Issue

Vol. 15 (2023)

Quasi-Solid Electrolyte Interphase Boosting Charge and Mass Transfer for Dendrite-Free Zinc Battery

https://doi.org/10.1007/s40820-023-01031-7
Xueer Xu
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Yifei Xu
Institute for Composites Science Innovation (InCSI) and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Jingtong Zhang
Zhejiang Laboratory, Hangzhou 311100, People’s Republic of China
Yu Zhong
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Zhongxu Li
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Huayu Qiu
Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, People’s Republic of China
Hao Bin Wu
Institute for Composites Science Innovation (InCSI) and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Jie Wang
Zhejiang Laboratory, Hangzhou 311100, People’s Republic of China
Xiuli Wang
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Changdong Gu
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Jiangping Tu
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China

Corresponding Author: Changdong Gu

cdgu@zju.edu.cn

Nano-Micro Letters, Vol. 15 (2023), Article Number: 56

Abstract

The practical applications of zinc metal batteries are plagued by the dendritic propagation of its metal anodes due to the limited transfer rate of charge and mass at the electrode/electrolyte interphase. To enhance the reversibility of Zn metal, a quasi-solid interphase composed by defective metal–organic framework (MOF) nanoparticles (D-UiO-66) and two kinds of zinc salts electrolytes is fabricated on the Zn surface served as a zinc ions reservoir. Particularly, anions in the aqueous electrolytes could be spontaneously anchored onto the Lewis acidic sites in defective MOF channels. With the synergistic effect between the MOF channels and the anchored anions, Zn2+ transport is prompted significantly. Simultaneously, such quasi-solid interphase boost charge and mass transfer of Zn2+, leading to a high zinc transference number, good ionic conductivity, and high Zn2+ concentration near the anode, which mitigates Zn dendrite growth obviously. Encouragingly, unprecedented average coulombic efficiency of 99.8% is achieved in the Zn||Cu cell with the proposed quasi-solid interphase. The cycling performance of D-UiO-66@Zn||MnO2 (~ 92.9% capacity retention after 2000 cycles) and D-UiO-66@Zn||NH4V4O10 (~ 84.0% capacity retention after 800 cycles) prove the feasibility of the quasi-solid interphase.


Highlights:


1 Defect engineering for constructing Zn2+ reservoir to anchor anions.
2 The quasi-solid electrolyte interphase as Zn2+ reservoir boosting charge and mass transfer for dendrite-free zinc battery.
3 A Coulombic efficiency of 99.8% was achieved in Zn||Cu cell.

Keywords

Mass transfer Defect engineering Quasi-solid electrolyte interphase Zinc metal anode Zinc batteries
Xu, Xueer, Yifei Xu, Jingtong Zhang, Yu Zhong, Zhongxu Li, Huayu Qiu, Hao Bin Wu, Jie Wang, Xiuli Wang, Changdong Gu, and Jiangping Tu. 2023. “Quasi-Solid Electrolyte Interphase Boosting Charge and Mass Transfer for Dendrite-Free Zinc Battery”. Nano-Micro Letters 15 (February):56. https://doi.org/10.1007/s40820-023-01031-7.
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References
  1. G. Fang, J. Zhou, A. Pan, S. Liang, Recent advances in aqueous zinc-ion batteries. ACS Energy Lett. 3, 2480–2501 (2018). https://doi.org/10.1021/acsenergylett.8b01426
  2. X. Ge, S. Cao, Z. Lv, Z. Zhu, Y. Tang et al., Mechano-graded electrodes mitigate the mismatch between mechanical reliability and energy density for foldable lithium-ion batteries. Adv. Mater. 34, e2206797 (2022). https://doi.org/10.1002/adma.202206797
  3. J. Yang, B. Yin, Y. Sun, H. Pan, W. Sun et al., Zinc anode for mild aqueous zinc-ion batteries: challenges, strategies, and perspectives. Nano-Micro Lett. 14, 42 (2022). https://doi.org/10.1007/s40820-021-00782-5
  4. D. Han, C. Cui, K. Zhang, Z. Wang, J. Gao et al., A non-flammable hydrous organic electrolyte for sustainable zinc batteries. Nat. Sustain. 5, 205–213 (2021). https://doi.org/10.1038/s41893-021-00800-9
  5. S. Li, J. Shang, M. Li, M. Xu, F. Zeng et al., Design and synthesis of a pi-conjugated N-heteroaromatic material for aqueous zinc-organic batteries with ultrahigh rate and extremely long life. Adv. Mater. e2207115 (2022). https://doi.org/10.1002/adma.202207115
  6. X. Wang, X. Li, H. Fan, L. Ma, Solid electrolyte interface in Zn-based battery systems. Nano-Micro Lett. 14, 205 (2022). https://doi.org/10.1007/s40820-022-00939-w
  7. Y. Zhang, L. Wang, Q. Li, B. Hu, J. Kang et al., Iodine promoted ultralow Zn nucleation overpotential and Zn-rich cathode for low-cost, fast-production and high-energy density anode-free Zn-iodine batteries. Nano-Micro Lett. 14, 208 (2022). https://doi.org/10.1007/s40820-022-00948-9
  8. Z. Wang, L. Dong, W. Huang, H. Jia, Q. Zhao et al., Simultaneously regulating uniform Zn2+ flux and electron conduction by MOF/rGO interlayers for high-performance Zn anodes. Nano-Micro Lett. 13, 73 (2021). https://doi.org/10.1007/s40820-021-00594-7
  9. B. Li, X. Zhang, T. Wang, Z. He, B. Lu et al., Interfacial engineering strategy for high-performance Zn metal anodes. Nano-Micro Lett. 14, 6 (2021). https://doi.org/10.1007/s40820-021-00764-7
  10. S. Xie, Y. Li, X. Li, Y. Zhou, Z. Dang et al., Stable zinc anodes enabled by zincophilic Cu nanowire networks. Nano-Micro Lett. 14, 39 (2021). https://doi.org/10.1007/s40820-021-00783-4
  11. H. Meng, Q. Ran, T.Y. Dai, H. Shi, S.P. Zeng et al., Surface-alloyed nanoporous zinc as reversible and stable anodes for high-performance aqueous zinc-ion battery. Nano-Micro Lett. 14, 128 (2022). https://doi.org/10.1007/s40820-022-00867-9
  12. S. Guo, S. Liang, B. Zhang, G. Fang, D. Ma et al., Cathode interfacial layer formation via in situ electrochemically charging in aqueous zinc-ion battery. ACS Nano 13, 13456–13464 (2019). https://doi.org/10.1021/acsnano.9b07042
  13. C. Sun, C. Wu, X. Gu, C. Wang, Q. Wang, Interface engineering via Ti3C2Tx MXene electrolyte additive toward dendrite-free zinc deposition. Nano-Micro Lett. 13, 89 (2021). https://doi.org/10.1007/s40820-021-00612-8
  14. Y. Zhang, C. Wei, M.-X. Wu, Y. Wang, H. Jiang et al., A high-performance COF-based aqueous zinc-bromine battery. Chem. Eng. J. 451, 138915 (2023). https://doi.org/10.1016/j.cej.2022.138915
  15. R. Zhao, H. Wang, H. Du, Y. Yang, Z. Gao et al., Lanthanum nitrate as aqueous electrolyte additive for favourable zinc metal electrodeposition. Nat. Commun. 13, 3252 (2022). https://doi.org/10.1038/s41467-022-30939-8
  16. D.E. Ciurduc, C.d.l. Cruz, N. Patil, A. Mavrandonakis, R. Marcilla, Molecular crowding bi-salt electrolyte for aqueous zinc hybrid batteries. Energy Storage Mater. 53, 532–543 (2022). https://doi.org/10.1016/j.ensm.2022.09.036
  17. S. Lv, T. Fang, Z. Ding, Y. Wang, H. Jiang et al., A high-performance quasi-solid-state aqueous zinc-dual halogen battery. ACS Nano 16, 20389–20399 (2022). https://doi.org/10.1021/acsnano.2c06362
  18. Y. Wang, Y. Liu, H. Wang, S. Dou, W. Gan et al., MOF-based ionic sieve interphase for regulated Zn2+ flux toward dendrite-free aqueous zinc-ion batteries. J. Mater. Chem. A 10, 4366–4375 (2022). https://doi.org/10.1039/d1ta10245a
  19. R. Yuksel, O. Buyukcakir, W.K. Seong, R.S. Ruoff, Metal-organic framework integrated anodes for aqueous zinc-ion batteries. Adv. Energy Mater. 10, 1904215 (2020). https://doi.org/10.1002/aenm.201904215
  20. L. Ma, M.A. Schroeder, O. Borodin, T.P. Pollard, M.S. Ding et al., Realizing high zinc reversibility in rechargeable batteries. Nat. Energy 5, 743–749 (2020). https://doi.org/10.1038/s41560-020-0674-x
  21. N. Becknell, P.P. Lopes, T. Hatsukade, X. Zhou, Y. Liu et al., Employing the dynamics of the electrochemical interface in aqueous zinc-ion battery cathodes. Adv. Funct. Mater. 31, 2102135 (2021). https://doi.org/10.1002/adfm.202102135
  22. X. Zeng, J. Mao, J. Hao, J. Liu, S. Liu et al., Electrolyte design for in situ construction of highly Zn2+ conductive solid electrolyte interphase to enable high-performance aqueous Zn-ion batteries under practical conditions. Adv. Mater. 33, e2007416 (2021). https://doi.org/10.1002/adma.202007416
  23. P. Bai, J. Li, F.R. Brushett, M.Z. Bazant, Transition of lithium growth mechanisms in liquid electrolytes. Energy Environ. Sci. 9, 3221–3229 (2016). https://doi.org/10.1039/c6ee01674j
  24. K. Wang, C. Li, Y. Liang, T. Han, H. Huang et al., Rational construction of defects in a metal–organic framework for highly efficient adsorption and separation of dyes. Chem. Eng. J. 289, 486–493 (2016). https://doi.org/10.1016/j.cej.2016.01.019
  25. Y. Song, P. Ruan, C. Mao, Y. Chang, L. Wang et al., Metal-organic frameworks functionalized separators for robust aqueous zinc-ion batteries. Nano-Micro Lett. 14, 218 (2022). https://doi.org/10.1007/s40820-022-00960-z
  26. H. Furukawa, K.E. Cordova, M. O’Keeffe, O.M. Yaghi, The chemistry and applications of metal-organic frameworks. Science 341, 1230444 (2013). https://doi.org/10.1126/science.1230444
  27. W. Xiang, J. Ren, S. Chen, C. Shen, Y. Chen et al., The metal–organic framework UiO-66 with missing-linker defects: A highly active catalyst for carbon dioxide cycloaddition. Appl. Energy 277, 115560 (2020). https://doi.org/10.1016/j.apenergy.2020.115560
  28. G.C. Shearer, S. Chavan, S. Bordiga, S. Svelle, U. Olsbye et al., Defect engineering: tuning the porosity and composition of the metal–organic framework UiO-66 via modulated synthesis. Chem. Mater. 28, 3749–3761 (2016). https://doi.org/10.1021/acs.chemmater.6b00602
  29. Y. Xu, L. Gao, L. Shen, Q. Liu, Y. Zhu et al., Ion-transport-rectifying layer enables Li-metal batteries with high energy density. Matter 3, 1685–1700 (2020). https://doi.org/10.1016/j.matt.2020.08.011
  30. L. Shen, H.B. Wu, F. Liu, J.L. Brosmer, G. Shen et al., Creating lithium-ion electrolytes with biomimetic ionic channels in metal-organic frameworks. Adv. Mater. 30, e1707476 (2018). https://doi.org/10.1002/adma.201707476
  31. Z. Pei, Symmetric is nonidentical: Operation history matters for Zn metal anode. Nano Res. Energy 1, 9120023 (2022). https://doi.org/10.26599/nre.2022.9120023
  32. L. Ma, Y. Ying, S. Chen, Z. Huang, X. Li et al., Electrocatalytic iodine reduction reaction enabled by aqueous zinc-iodine battery with improved power and energy densities. Angew. Chem. Int. Ed. 60, 3791–3798 (2021). https://doi.org/10.1002/anie.202014447
  33. J.H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti et al., A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability. J. Am. Chem. Soc. 130, 13850–13851 (2008). https://doi.org/10.1021/ja8057953
  34. K. Užarević, T.C. Wang, S.Y. Moon, A.M. Fidelli, J.T. Hupp et al., Mechanochemical and solvent-free assembly of zirconium-based metal-organic frameworks. Chem. Commun. 52, 2133–2136 (2016). https://doi.org/10.1039/c5cc08972g
  35. C.L. Luu, T.T.V. Nguyen, T. Nguyen, T.C. Hoang, Synthesis, characterization and adsorption ability of UiO-66-NH2. Adv. Nat. Sci. Nanosci. Nanotechnol. 6, 025004 (2015). https://doi.org/10.1088/2043-6262/6/2/025004
  36. G.Y. Zhang, D. Peak, Studies of Cd(II)–sulfate interactions at the goethite–water interface by ATR-FTIR spectroscopy. Geochim. Cosmochim. Acta 71, 2158–2169 (2007). https://doi.org/10.1016/j.gca.2006.12.020
  37. A.M. Petrosyan, V.V. Ghazaryan, G. Giester, M. Fleck, Sulfamates and methanesulfonates of l -arginine and l -histidine. J. Mol. Struct. 1163, 114–127 (2018). https://doi.org/10.1016/j.molstruc.2018.02.112
  38. X. Xu, H. Su, J. Zhang, Y. Zhong, Y. Xu et al., Sulfamate-derived solid electrolyte interphase for reversible aqueous zinc battery. ACS Energy Lett. 4459–4468 (2022). https://doi.org/10.1021/acsenergylett.2c02236
  39. H. Qiu, R. Hu, X. Du, Z. Chen, J. Zhao et al., Eutectic Crystallization Activates Solid-State Zinc-Ion Conduction. Angew. Chem. Int. Ed. 61, e202113086 (2021). https://doi.org/10.1002/anie.202113086
  40. Atzori C, Shearer GC, Maschio L, Civalleri B, Bonino F et al., Effect of benzoic acid as a modulator in the structure of UiO-66. J. Phys. Chem. C 121, 9312–9324 (2017). https://doi.org/10.1021/acs.jpcc.7b00483
  41. F. Mo, Z. Chen, G. Liang, D. Wang, Y. Zhao et al., Zwitterionic sulfobetaine hydrogel electrolyte building separated positive/negative ion migration channels for aqueous Zn-MnO2 batteries with superior rate capabilities. Adv. Energy Mater. 10, 2000035 (2020). https://doi.org/10.1002/aenm.202000035
  42. H. Yang, Z. Chang, Y. Qiao, H. Deng, X. Mu et al., Constructing a super-saturated electrolyte front surface for stable rechargeable aqueous zinc batteries. Angew. Chem. Int. Ed. 59, 9377–9381 (2020). https://doi.org/10.1002/anie.202001844
  43. F. Sagane, K.-I. Ikeda, K. Okita, H. Sano, H. Sakaebe et al., Effects of current densities on the lithium plating morphology at a lithium phosphorus oxynitride glass electrolyte/copper thin film interface. J. Power Sources 233, 34–42 (2013). https://doi.org/10.1016/j.jpowsour.2013.01.051
  44. M. Zhou, Y. Chen, G. Fang, S. Liang, Electrolyte/electrode interfacial electrochemical behaviors and optimization strategies in aqueous zinc-ion batteries. Energy Storage Mater. 45, 618–646 (2022). https://doi.org/10.1016/j.ensm.2021.12.011
  45. Q. Yang, G. Liang, Y. Guo, Z. Liu, B. Yan et al., Do zinc dendrites exist in neutral zinc batteries: a developed electrohealing strategy to in situ rescue in-service batteries. Adv. Mater. 31, e1903778 (2019). https://doi.org/10.1002/adma.201903778
  46. M. He, C. Shu, A. Hu, R. Zheng, M. Li et al., Suppressing dendrite growth and side reactions on Zn metal anode via guiding interfacial anion/cation/H2O distribution by artificial multi-functional interface layer. Energy Storage Mater. 44, 452–460 (2022). https://doi.org/10.1016/j.ensm.2021.11.010
  47. A. Kushima, K.P. So, C. Su, P. Bai, N. Kuriyama et al., Liquid cell transmission electron microscopy observation of lithium metal growth and dissolution: Root growth, dead lithium and lithium flotsams. Nano Energy 32, 271–279 (2017). https://doi.org/10.1016/j.nanoen.2016.12.001
  48. X. Li, M. Li, K. Luo, Y. Hou, P. Li et al., Lattice matching and halogen regulation for synergistically induced uniform zinc electrodeposition by halogenated Ti3C2 MXenes. ACS Nano 16, 813–822 (2022). https://doi.org/10.1021/acsnano.1c08358
  49. X. Li, Q. Li, Y. Hou, Q. Yang, Z. Chen et al., Toward a practical Zn powder anode: Ti3C2TXMXene as a lattice-match electrons/ions redistributor. ACS Nano 15, 14631–14642 (2021). https://doi.org/10.1021/acsnano.1c04354
  50. F. Wang, E. Hu, W. Sun, T. Gao, X. Ji et al., A rechargeable aqueous Zn2+ battery with high power density and a long cycle-life. Energy Environ. Sci. 11, 3168–3175 (2018). https://doi.org/10.1039/c8ee01883a
  51. J. Gao, X. Xie, S. Liang, B. Lu, J. Zhou, Inorganic colloidal electrolyte for highly robust zinc-ion batteries. Nano-Micro Lett. 13, 69 (2021). https://doi.org/10.1007/s40820-021-00595-6
  52. Y. Zhang, S. Deng, Y. Li, B. Liu, G. Pan et al., Anchoring MnO2 on nitrogen-doped porous carbon nanosheets as flexible arrays cathodes for advanced rechargeable Zn–MnO2 batteries. Energy Storage Mater. 29, 52–59 (2020). https://doi.org/10.1016/j.ensm.2020.04.003
  53. X. Wang, J. Meng, X. Lin, Y. Yang, S. Zhou et al., Stable zinc metal anodes with textured crystal faces and functional zinc compound coatings. Adv. Funct. Mater. 31, 2106114 (2021). https://doi.org/10.1002/adfm.202106114
  54. H. Pan, Y. Shao, P. Yan, Y. Cheng, K.S. Han et al., Reversible aqueous zinc/manganese oxide energy storage from conversion reactions. Nat. Energy 1, 1–7 (2016). https://doi.org/10.1038/nenergy.2016.39
  55. X. Li, P. Xu, Y. Tian, A. Fortini, S.H. Choi et al., Electrolyte modulators toward polarization-mitigated lithium-ion batteries for sustainable electric transportation. Adv. Mater. 34, e2107787 (2022). https://doi.org/10.1002/adma.202107787
  56. D. Han, Z. Wang, H. Lu, H. Li, C. Cui et al., A Self-regulated interface toward highly reversible aqueous zinc batteries. Adv. Energy Mater. 12, 2102982 (2022). https://doi.org/10.1002/aenm.202102982
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