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Vol. 15 (2023)

MXene Lubricated Tribovoltaic Nanogenerator with High Current Output and Long Lifetime

https://doi.org/10.1007/s40820-023-01198-z
Wenyan Qiao
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, People’s Republic of China
Linglin Zhou
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, People’s Republic of China
Zhihao Zhao
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, People’s Republic of China
Peiyuan Yang
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, People’s Republic of China
Di Liu
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, People’s Republic of China
Xiaoru Liu
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, People’s Republic of China
Jiaqi Liu
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, People’s Republic of China
Dongyang Liu
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, People’s Republic of China
Zhong Lin Wang
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, People’s Republic of China
Jie Wang
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, People’s Republic of China

Corresponding Author: Jie Wang

wangjie@binn.cas.cn

Nano-Micro Letters, Vol. 15 (2023), Article Number: 218

Abstract

Tribovoltaic nanogenerators (TVNGs) have the characteristics of high current density, low matched impedance and continuous output, which is expected to solve the problem of power supply for small electronic devices. However, wear occurrence in friction interface will seriously reduce the performance of TVNGs as well as lifetime. Here, we employ MXene solution as lubricate to improve output current density and lifetime of TVNG simultaneously, where a high value of 754 mA m−2 accompanied with a record durability of 90,000 cycles were achieved. By comparing multiple liquid lubricates with different polarity, we show that conductive polar liquid with MXene as additive plays a crucial role in enhancing the electrical output performance and durability of TVNG. Moreover, the universality of MXene solution is well demonstrated in various TVNGs with Cu and P-type Si, and Cu and N-GaAs as material pairs. This work may guide and accelerates the practical application of TVNG in future.


Highlights:
1 Successfully solves the key issue of tribovoltaic nanogenerators (TVNGs) lifetime (90,000 cycles) and improves its output current density (754 mA m−2) simultaneously.
2 Conductive polar liquid with MXene as additive is proposed as the dominant factor in enhancing the electrical output performance and durability of TVNG simultaneously.
3 The mechanism of lubricated TVNG with enhanced output performance is explained from the perspective of solution polarity at the first time.
4 Mxene solution exhibits universality in different types of semiconductor systems (Cu and P-type Si, and Cu and N-GaAs as material pairs).

Keywords

Tribovoltaic nanogenerators Ultra-robust Interface wear Interface lubricant
Qiao, Wenyan, Linglin Zhou, Zhihao Zhao, Peiyuan Yang, Di Liu, Xiaoru Liu, Jiaqi Liu, Dongyang Liu, Zhong Lin Wang, and Jie Wang. 2023. “MXene Lubricated Tribovoltaic Nanogenerator With High Current Output and Long Lifetime”. Nano-Micro Letters 15 (October):218. https://doi.org/10.1007/s40820-023-01198-z.
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References
  1. Z.L. Wang, W. Wu, Nanotechnology-enabled energy harvesting for self-powered micro-/nanosystems. Angew. Chem. Int. Ed. 51, 11700–11721 (2012). https://doi.org/10.1002/anie.201201656
  2. Z.L. Wang, On Maxwell’s displacement current for energy and sensors: the origin of nanogenerators. Mater. Today 20, 74–82 (2017). https://doi.org/10.1016/j.mattod.2016.12.001
  3. F. Fan, Z. Tian, Z.L. Wang, Flexible triboelectric generator! Nano Energy 1, 328–334 (2012). https://doi.org/10.1016/j.nanoen.2012.01.004
  4. X. Yin, D. Liu, L. Zhou, X. Li, G. Xu et al., A motion vector sensor via direct-current triboelectric nanogenerator. Adv. Funct. Mater. 30, 2002547 (2020). https://doi.org/10.1002/adfm.202002547
  5. S. Li, Z. Zhao, D. Liu, J. An, Y. Gao et al., A self-powered dual-type signal vector sensor for smart robotics and automatic vehicles. Adv. Mater. 10, 1002 (2022). https://doi.org/10.1002/adma.202110363
  6. S. Li, L. Liu, Z. Zhao, L. Zhou, X. Yin et al., A fully self-powered vibration monitoring system driven by dual-mode triboelectric nanogenerators. ACS Nano 14, 2475–2482 (2020). https://doi.org/10.1021/acsnano.9b10142
  7. M. Xu, P. Wang, Y. Wang, S. Zhang, A. Wang et al., A soft and robust spring based triboelectric nanogenerator for harvesting arbitrary directional vibration energy and self-powered vibration sensing. Adv. Energy Mater. 8, 1702432 (2018). https://doi.org/10.1002/aenm.201702432
  8. X. Xiao, X. Zhang, S. Wang, H. Ouyang, P. Chen et al., Honeycomb structure inspired triboelectric nanogenerator for highly effective vibration energy harvesting and self-powered engine condition monitoring. Adv. Energy Mater. 9, 1902460 (2019). https://doi.org/10.1002/aenm.201902460
  9. R. Wu, S. Seo, L. Ma, J. Bae, T. Kim, Full-fiber auxetic-interlaced yarn sensor for sign-language translation glove assisted by artificial neural network. Nano-Micro Lett. 14, 139 (2022). https://doi.org/10.1007/s40820-022-00887-5
  10. S. Shen, J. Yi, Z. Sun, Z. Guo, T. He et al., Human machine interface with wearable electronics using biodegradable triboelectric films for calligraphy practice and correction. Nano-Micro Lett. 14, 225 (2022). https://doi.org/10.1007/s40820-022-00965-8
  11. L. Ma, R. Wu, S. Liu, A. Patil, H. Gong et al., A machine-fabricated 3d honeycomb-structured flame-retardant triboelectric fabric for fire escape and rescue. Adv. Mater. 32, 2003897 (2020). https://doi.org/10.1002/adma.202003897
  12. R. Wu, S. Liu, Z. Lin, S. Zhu, L. Ma et al., Industrial fabrication of 3d braided stretchable hierarchical interlocked fancy-yarn triboelectric nanogenerator for self-powered smart fitness system. Adv. Energy Mater. 12, 2201288 (2022). https://doi.org/10.1002/aenm.202201288
  13. L. Ma, M. Zhou, J. Wang, W. Guo, Z.L. Wang et al., Continuous and scalable manufacture of hybridized nano-micro triboelectric yarns for energy harvesting and signal sensing. ACS Nano 14, 4716–4726 (2020). https://doi.org/10.1021/acsnano.0c00524
  14. X. Hang, X. Xiang, J. Nie, D. Peng, F. Yang et al., Microscale Schottky superlubric generator with high direct-current density and ultralong life. Nat. Commun. 12, 2268 (2021). https://doi.org/10.1038/s41467-021-22371-1
  15. Z.L. Wang, A. Wang, On the origin of contact-electrification. Mater. Today 30, 34–51 (2019). https://doi.org/10.1016/j.mattod.2019.05.016
  16. M. Zheng, S. Lin, Z. Tang, Y. Feng, Z.L. Wang, Photovoltaic effect and tribovoltaic effect at liquid-semiconductor interface. Nano Energy 83, 105810 (2021). https://doi.org/10.1016/j.nanoen.2021.105810
  17. G. Liu, J. Liu, W. Dou, Non-adiabatic quantum dynamics of tribovoltaic effects at sliding metal–semiconductor interfaces. Nano Energy 96, 107034 (2022). https://doi.org/10.1016/j.nanoen.2022.107034
  18. H. Yuan, Z. Xiao, J. Wan, Y. Xiang, G. Dai et al., A rolling-mode Al/CsPbBr3 schottky junction direct-current triboelectric nanogenerator for harvesting mechanical and solar energy. Adv. Energy Mater. 12, 2200550 (2022). https://doi.org/10.1002/aenm.202200550
  19. L. Ren, A. Yu, W. Wang, D. Guo, M. Jia et al., p–n junction based direct-current triboelectric nanogenerator by conjunction of tribovoltaic effect and photovoltaic effect. Nano Lett. 21, 10099–10106 (2021). https://doi.org/10.1021/acs.nanolett.1c03922
  20. S. Lin, X. Chen, Z.L. Wang, The tribovoltaic effect and electron transfer at a liquid-semiconductor interface. Nano Energy 76, 105070 (2020). https://doi.org/10.1016/j.nanoen.2020.105070
  21. Y. Lu, Y. Yan, X. Yu, X. Zhou, S. Feng et al., Polarized water driven dynamic p–n junction-based direct-current generator. Research 221, 7505638 (2021). https://doi.org/10.34133/2021/7505638
  22. Z. Zhang, Z. Wang, Y. Chen, Y. Feng, S. Dong et al., Semiconductor contact-electrification-dominated tribovoltaic effect for ultrahigh power generation. Adv. Mater. 34, 2200146 (2022). https://doi.org/10.1002/adma.202200146
  23. M. Zheng, S. Lin, L. Zhu, Z. Tang, Z.L. Wang, Effects of temperature on the tribovoltaic effect at liquid-solid interfaces. Adv. Mater. Interfaces 9, 2101757 (2021). https://doi.org/10.1002/admi.202101757
  24. M. Zheng, S. Lin, L. Xu, L. Zhu, Z.L. Wang, Scanning probing of the tribovoltaic effect at the sliding interface of two semiconductors. Adv. Mater. 32, 2000928 (2020). https://doi.org/10.1002/adma.202000928
  25. Y. Chen, Z. Zhang, Z. Wang, T. Bu, S. Dong et al., Friction-dominated carrier excitation and transport mechanism for gan-based direct-current triboelectric nanogenerators. ACS Appl. Mater. Interfaces 14, 24020–24027 (2022). https://doi.org/10.1021/acsami.2c03853
  26. M. Benner, R. Yang, L. Lin, M. Liu, H. Li et al., Mechanism of in-plane and out-of-plane tribovoltaic direct-current transport with a metal/oxide/metal dynamic heterojunction. ACS Appl. Mater. Interfaces 14, 2968–2978 (2022). https://doi.org/10.1021/acsami.1c22438
  27. R. Yang, Z. He, S. Lin, W. Dou, Z.L. Wang et al., Tunable tribovoltaic effect via metal−insulator transition. Nano Lett. 22, 9084–9091 (2022). https://doi.org/10.1021/acs.nanolett.2c03481
  28. A. Šutka, M. Zubkins, A. Linarts, L. Lapcinskis, K. Ma ̌lalnieks et al., Tribovoltaic device based on the W/WO3 schottky junction operating through hot carrier extraction. J. Phys. Chem. C 125, 14212–14220 (2021). https://doi.org/10.1021/acs.jpcc.1c04312
  29. J. Meng, Z. Guo, C. Pan, L. Wang, C. Chang et al., Flexible textile direct-current generator based on the tribovoltaic effect at dynamic metal-semiconducting polymer interfaces. ACS Energy Lett. 6, 2442–2450 (2021). https://doi.org/10.1021/acsenergylett.1c00288
  30. L. Zhang, H. Cai, L. Xu, L. Ji, D. Wang et al., Macro-superlubric triboelectric nanogenerator based on tribovoltaic effect. Matter 5, 1532–1546 (2022). https://doi.org/10.1016/j.matt.2022.02.021
  31. Z. Wang, Z. Zhang, Y. Chen, L. Gong, S. Dong et al., Achieving an ultrahigh direct-current voltage of 130 V by semiconductor heterojunction power generation based on the tribovoltaic effect. Energy Environ. Sci. 15, 2366–2373 (2022)
  32. W. Qiao, Z. Zhao, L. Zhou, D. Liu, S. Li et al., Simultaneously enhancing direct-current density and lifetime of tribovotaic nanogenerator via interface lubrication. Adv. Funct. Mater. 32, 2208544 (2022). https://doi.org/10.1002/adfm.202208544
  33. J. Xia, X. Luo, J. Li, L. Zhu, Z.L. Wang, Wear-resisting and stable 4H-SiC/Cu-based tribovoltaic nanogenerators for self-powered sensing in a harsh environment. ACS Appl. Mater. Interfaces 14, 55192–55200 (2022). https://doi.org/10.1021/acsami.2c15781
  34. Z. Zhang, T. He, J. Zhao, G. Liu, Z.L. Wang et al., Tribo-thermoelectric and tribovoltaic coupling effect at metalsemiconductor interface. Mater. Today Phys. 16, 100295 (2021). https://doi.org/10.1016/j.mtphys.2020.100295
  35. D. Yang, L. Zhang, N. Luo, Y. Liu, W. Sun et al., Tribological-behaviour-controlled direct-current triboelectric nanogenerator based on the tribovoltaic effect under high contact pressure. Nano Energy 99, 107370 (2022). https://doi.org/10.1016/j.nanoen.2022.107370
  36. Z. Wang, L. Gong, S. Dong, B. Fan, Y. Feng et al., A humidity-enhanced silicon-based semiconductor tribovoltaic direct-current nanogenerator. J. Mater. Chem. A 10, 25230 (2022). https://doi.org/10.1039/d2ta07637c
  37. Z. Zhang, D. Jiang, J. Zhao, G. Liu, T. Bu et al., Tribovoltaic effect on metal–semiconductor interface for direct-current low-impedance triboelectric nanogenerators. Adv. Energy Mater. 10, 1903713 (2020). https://doi.org/10.1002/aenm.201903713
  38. X. Luo, L. Liu, Y. Wang, J. Li, A. Berbille et al., Tribovoltaic nanogenerators based on mxene–silicon heterojunctions for highly stable self-powered speed, displacement, tension, oscillation angle, and vibration sensors. Adv. Funct. Mater. 32, 2113149 (2022). https://doi.org/10.1002/adfm.202113149
  39. X. Xu, J. Li, X. Tao, Q. Yan, H. Wu et al., Study of interfacial design for direct-current tribovoltaic generators. Nano Energy 94, 106957 (2022). https://doi.org/10.1016/j.nanoen.2022.106957
  40. S. Yi, J. Li, Y. Liu, X. Ge, J. Zhang et al., In-situ formation of tribofilm with Ti3C2Tx MXene nanoflakes triggers macroscale superlubricity. Tribol. Int. 154, 106695 (2021). https://doi.org/10.1016/j.triboint.2020.106695
  41. M. Mariana, S. Tremmela, S. Wartzacka, G. Songb, B. Wangb et al., Mxene nanosheets as an emerging solid lubricant for machine elements—towards increased energy efficiency and service life. Appl. Surf. Sci. 523, 146503 (2020). https://doi.org/10.1016/j.apsusc.2020.146503
  42. S. Huang, K. Mutyala, A. Sumant, V. Mochalin, Achieving superlubricity with 2D transition metal carbides (MXenes) and MXene/graphene coatings. Mater. Today Adv. 9, 100133 (2021). https://doi.org/10.1016/j.mtadv.2021.100133
  43. P. Serles, M. Hamidinejad, P. Demingos, L. Ma, N. Barri et al., Friction of Ti3C2Tx MXenes. Nano Lett. 22, 3356–3363 (2022). https://doi.org/10.1021/acs.nanolett.2c00614
  44. P. Pendyala, J. Lee, S. Kim, E. Yoon, Layer-dependent frictional properties of Ti3C2Tx MXene nanosheets. Appl. Surface Sci. 603, 154402 (2022). https://doi.org/10.1016/j.apsusc.2022.154402
  45. A. Rosenkranz, M. Righi, A. Sumant, B. Anasori, V. Mochalin, Perspectives of 2D MXene tribology. Adv. Mater. 35, 2207757 (2023). https://doi.org/10.1002/adma.202207757
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