A 4, 18164–18173 (2016). https://doi.org/10.1039/C6TA08233E
  10. X. Dong, Z. Guo, Y. Song, M. Hou, J. Wang, Y. Wang, Y. Xia, Flexible and wire-shaped micro-supercapacitor based on Ni(OH)2-nanowire and ordered mesoporous carbon electrodes. Adv. Funct. Mater. 24, 3405–3412 (2014). https://doi.org/10.1002/adfm.201304001
  11. Q. Zhang, X. Wang, Z. Pan, J. Sun, J. Zhao et al., Wrapping aligned carbon nanotube composite sheets around vanadium nitride nanowire arrays for asymmetric coaxial fiber-shaped supercapacitors with ultrahigh energy density. Nano Lett. 17, 2719–2726 (2017). https://doi.org/10.1021/acs.nanolett.7b00854
  12. Y. Zhang, B. Wang, F. Liu, J. Cheng, X.W. Zhang, L. Zhang, Full synergistic contribution of electrodeposited three-dimensional NiCO2O4@MnO2 nanosheet networks electrode for asymmetric supercapacitors. Nano Energy 27, 627–637 (2016). https://doi.org/10.1016/j.nanoen.2016.08.013
  13. N. Liu, Y. Su, Z. Wang, Z. Wang, J. Xia et al., Electrostatic-interaction-assisted construction of 3D networks of manganese dioxide nanosheets for flexible high-performance solid-state asymmetric supercapacitors. ACS Nano 11, 7879–7888 (2017). https://doi.org/10.1021/acsnano.7b02344
  14. P. Gao, P. Metz, T. Hey, Y. Gong, D. Liu et al., The critical role of point defects in improving the specific capacitance of δ-MnO2 nanosheets. Nat. Commun. 8, 14559 (2017). https://doi.org/10.1038/ncomms14559
  15. J. Zhu, J. He, Facile synthesis of graphene-wrapped honeycomb MnO2 nanospheres and their application in supercapacitors. ACS Appl. Mater. Interfaces 4, 1770–1776 (2012). https://doi.org/10.1021/am3000165
  16. S.W. Lee, J. Kim, S. Chen, P.T. Hammond, Y. Shao-Horn, Carbon nanotube/manganese oxide ultrathin film electrodes for electrochemical capacitors. ACS Nano 4, 3889–3896 (2010). https://doi.org/10.1021/nn100681d
  17. Z.H. Huang, Y. Song, D.-Y. Feng, Z. Sun, X. Sun, X.X. Liu, High mass loading MnO2 with hierarchical nanostructures for supercapacitors. ACS Nano 12, 3557–3567 (2018). https://doi.org/10.1021/acsnano.8b00621
  18. L. Han, P. Tang, L. Zhang, Hierarchical Co3O4@ppy@MnO2 core–shell–shell nanowire arrays for enhanced electrochemical energy storage. Nano Energy 7, 42–51 (2014). https://doi.org/10.1016/j.nanoen.2014.04.014
  19. X. Lu, T. Zhai, X. Zhang, Y. Shen, L. Yuan et al., WO3-x@Au@MnO2 core–shell nanowires on carbon fabric for high-performance flexible supercapacitors. Adv. Mater. 24, 938–944 (2012). https://doi.org/10.1002/adma.201104113
  20. H. Xu, X. Hu, Y. Sun, H. Yang, X. Liu, Y. Huang, Flexible fiber-shaped supercapacitors based on hierarchically nanostructured composite electrodes. Nano Res. 8, 1148–1158 (2015). https://doi.org/10.1007/s12274-014-0595-8
  21. L. Yu, H. Zhou, J. Sun, F. Qin, F. Yu et al., Cu nanowires shelled with NiFe layered double hydroxide nanosheets as bifunctional electrocatalysts for overall water splitting. Energy Environ. Sci. 10, 1820–1827 (2017). https://doi.org/10.1039/C7EE01571B
  22. Z. Pan, Y. Qiu, J. Yang, F. Ye, Y. Xu et al., Ultra-endurance flexible all-solid-state asymmetric supercapacitors based on three-dimensionally coated mnox nanosheets on nanoporous current collectors. Nano Energy 26, 610–619 (2016). https://doi.org/10.1016/j.nanoen.2016.05.053
  23. D. Kong, C. Cheng, Y. Wang, J. Wong, Y. Yang, H. Yang, Three-dimensional Co3O4@C@Ni3S2 sandwich-structured nanoneedle arrays: towards high-performance flexible all-solid-state asymmetric supercapacitors. J. Mater. Chem. A 3, 16150–16161 (2015). https://doi.org/10.1039/c5ta03469h
  24. Z. Zhang, F. Xiao, S. Wang, Hierarchically structured MnO2/graphene/carbon fiber and porous graphene hydrogel wrapped copper wire for fiber-based flexible all-solid-state asymmetric supercapacitors. J. Mater. Chem. A 3, 11215–11223 (2015). https://doi.org/10.1039/c5ta02331a
  25. X. Wang, J. Sun, J. Zhao, Z. Zhou, Q. Zhang, C.P. Wong, Y. Yao, All-solid-state fiber-shaped asymmetric supercapacitors with ultrahigh energy density based on porous vanadium nitride nanowires and ultrathin Ni(OH)2 nanosheet wrapped NiCo2O4 nanowires arrays electrode. J. Phys. Chem. C 123, 985–993 (2019). https://doi.org/10.1021/acs.jpcc.8b05862
  26. R.O. Yathisha, Y. Arthoba Nayaka, Structural, optical and electrical properties of zinc incorporated copper oxide nanoparticles: Doping effect of Zn. J. Mater. Sci. 53, 678–691 (2018). https://doi.org/10.1007/s10853-017-1496-5
  27. Z. Li, M. Shao, L. Zhou, R. Zhang, C. Zhang et al., A flexible all-solid-state micro-supercapacitor based on hierarchical CuO@layered double hydroxide core–shell nanoarrays. Nano Energy 20, 294–304 (2016). https://doi.org/10.1016/j.nanoen.2015.12.030
  28. M. Huang, Y. Zhang, F. Li, Z.A. Wang et al., Merging of kirkendall growth and ostwald ripening: CuO@MnO2 core-shell architectures for asymmetric supercapacitors. Sci. Rep. 4, 4518 (2014). https://doi.org/10.1038/srep04518
  29. T. Wen, X.L. Wu, S. Zhang, X. Wang, A.W. Xu, Core–shell carbon-coated CuO nanocomposites: a highly stable electrode material for supercapacitors and lithium-ion batteries. Chem. Asian J. 10, 595–601 (2015). https://doi.org/10.1002/asia.201403295
  30. A.K. Jyoti, G.D. Srivastava, Varma, highly selective and efficient room temperature NO2 gas sensors based on Zn-doped CuO nanostructure-rGo hybrid. J. Mater. Sci. Mater. E 29, 10640 (2018). https://doi.org/10.1007/s10854-018-9128-7
  31. N. Yu, H. Yin, W. Zhang, Y. Liu, Z. Tang, M.Q. Zhu, High-performance fiber-shaped all-solid-state asymmetric supercapacitors based on ultrathin MnO2 nanosheet/carbon fiber cathodes for wearable electronics. Adv. Energy Mater. 6, 1501458 (2016). https://doi.org/10.1002/aenm.201501458
  32. J. Yu, W. Lu, J.P. Smith, K.S. Booksh, L. Meng et al., A high performance stretchable asymmetric fiber-shaped supercapacitor with a core-sheath helical structure. Adv. Energy Mater. 7, 1600976 (2017). https://doi.org/10.1002/aenm.201600976
  33. Z. Pan, J. Zhong, Q. Zhang, J. Yang, Y. Qiu et al., Ultrafast all-solid-state coaxial asymmetric fiber supercapacitors with a high volumetric energy density. Adv. Energy Mater. 8, 1702946 (2018). https://doi.org/10.1002/aenm.201702946
  34. L. Li, Z. Lou, D. Chen, W. Han, G. Shen, Hollow polypyrrole sleeve based coaxial fiber supercapacitors for wearable integrated photosensing system. Adv. Mater. Technol. 3, 1800115 (2018). https://doi.org/10.1002/admt.201800115
  35. B. Patil, S. Ahn, S. Yu, H. Song, Y. Jeong, J.H. Kim, H. Ahn, Electrochemical performance of a coaxial fiber-shaped asymmetric supercapacitor based on nanostructured MnO2/CNT-web paper and Fe2O3/carbon fiber electrodes. Carbon 134, 366–375 (2018). https://doi.org/10.1016/j.carbon.2018.03.080
  36. Z. Yu, J. Moore, J. Calderon, L. Zhai, J. Thomas, Coil-type asymmetric supercapacitor electrical cables. Small 11, 5289–5295 (2015). https://doi.org/10.1002/smll.201501802
  37. Z. Yu, J. Thomas, Energy storing electrical cables: Integrating energy storage and electrical conduction. Adv. Mater. 26, 4279–4285 (2014). https://doi.org/10.1002/adma.201400440
  38. H. Yuan, G. Wang, Y. Zhao, Y. Liu, Y. Wu, Y. Zhang, A stretchable, asymmetric, coaxial fiber-shaped supercapacitor for wearable electronics. Nano Res. 13, 1686–1692 (2020). https://doi.org/10.1007/s12274-020-2793-x
  39. T.S. Le, T.K. Truong, V.N. Huynh, J. Bae, D. Suh, Synergetic design of enlarged surface area and pseudo-capacitance for fiber-shaped supercapacitor yarn. Nano Energy 67, 104198 (2020). https://doi.org/10.1016/j.nanoen.2019.104198
  40. A. Rafique, A. Massa, M. Fontana, S. Bianco, A. Chiodoni et al., Highly uniform anodically deposited film of MnO2 nanoflakes on carbon fibers for flexible and wearable fiber-shaped Supercapacitors. ACS Appl. Mater. Interfaces 9, 28386 (2017). https://doi.org/10.1021/acsami.7b06311
  41. P. Zhang, Y. Li, G. Wang, F. Wang, S. Yang et al., Zn-ion hybrid micro-supercapacitors with ultrahigh areal energy density and long-term durability. Adv. Mater. 31, 1806005 (2019). https://doi.org/10.1002/adma.201806005
  42. J. Guoa, Q. Zhang, J. Sun, C. Li, J. Zhao et al., Direct growth of vanadium nitride nanosheets on carbon nanotube fibers as novel negative electrodes for high-energy-density wearable fiber-shaped asymmetric supercapacitors. J. Power Sources 382, 122–127 (2018). https://doi.org/10.1016/j.jpowsour.2018.02.034
  43. Q. Zhang, J. Sun, Z. Pan, J. Zhang, J. Zhao et al., Stretchable fiber-shaped asymmetric supercapacitors with ultrahigh energy density. Nano Energy 39, 219–228 (2017). https://doi.org/10.1016/j.nanoen.2017.06.052
  44. Z. Wang, J. Cheng, J. Zhou, J. Zhang, H. Huang et al., All-climate aqueous fiber-shaped supercapacitors with record areal energy density and high safety. Nano Energy 50, 106–117 (2018). https://doi.org/10.1016/j.nanoen.2018.05.029
  45. W. Teng, Q. Zhou, X. Wang, H. Che, P. Hu, H. Li, J. Wang, Hierarchically interconnected conducting polymer hybrid fiber with high specific capacitance for flexible fiber-shaped supercapacitor. Chem. Eng. J. 390, 124569 (2020). https://doi.org/10.1016/j.cej.2020.124569
  46. J. Zhao, L. Li, Y. Zhang, C. Li, Q. Zhang et al., Novel coaxial fiber-shaped sensing system integrated with an asymmetric supercapacitor and a humidity sensor. Energy Storage Mater. 15, 315–323 (2018). https://doi.org/10.1016/j.ensm.2018.06.007
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