Issue

Vol. 18 (2026)

Electrospun Nanofiber-Based Ceramic Aerogels: Synergistic Strategies for Design and Functionalization

https://doi.org/10.1007/s40820-025-01864-4
Panpan Li
State Key Laboratory of Advanced Fiber Materials, College of Textiles, Donghua University, Shanghai 201620, People’s Republic of China
Xuan Zhang
College of Materials Science and Engineering, Donghua University, Shanghai 201620, People’s Republic of China
Ying Li
Innovation Center for Textile Science and Technology, Donghua University, Shanghai 200051, People’s Republic of China
Cunyi Zhao
State Key Laboratory of Advanced Fiber Materials, College of Textiles, Donghua University, Shanghai 201620, People’s Republic of China
Jianyong Yu
Innovation Center for Textile Science and Technology, Donghua University, Shanghai 200051, People’s Republic of China
Yang Si
State Key Laboratory of Advanced Fiber Materials, College of Textiles, Donghua University, Shanghai 201620, People’s Republic of China

Corresponding Author: Yang Si

yangsi@dhu.edu.cn

Nano-Micro Letters, Vol. 18 (2026), Article Number: 23

Abstract

Ceramic aerogels (CAs) have emerged as a significant research frontier across various applications due to their lightweight, high porosity, and easily tunable structural characteristics. However, the intrinsic weak interactions among the constituent nanoparticles, coupled with the limited toughness of traditional CAs, make them susceptible to structural collapse or even catastrophic failure when exposed to complex mechanical external forces. Unlike 0D building units, 1D ceramic nanofibers (CNFs) possess a high aspect ratio and exceptional flexibility simultaneously, which are desirable building blocks for elastic CAs. This review presents the recent progress in electrospun ceramic nanofibrous aerogels (ECNFAs) that are constructed using ECNFs as building blocks, focusing on the various preparation methods and corresponding structural characteristics, strategies for optimizing mechanical performance, and a wide range of applications. The methods for preparing ECNFs and ECNFAs with diverse structures were initially explored, followed by the implementation of optimization strategies for enhancing ECNFAs, emphasizing the improvement of reinforcing the ECNFs, establishing the bonding effects between ECNFs, and designing the aggregate structures of the aerogels. Moreover, the applications of ECNFAs across various fields are also discussed. Finally, it highlights the existing challenges and potential opportunities for ECNFAs to achieve superior properties and realize promising prospects.


Highlights:
1 This review provides comprehensive fabrication methods for the manufacturing of electrospun ceramic nanofibrous aerogels and offers professional guidance for materials development in this field.
2 The optimization strategies for electrospun ceramic nanofibrous aerogels (ECNFAs)’ mechanical properties have been provided, highlighting multi-scale design from nano-building blocks to nanofiber aggregate structure design.
3 This review systematically introduces the diverse roles of ECNFAs in specific application scenarios and application-specific mechanisms and provides transformative solutions for advanced engineering applications.

Keywords

Electrospinning nanofibers Ceramic aerogels Mechanical properties
Li, Panpan, Xuan Zhang, Ying Li, Cunyi Zhao, Jianyong Yu, and Yang Si. 2025. “Electrospun Nanofiber-Based Ceramic Aerogels: Synergistic Strategies for Design and Functionalization”. Nano-Micro Letters 18 (August):23. https://doi.org/10.1007/s40820-025-01864-4.
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References
  1. X. Chang, X. Cheng, H. Zhang, W. Li, L. He et al., Superelastic carbon aerogels: an emerging material for advanced thermal protection in extreme environments. Adv. Funct. Mater. 33(26), 2215168 (2023). https://doi.org/10.1002/adfm.202215168
  2. S.S. Kistler, Coherent expanded aerogels and jellies. Nature 127(3211), 741 (1931). https://doi.org/10.1038/127741a0
  3. X. Xu, Q. Zhang, M. Hao, Y. Hu, Z. Lin et al., Double-negative-index ceramic aerogels for thermal superinsulation. Science 363(6428), 723–727 (2019). https://doi.org/10.1126/science.aav7304
  4. X. Cheng, X. Chang, F. Wu, Y. Liao, K. Pan et al., Advanced nanofabrication for elastic inorganic aerogels. Nano Res. 17(10), 8842–8862 (2024). https://doi.org/10.1007/s12274-023-6369-4
  5. X. Hou, J. Chen, Z. Chen, D. Yu, S. Zhu et al., Flexible aerogel materials: a review on revolutionary flexibility strategies and the multifunctional applications. ACS Nano 18(18), 11525–11559 (2024). https://doi.org/10.1021/acsnano.4c00347
  6. Y. Si, J. Yu, X. Tang, J. Ge, B. Ding, Ultralight nanofibre-assembled cellular aerogels with superelasticity and multifunctionality. Nat. Commun. 5, 5802 (2014). https://doi.org/10.1038/ncomms6802
  7. N. Méndez-Lozano, R. Velázquez-Castillo, E.M. Rivera-Muñoz, L. Bucio-Galindo, G. Mondragón-Galicia et al., Crystal growth and structural analysis of hydroxyapatite nanofibers synthesized by the hydrothermal microwave-assisted method. Ceram. Int. 43(1), 451–457 (2017). https://doi.org/10.1016/j.ceramint.2016.09.179
  8. M. Boufas, O. Guellati, A. Harat, D. Momodu, J. Dangbegnon et al., Optical and electrochemical properties of iron oxide and hydroxide nanofibers synthesized using new template-free hydrothermal method. J. Nanostruct. Chem. 10(4), 275–288 (2020). https://doi.org/10.1007/s40097-020-00348-8
  9. M.W. Boey, S.A. Khan, X. Li, J. Sun, M.U. Farid et al., Thermally efficient hydrophobic zirconia ceramic nanofiber membrane for enhanced membrane distillation performance. Chem. Eng. J. 512, 162582 (2025). https://doi.org/10.1016/j.cej.2025.162582
  10. M. Dilamian, M. Joghataei, Z. Ashrafi, C. Bohr, S. Mathur et al., From 1D electrospun nanofibers to advanced multifunctional fibrous 3D aerogels. Appl. Mater. Today 22, 100964 (2021). https://doi.org/10.1016/j.apmt.2021.100964
  11. S. Ramakrishna, K. Fujihara, W.-E. Teo, T. Yong, Z. Ma et al., Electrospun nanofibers: solving global issues. Mater. Today 9(3), 40–50 (2006). https://doi.org/10.1016/S1369-7021(06)71389-X
  12. J.-H. Kim, J.-H. Kim, J.-M. Kim, Y.-G. Lee, S.-Y. Lee, Superlattice crystals–mimic, flexible/functional ceramic membranes: beyond polymeric battery separators. Adv. Energy Mater. 5(24), 1500954 (2015). https://doi.org/10.1002/aenm.201500954
  13. Y. Jeon, J.-H. Myung, S.-H. Hyun, Y.-G. Shul, J.T.S. Irvine, Corn-cob like nanofibres as cathode catalysts for an effective microstructure design in solid oxide fuel cells. J. Mater. Chem. A 5(8), 3966–3973 (2017). https://doi.org/10.1039/C6TA08692F
  14. H. Wang, X. Zhang, N. Wang, Y. Li, X. Feng et al., Ultralight, scalable, and high-temperature-resilient ceramic nanofiber sponges. Sci. Adv. 3(6), e1603170 (2017). https://doi.org/10.1126/sciadv.1603170
  15. C. Jia, L. Li, Y. Liu, B. Fang, H. Ding et al., Highly compressible and anisotropic lamellar ceramic sponges with superior thermal insulation and acoustic absorption performances. Nat. Commun. 11(1), 3732 (2020). https://doi.org/10.1038/s41467-020-17533-6
  16. H. Wang, S. Lin, S. Yang, X. Yang, J. Song et al., High-temperature particulate matter filtration with resilient yttria-stabilized ZrO2 nanofiber sponge. Small 14(19), e1800258 (2018). https://doi.org/10.1002/smll.201800258
  17. J.L. Daristotle, A.M. Behrens, A.D. Sandler, P. Kofinas, A review of the fundamental principles and applications of solution blow spinning. ACS Appl. Mater. Interfaces 8(51), 34951–34963 (2016). https://doi.org/10.1021/acsami.6b12994
  18. Y. Gao, J. Zhang, Y. Su, H. Wang, X.-X. Wang et al., Recent progress and challenges in solution blow spinning. Mater. Horiz. 8(2), 426–446 (2021). https://doi.org/10.1039/d0mh01096k
  19. E.S. Medeiros, G.M. Glenn, A.P. Klamczynski, W.J. Orts, L.H.C. Mattoso, Solution blow spinning: a new method to produce micro- and nanofibers from polymer solutions. J. Appl. Polym. Sci. 113(4), 2322–2330 (2009). https://doi.org/10.1002/app.30275
  20. M.F. Mota, A.M.C. Santos, R.M.C. Farias, G.A. Neves, R.R. Menezes, Synthesis and characterization of alumina fibers using solution blow spinning. Cerâmica 65(374), 190–193 (2019). https://doi.org/10.1590/0366-69132019653742618
  21. M.B. Ferreira Junior, D.A.D. Chaves, M.J. Van Bael, M. Motta, W.A. Ortiz et al., YBCO nanofibers produced by solution blow spinning doped with Ni and Zn at low concentrations. Supercond. Sci. Technol. 38(4), 045014 (2025). https://doi.org/10.1088/1361-6668/adc0c6
  22. M. Rotta, L. Zadorosny, C.L. Carvalho, J.A. Malmonge, L.F. Malmonge et al., YBCO ceramic nanofibers obtained by the new technique of solution blow spinning. Ceram. Int. 42(14), 16230–16234 (2016). https://doi.org/10.1016/j.ceramint.2016.07.152
  23. D.L. Costa, R. Santos Leite, G.A. Neves, L.N. de Lima Santana, E.S. Medeiros et al., Synthesis of TiO2 and ZnO nano and submicrometric fibers by solution blow spinning. Mater. Lett. 183, 109–113 (2016). https://doi.org/10.1016/j.matlet.2016.07.073
  24. J. Carriles, P. Nguewa, G. González-Gaitano, Advances in biomedical applications of solution blow spinning. Int. J. Mol. Sci. 24(19), 14757 (2023). https://doi.org/10.3390/ijms241914757
  25. T.S. Natarajan, P. Bhargava, Influence of spinning parameters on synthesis of alumina fibres by centrifugal spinning. Ceram. Int. 44(10), 11644–11649 (2018). https://doi.org/10.1016/j.ceramint.2018.03.239
  26. L. Ren, R. Ozisik, S.P. Kotha, Rapid and efficient fabrication of multilevel structured silica micro-/ nanofibers by centrifugal jet spinning. J. Colloid Interface Sci. 425, 136–142 (2014). https://doi.org/10.1016/j.jcis.2014.03.039
  27. H. Aminirastabi, Z. Weng, H. Xue, Y. Yu, G. Ji et al., Evaluation of nano grain growth of TiO2 fibers fabricated via centrifugal jet spinning. Nano Struct. Nano Objects 21, 100413 (2020). https://doi.org/10.1016/j.nanoso.2019.100413
  28. M. Wang, J. Chen, Z. Ahmad, X. Li, F. Chen, High-temperature resistance and thermal insulation performance of continuous SiMOC ceramic fibers fabricated by the modified Sol-gel method combined with dry spinning. J. Sol Gel Sci. Technol. 113(2), 427–437 (2025). https://doi.org/10.1007/s10971-024-06628-x
  29. H. Scholz, J. Vetter, R. Herborn, A. Ruedinger, Oxide ceramic fibers via dry spinning process: From lab to fab. Int. J. Appl. Ceram. Technol. 17(4), 1636–1645 (2020). https://doi.org/10.1111/ijac.13521
  30. C. Liu, S. Wang, N. Wang, J. Yu, Y.-T. Liu et al., From 1D nanofibers to 3D nanofibrous aerogels: a marvellous evolution of electrospun SiO2 nanofibers for emerging applications. Nano-Micro Lett. 14(1), 194 (2022). https://doi.org/10.1007/s40820-022-00937-y
  31. J. Xue, T. Wu, Y. Dai, Y. Xia, Electrospinning and electrospun nanofibers: methods, materials, and applications. Chem. Rev. 119(8), 5298–5415 (2019). https://doi.org/10.1021/acs.chemrev.8b00593
  32. M. Zhang, Y. Wang, Y. Zhang, J. Song, Y. Si et al., Conductive and elastic TiO2 nanofibrous aerogels: a new concept toward self-supported electrocatalysts with superior activity and durability. Angew. Chem. Int. Ed. 59(51), 23252–23260 (2020). https://doi.org/10.1002/anie.202010110
  33. M. Liu, M. Shafiq, B. Sun, J. Wu, W. Wang et al., Composite superelastic aerogel scaffolds containing flexible SiO2 nanofibers promote bone regeneration. Adv. Healthc. Mater. 11(15), e2200499 (2022). https://doi.org/10.1002/adhm.202200499
  34. H. Zhang, Y. Hang, Y. Qin, J. Yang, B. Wang, Synthesis and characterization of Sol–gel derived continuous spinning alumina based fibers with silica nano-powders. J. Eur. Ceram. Soc. 34(2), 465–473 (2014). https://doi.org/10.1016/j.jeurceramsoc.2013.08.015
  35. J.-H. Kim, S.-J. Yoo, D.-H. Kwak, H.-J. Jung, T.-Y. Kim et al., Characterization and application of electrospun alumina nanofibers. Nanoscale Res. Lett. 9(1), 44 (2014). https://doi.org/10.1186/1556-276X-9-44
  36. Y. Hou, L. Cheng, Y. Zhang, Y. Yang, C. Deng et al., SiC nanofiber mat: a broad-band microwave absorber, and the alignment effect. ACS Appl. Mater. Interfaces 9(49), 43072–43080 (2017). https://doi.org/10.1021/acsami.7b13634
  37. Y. Sun, J.Y. Li, Y. Tan, L. Zhang, Fabrication of aluminum nitride (AlN) hollow fibers by carbothermal reduction and nitridation of electrospun precursor fibers. J. Alloys Compd. 471(1–2), 400–403 (2009). https://doi.org/10.1016/j.jallcom.2008.03.099
  38. Y. Qiu, J. Yu, J. Rafique, J. Yin, X. Bai et al., Large-scale production of aligned long boron nitride nanofibers by multijet/multicollector electrospinning. J. Phys. Chem. C 113(26), 11228–11234 (2009). https://doi.org/10.1021/jp901267k
  39. F. Rechberger, M. Niederberger, Synthesis of aerogels: from molecular routes to 3-dimensional nanop assembly. Nanoscale Horiz. 2(1), 6–30 (2017). https://doi.org/10.1039/c6nh00077k
  40. W. Su, Z. Chang, Y. E, Y. Feng, X. Yao et al., Electrospinning and electrospun polysaccharide-based nanofiber membranes: a review. Int. J. Biol. Macromol. 263(pt 2), 130335 (2024). https://doi.org/10.1016/j.ijbiomac.2024.130335
  41. W. Matysiak, T. Tański, Analysis of the morphology, structure and optical properties of 1D SiO2 nanostructures obtained with Sol-gel and electrospinning methods. Appl. Surf. Sci. 489, 34–43 (2019). https://doi.org/10.1016/j.apsusc.2019.05.090
  42. M. Yanilmaz, Y. Lu, J. Zhu, X. Zhang, Silica/polyacrylonitrile hybrid nanofiber membrane separators via Sol-gel and electrospinning techniques for lithium-ion batteries. J. Power. Sources 313, 205–212 (2016). https://doi.org/10.1016/j.jpowsour.2016.02.089
  43. S. Khalili, H.M. Chenari, Successful electrospinning fabrication of ZrO2 nanofibers: a detailed physical–chemical characterization study. J. Alloys Compd. 828, 154414 (2020). https://doi.org/10.1016/j.jallcom.2020.154414
  44. S. Chattopadhyay, S. Bysakh, J. Saha, G. De, Electrospun ZrO2 nanofibers: precursor controlled mesopore ordering and evolution of garland-like nanocrystal arrays. Dalton Trans. 47(16), 5789–5800 (2018). https://doi.org/10.1039/c8dt00415c
  45. V. Bhullar, S. Sardana, A. Mahajan, Size modeling of TiO2 nanofibers for efficient TiO2 sensitized mesoscopic solar cells. Sol. Energy 230, 177–185 (2021). https://doi.org/10.1016/j.solener.2021.10.023
  46. J.-H. Kim, J.-H. Lee, J.-Y. Kim, S.S. Kim, Synthesis of aligned TiO2 nanofibers using electrospinning. Appl. Sci. 8(2), 309 (2018). https://doi.org/10.3390/app8020309
  47. I.I. Maor, S. Heyte, O. Elishav, M. Mann-Lahav, J. Thuriot-Roukos et al., Performance of Cu/ZnO nanosheets on electrospun Al2O3 nanofibers in CO2 catalytic hydrogenation to methanol and dimethyl ether. Nanomaterials 13(4), 635 (2023). https://doi.org/10.3390/nano13040635
  48. M. Mohammad Ali Zadeh, M. Keyanpour-Rad, T. Ebadzadeh, Synthesis of mullite nanofibres by electrospinning of solutions containing different proportions of polyvinyl butyral. Ceram. Int. 39(8), 9079–9084 (2013). https://doi.org/10.1016/j.ceramint.2013.05.003
  49. Y. Peng, Y. Xie, L. Wang, L. Liu, S. Zhu et al., High-temperature flexible, strength and hydrophobic YSZ/SiO2 nanofibrous membranes with excellent thermal insulation. J. Eur. Ceram. Soc. 41(2), 1471–1480 (2021). https://doi.org/10.1016/j.jeurceramsoc.2020.09.071
  50. S. Li, F. Wu, X. Zhang, G. Han, Y. Si et al., Flexible Al2O3/ZrO2 nanofibrous membranes for thermal insulation. CrystEngComm 24(10), 1859–1865 (2022). https://doi.org/10.1039/d1ce01512e
  51. S. Yajima, K. Okamura, J. Hayashi, M. Omori, Synthesis of continuous sic fibers with high tensile strength. J. Am. Ceram. Soc. 59(7–8), 324–327 (1976). https://doi.org/10.1111/j.1151-2916.1976.tb10975.x
  52. B.M. Eick, J.P. Youngblood, SiC nanofibers by pyrolysis of electrospun preceramic polymers. J. Mater. Sci. 44(1), 160–165 (2009). https://doi.org/10.1007/s10853-008-3102-3
  53. X. Zhang, J. Yu, C. Zhao, Y. Si, Engineering covalent heterointerface enables superelastic amorphous SiC meta-aerogels. ACS Nano 17(21), 21813–21821 (2023). https://doi.org/10.1021/acsnano.3c07780
  54. H. Ramlow, G.B. de Souza, M.P. Fonseca, A. Raizer, C.R. Rambo et al., Lightweight and flexible nanostructured C/SiCN nanofiber nonwoven for electromagnetic reflection shielding of 5G C-Band frequencies. J. Mater. Sci. Mater. Electron. 34(22), 1631 (2023). https://doi.org/10.1007/s10854-023-11037-x
  55. X. Guo, F. Xiao, J. Li, H. Zhang, Q. Hu et al., Fe-doped SiCN composite fibers for electromagnetic waves absorption. Ceram. Int. 47(1), 1184–1190 (2021). https://doi.org/10.1016/j.ceramint.2020.08.236
  56. Q. Chen, D. Jia, B. Liang, Z. Yang, Y. Zhou et al., Electrospinning of pure polymer-derived SiBCN nanofibers with high yield. Ceram. Int. 47(8), 10958–10964 (2021). https://doi.org/10.1016/j.ceramint.2020.12.215
  57. Q. Ding, J. Yang, S. Gu, C. Chen, Z. Cheng et al., Novel fire-resistant SiBCN fiber paper with efficient electromagnetic interference shielding and Joule-heating performance. Chem. Eng. J. 497, 154485 (2024). https://doi.org/10.1016/j.cej.2024.154485
  58. H.J. Hwang, N.A.M. Barakat, M.A. Kanjwal, F.A. Sheikh, H.Y. Kim et al., Boron nitride nanofibers by the electrospinning technique. Macromol. Res. 18(6), 551–557 (2010). https://doi.org/10.1007/s13233-010-0601-2
  59. Y.S. Nam, X.M. Cui, L. Jeong, J.Y. Lee, W.H. Park, Fabrication and characterization of zirconium carbide (ZrC) nanofibers with thermal storage property. Thin Solid Films 517(24), 6531–6538 (2009). https://doi.org/10.1016/j.tsf.2009.04.021
  60. K. Nakane, S. Matsuoka, S. Gao, S. Yonezawa, J.H. Kim et al., Formation of inorganic nanofibers by heat-treatment of poly(vinyl alcohol)-zirconium compound hybrid nanofibers. J. Min. Metall. Sect. B Metall. 49(1), 77–82 (2013). https://doi.org/10.2298/jmmb121101027n
  61. V. Rahmanian, T. Pirzada, E. Barbieri, S. Iftikhar, F. Li et al., Mechanically robust, thermally insulating and photo-responsive aerogels designed from Sol-gel electrospun PVP-TiO2 nanofibers. Appl. Mater. Today 32, 101784 (2023). https://doi.org/10.1016/j.apmt.2023.101784
  62. R. Liu, X. Dong, S. Xie, T. Jia, Y. Xue et al., Ultralight, thermal insulating, and high-temperature-resistant mullite-based nanofibrous aerogels. Chem. Eng. J. 360, 464–472 (2019). https://doi.org/10.1016/j.cej.2018.12.018
  63. Y.-T. Liu, B. Ding, Ultralight and superelastic ceramic nanofibrous aerogels: a new vision of an ancient material. Sci. Bull. 68(8), 753–755 (2023). https://doi.org/10.1016/j.scib.2023.03.039
  64. L. Dou, X. Zhang, H. Shan, X. Cheng, Y. Si et al., Interweaved cellular structured ceramic nanofibrous aerogels with superior bendability and compressibility. Adv. Funct. Mater. 30(49), 2005928 (2020). https://doi.org/10.1002/adfm.202005928
  65. Y. Si, X. Wang, L. Dou, J. Yu, B. Ding, Ultralight and fire-resistant ceramic nanofibrous aerogels with temperature-invariant superelasticity. Sci. Adv. 4(4), eaas8925 (2018). https://doi.org/10.1126/sciadv.aas8925
  66. W. Li, F. He, H. Liu, Y. Jiang, Y. Mu et al., Electric field-induced ordered-structural aerogels enable superinsulation and multifunctionality. Small 20(51), e2406188 (2024). https://doi.org/10.1002/smll.202406188
  67. F. Wu, S. Qiang, X.-D. Zhu, W. Jiao, L. Liu et al., Fibrous MXene aerogels with tunable pore structures for high-efficiency desalination of contaminated seawater. Nano-Micro Lett. 15(1), 71 (2023). https://doi.org/10.1007/s40820-023-01030-8
  68. X. Zhang, F. Wang, L. Dou, X. Cheng, Y. Si et al., Ultrastrong, superelastic, and lamellar multiarch structured ZrO2-Al2O3 nanofibrous aerogels with high-temperature resistance over 1300 ℃. ACS Nano 14(11), 15616–15625 (2020). https://doi.org/10.1021/acsnano.0c06423
  69. X. Zhang, X. Cheng, Y. Si, J. Yu, B. Ding, All-ceramic and elastic aerogels with nanofibrous-granular binary synergistic structure for thermal superinsulation. ACS Nano 16(4), 5487–5495 (2022). https://doi.org/10.1021/acsnano.1c09668
  70. P. Zhao, M. Cao, H. Gu, Q. Gao, N. Xia et al., Research on the electrospun foaming process to fabricate three-dimensional tissue engineering scaffolds. J. Appl. Polym. Sci. 135(46), 46898 (2018). https://doi.org/10.1002/app.46898
  71. Q. Gao, H. Gu, P. Zhao, C. Zhang, M. Cao et al., Fabrication of electrospun nanofibrous scaffolds with 3D controllable geometric shapes. Mater. Des. 157, 159–169 (2018). https://doi.org/10.1016/j.matdes.2018.07.042
  72. S.W. Ko, J. Lee, J.Y. Lee, J.H. Cho, S. Lee et al., Composite demineralized bone matrix nanofiber scaffolds with hierarchical interconnected networks via eruptive inorganic catalytic decomposition for osteoporotic bone regeneration. J. Mater. Sci. Technol. 199, 246–259 (2024). https://doi.org/10.1016/j.jmst.2024.02.018
  73. D. Zong, W. Bai, M. Geng, X. Yin, J. Yu et al., Bubble templated flexible ceramic nanofiber aerogels with cascaded resonant cavities for high-temperature noise absorption. ACS Nano 16(9), 13740–13749 (2022). https://doi.org/10.1021/acsnano.2c06011
  74. Y. Wang, H. Huang, Y. Zhao, Z. Feng, H. Fan et al., Self-assembly of ultralight and compressible inorganic sponges with hierarchical porosity by electrospinning. Ceram. Int. 46(1), 768–774 (2020). https://doi.org/10.1016/j.ceramint.2019.09.031
  75. M.H. Tai, B.Y.L. Tan, J. Juay, D.D. Sun, J.O. Leckie, A self-assembled superhydrophobic electrospun carbon–silica nanofiber sponge for selective removal and recovery of oils and organic solvents. Chem. 21(14), 5395–5402 (2015). https://doi.org/10.1002/chem.201405670
  76. M. Yousefzadeh, M. Latifi, M. Amani-Tehran, W.-E. Teo, S. Ramakrishna, A note on the 3D structural design of electrospun nanofibers. J. Eng. Fibres. Fabr. 7(2), 155892501200700200 (2012). https://doi.org/10.1177/155892501200700204
  77. J. Guo, S. Fu, Y. Deng, X. Xu, S. Laima et al., Hypocrystalline ceramic aerogels for thermal insulation at extreme conditions. Nature 606(7916), 909–916 (2022). https://doi.org/10.1038/s41586-022-04784-0
  78. W. Cheng, W. Jiao, Y. Fei, Z. Yang, X. Zhang et al., Direct synthesis of ultralight, elastic, high-temperature insulation N-doped TiO2 ceramic nanofibrous sponges via conjugate electrospinning. Nanoscale 16(3), 1135–1146 (2024). https://doi.org/10.1039/D3NR04987F
  79. X. Cheng, Y.-T. Liu, Y. Si, J. Yu, B. Ding, Direct synthesis of highly stretchable ceramic nanofibrous aerogels via 3D reaction electrospinning. Nat. Commun. 13(1), 2637 (2022). https://doi.org/10.1038/s41467-022-30435-z
  80. X. Cheng, X. Chang, X. Zhang, J. Dai, H. Fong et al., Way to a library of Ti-series oxide nanofiber sponges that are highly stretchable, compressible, and bendable. Adv. Mater. 36(14), 2307690 (2024). https://doi.org/10.1002/adma.202307690
  81. J. Dong, Y. Xie, L. Liu, Z. Deng, W. Liu et al., Lightweight and resilient ZrO2–TiO2 fiber sponges with layered structure for thermal insulation. Adv. Eng. Mater. 24(8), 2101603 (2022). https://doi.org/10.1002/adem.202101603
  82. J.T. Cahill, S. Turner, J. Ye, B. Shevitski, S. Aloni et al., Ultrahigh-temperature ceramic aerogels. Chem. Mater. 31(10), 3700–3704 (2019). https://doi.org/10.1021/acs.chemmater.9b00496
  83. C. Ziegler, A. Wolf, W. Liu, A.-K. Herrmann, N. Gaponik et al., Modern inorganic aerogels. Angew. Chem. Int. Ed. 56(43), 13200–13221 (2017). https://doi.org/10.1002/anie.201611552
  84. X. Xu, S. Fu, J. Guo, H. Li, Y. Huang et al., Elastic ceramic aerogels for thermal superinsulation under extreme conditions. Mater. Today 42, 162–177 (2021). https://doi.org/10.1016/j.mattod.2020.09.034
  85. H. Shan, X. Wang, F. Shi, J. Yan, J. Yu et al., Hierarchical porous structured SiO2/SnO2 nanofibrous membrane with superb flexibility for molecular filtration. ACS Appl. Mater. Interfaces 9(22), 18966–18976 (2017). https://doi.org/10.1021/acsami.7b04518
  86. F. Wu, Y. Liu, Y. Si, J. Yu, B. Ding, Multiphase ceramic nanofibers with super-elasticity from − 196–1600 ℃. Nano Today 44, 101455 (2022). https://doi.org/10.1016/j.nantod.2022.101455
  87. H. Liu, X. Huo, P. Zhao, R. Xu, X. Zhang et al., Confined gelation synthesis of flexible barium aluminate nanofibers as a high-performance refractory material. ACS Nano 18(42), 29273–29281 (2024). https://doi.org/10.1021/acsnano.4c11854
  88. Z. Li, M.K. Joshi, J. Chen, Z. Zhang, Z. Li et al., Mechanically compatible UV photodetectors based on electrospun free-standing Y3+-doped TiO2 nanofibrous membranes with enhanced flexibility. Adv. Funct. Mater. 30(52), 2005291 (2020). https://doi.org/10.1002/adfm.202005291
  89. X. Wang, Y. Zhang, Y. Zhao, G. Li, J. Yan et al., A general strategy to fabricate flexible oxide ceramic nanofibers with gradient bending-resilience properties. Adv. Funct. Mater. 31(36), 2103989 (2021). https://doi.org/10.1002/adfm.202103989
  90. N. Wu, B. Wang, Y. Wang, Enhanced mechanical properties of amorphous SiOC nanofibrous membrane through in situ embedding nanops. J. Am. Ceram. Soc. 101(10), 4763–4772 (2018). https://doi.org/10.1111/jace.15732
  91. Y. Zhang, S. Liu, J. Yan, X. Zhang, S. Xia et al., Superior flexibility in oxide ceramic crystal nanofibers. Adv. Mater. 33(44), 2105011 (2021). https://doi.org/10.1002/adma.202105011
  92. X. Mao, L. Zhao, K. Zhang, Y.-Y. Wang, B. Ding, Highly flexible ceramic nanofibrous membranes for superior thermal insulation and fire retardancy. Nano Res. 15(3), 2592–2598 (2022). https://doi.org/10.1007/s12274-021-3799-8
  93. C. Liu, Y. Liao, W. Jiao, X. Zhang, N. Wang et al., High toughness combined with high strength in oxide ceramic nanofibers. Adv. Mater. 35(32), 2304401 (2023). https://doi.org/10.1002/adma.202304401
  94. Z. Xu, H. Liu, F. Wu, L. Cheng, J. Yu et al., Inhibited grain growth through phase transition modulation enables excellent mechanical properties in oxide ceramic nanofibers up to 1700 ℃. Adv. Mater. 35(44), 2305336 (2023). https://doi.org/10.1002/adma.202305336
  95. Z. Xu, Y. Liu, Q. Xin, J. Dai, J. Yu et al., Ceramic meta-aerogel with thermal superinsulation up to 1700 ℃ constructed by self-crosslinked nanofibrous network via reaction electrospinning. Adv. Mater. 36(32), 2401299 (2024). https://doi.org/10.1002/adma.202401299
  96. G. Poologasundarampillai, D. Wang, S. Li, J. Nakamura, R. Bradley et al., Cotton-wool-like bioactive glasses for bone regeneration. Acta Biomater. 10(8), 3733–3746 (2014). https://doi.org/10.1016/j.actbio.2014.05.020
  97. D. Zong, X. Yin, J. Yu, W. Jiao, S. Zhang et al., Heat-conducting elastic ultrafine fiber sponges with boron nitride networks for noise reduction. J. Colloid Interface Sci. 649, 1023–1030 (2023). https://doi.org/10.1016/j.jcis.2023.05.209
  98. L. Xu, L. Huang, J. Yu, Y. Si, B. Ding, Ultralight and superelastic Gd2O3/Bi2O3 nanofibrous aerogels with nacre-mimetic brick-mortar structure for superior X-ray shielding. Nano Lett. 22(21), 8711–8718 (2022). https://doi.org/10.1021/acs.nanolett.2c03484
  99. H. Liu, X. Zhang, Y. Liao, J. Yu, Y.-T. Liu et al., Building-envelope-inspired, thermomechanically robust all-fiber ceramic meta-aerogel for temperature-controlled dominant infrared camouflage. Adv. Mater. 36(25), e2313720 (2024). https://doi.org/10.1002/adma.202313720
  100. Y. Wang, W. Xu, X. Zou, W. Fu, X. Meng et al., MXene-decorated flexible Al2O3/TiO2 nanofibrous mats with self-adaptive stress dispersion towards multifunctional desalination. J. Mater. Chem. A 11(14), 7422–7431 (2023). https://doi.org/10.1039/D2TA09488F
  101. D. Zong, L. Cao, X. Yin, Y. Si, S. Zhang et al., Flexible ceramic nanofibrous sponges with hierarchically entangled graphene networks enable noise absorption. Nat. Commun. 12(1), 6599 (2021). https://doi.org/10.1038/s41467-021-26890-9
  102. H. Zheng, H. Shan, Y. Bai, X. Wang, L. Liu et al., Assembly of silica aerogels within silica nanofibers: towards a super-insulating flexible hybrid aerogel membrane. RSC Adv. 5(111), 91813–91820 (2015). https://doi.org/10.1039/C5RA18137B
  103. S. Dang, J. Guo, Y. Deng, H. Yu, H. Zhao et al., Highly-buckled nanofibrous ceramic aerogels with ultra-large stretchability and tensile-insensitive thermal insulation. Adv. Mater. 37(4), 2415159 (2025). https://doi.org/10.1002/adma.202415159
  104. X. Zhang, J. Yu, Y. Si, Programmable shape-morphing enables ceramic meta-aerogel highly stretchable for thermal protection. Adv. Mater. 37(3), e2412962 (2025). https://doi.org/10.1002/adma.202412962
  105. H. Wang, L. Cheng, J. Yu, Y. Si, B. Ding, Biomimetic Bouligand chiral fibers array enables strong and superelastic ceramic aerogels. Nat. Commun. 15(1), 336 (2024). https://doi.org/10.1038/s41467-023-44657-2
  106. X. Zhang, J. Yu, C. Zhao, Y. Si, Elastic SiC aerogel for thermal insulation: a systematic review. Small 20(32), e2311464 (2024). https://doi.org/10.1002/smll.202311464
  107. B. Wicklein, A. Kocjan, G. Salazar-Alvarez, F. Carosio, G. Camino et al., Thermally insulating and fire-retardant lightweight anisotropic foams based on nanocellulose and graphene oxide. Nat. Nanotechnol. 10(3), 277–283 (2015). https://doi.org/10.1038/nnano.2014.248
  108. G.H. Tang, C. Bi, Y. Zhao, W.Q. Tao, Thermal transport in nano-porous insulation of aerogel: Factors, models and outlook. Energy 90, 701–721 (2015). https://doi.org/10.1016/j.energy.2015.07.109
  109. Y. Fu, J. Hansson, Y. Liu, S. Chen, A. Zehri et al., Graphene related materials for thermal management. 2D Mater. 7(1), 012001 (2020). https://doi.org/10.1088/2053-1583/ab48d9
  110. C.J.C. Otic, S. Yonemura, Thermally induced Knudsen forces for contactless manipulation of a micro-object. Micromachines 13(7), 1092 (2022). https://doi.org/10.3390/mi13071092
  111. X. Zhao, A.H. Brozena, L. Hu, Critical roles of pores and moisture in sustainable nanocellulose-based super-thermal insulators. Matter 4(3), 769–772 (2021). https://doi.org/10.1016/j.matt.2021.02.002
  112. L. Dou, X. Cheng, X. Zhang, Y. Si, J. Yu et al., Temperature-invariant superelastic, fatigue resistant, and binary-network structured silica nanofibrous aerogels for thermal superinsulation. J. Mater. Chem. A 8(16), 7775–7783 (2020). https://doi.org/10.1039/d0ta01092h
  113. L. Dou, X. Zhang, X. Cheng, Z. Ma, X. Wang et al., Hierarchical cellular structured ceramic nanofibrous aerogels with temperature-invariant superelasticity for thermal insulation. ACS Appl. Mater. Interfaces 11(32), 29056–29064 (2019). https://doi.org/10.1021/acsami.9b10018
  114. J. Liu, H. Li, H. Li, W. Song, S. Xia et al., Deep-sea glass sponges-like hollow porous ceramic fiber aerogel: Fabrication, anti-shrinkage and thermal insulation. Ceram. Int. 50(20), 37714–37725 (2024). https://doi.org/10.1016/j.ceramint.2024.07.132
  115. Y. Dong, X. Dong, L. Li, J. Wu, L. Yan et al., Lightweight and thermally insulating aluminum borate nanofibrous porous ceramics. Ceram. Int. 47(15), 21029–21037 (2021). https://doi.org/10.1016/j.ceramint.2021.04.104
  116. X. Meng, C. Liu, J. Zhang, W. Guo, N. Li et al., Thermal-insulating ceramic fiber aerogels reinforced by fusing knots of overlapping fibers for superelasticity and high compression resistance. J. Mater. Chem. A 12(26), 16079–16086 (2024). https://doi.org/10.1039/D4TA02257B
  117. S. Dong, B. Maciejewska, R. Millar, N. Grobert, 3D Electrospinning of Al2O3/ZrO2 fibrous aerogels for multipurpose thermal insulation. Adv. Compos. Hybrid Mater. 6(5), 186 (2023). https://doi.org/10.1007/s42114-023-00760-y
  118. L. Li, C. Jia, Y. Liu, B. Fang, W. Zhu et al., Nanograin–glass dual-phasic, elasto-flexible, fatigue-tolerant, and heat-insulating ceramic sponges at large scales. Mater. Today 54, 72–82 (2022). https://doi.org/10.1016/j.mattod.2022.02.007
  119. L. Dou, Y. Si, J. Yu, B. Ding, Semi-template based, biomimetic-architectured, and mechanically robust ceramic nanofibrous aerogels for thermal insulation. Nano Res. 15(6), 5581–5589 (2022). https://doi.org/10.1007/s12274-022-4194-9
  120. Y. Cheng, B. Ma, P. Hu, J. Zhang, D. Hu et al., Flexible and transformable ceramic aerogels via a fire-reborn strategy for thermal superinsulation in extreme conditions. Adv. Funct. Mater. 33(52), 2309148 (2023). https://doi.org/10.1002/adfm.202309148
  121. Y. Zhong, H. Li, H. Liu, J. Wang, X. Han et al., Elytra-mimetic ceramic fiber aerogel with excellent mechanical, anti-oxidation, and thermal insulation properties. J. Eur. Ceram. Soc. 43(4), 1407–1416 (2023). https://doi.org/10.1016/j.jeurceramsoc.2022.11.061
  122. P.-E. Okafor, C. He, G. Tang, Finite-difference time-domain study of hollow Zirconium dioxide nanofibrous aerogel composite for thermal insulation under harsh environments. Int. J. Therm. Sci. 194, 108599 (2023). https://doi.org/10.1016/j.ijthermalsci.2023.108599
  123. S. Fu, D. Liu, Y. Deng, M. Li, H. Zhao et al., Medium-entropy ceramic aerogels for robust thermal sealing. J. Mater. Chem. A 11(2), 742–752 (2023). https://doi.org/10.1039/d2ta08264k
  124. X. Wang, H. Li, H. Li, Z. Cui, J. Wang et al., Coaxial porous SiBCN/SiCN ceramic fiber aerogels with reduced shrinkage and low thermal conductivity. Chem. Eng. J. 501, 157621 (2024). https://doi.org/10.1016/j.cej.2024.157621
  125. W. Wang, Q. You, Z. Wu, S. Cui, W. Shen, Fabrication of the SiC/HfC composite aerogel with ultra-low thermal conductivity and excellent compressive strength. Gels 10(5), 292 (2024). https://doi.org/10.3390/gels10050292
  126. Z. Xu, K. Zhao, F. Li, S. Zhang, X. Zhao et al., High temperature thermal insulation ceramic aerogels fabricated from ZrC nanofibers welded with carbon nanops. ACS Appl. Nano Mater. 7(9), 10046–10055 (2024). https://doi.org/10.1021/acsanm.4c00280
  127. F. Liu, Y. Jiang, F. Peng, J. Feng, L. Li et al., Fiber-reinforced alumina-carbon core-shell aerogel composite with heat-induced gradient structure for thermal protection up to 1800 ℃. Chem. Eng. J. 461, 141721 (2023). https://doi.org/10.1016/j.cej.2023.141721
  128. X. Chang, Y. Yang, X. Cheng, X. Yin, J. Yu et al., Multiphase symbiotic engineered elastic ceramic-carbon aerogels with advanced thermal protection in extreme oxidative environments. Adv. Mater. 36(32), 2406055 (2024). https://doi.org/10.1002/adma.202406055
  129. S. Zeng, S. Pian, M. Su, Z. Wang, M. Wu et al., Hierarchical-morphology metafabric for scalable passive daytime radiative cooling. Science 373(6555), 692–696 (2021). https://doi.org/10.1126/science.abi5484
  130. Z. Chen, L. Zhu, A. Raman, S. Fan, Radiative cooling to deep sub-freezing temperatures through a 24-h day-night cycle. Nat. Commun. 7, 13729 (2016). https://doi.org/10.1038/ncomms13729
  131. T.M.J. Nilsson, G.A. Niklasson, Radiative cooling during the day: simulations and experiments on pigmented polyethylene cover foils. Sol. Energy Mater. Sol. Cells 37(1), 93–118 (1995). https://doi.org/10.1016/0927-0248(94)00200-2
  132. A.P. Raman, M.A. Anoma, L. Zhu, E. Rephaeli, S. Fan, Passive radiative cooling below ambient air temperature under direct sunlight. Nature 515(7528), 540–544 (2014). https://doi.org/10.1038/nature13883
  133. E. Rephaeli, A. Raman, S. Fan, Ultrabroadband photonic structures to achieve high-performance daytime radiative cooling. Nano Lett. 13(4), 1457–1461 (2013). https://doi.org/10.1021/nl4004283
  134. Y. Zhai, Y. Ma, S.N. David, D. Zhao, R. Lou et al., Scalable-manufactured randomized glass-polymer hybrid metamaterial for daytime radiative cooling. Science 355(6329), 1062–1066 (2017). https://doi.org/10.1126/science.aai7899
  135. R. Zhang, X. Wang, J. Song, Y. Si, X. Zhuang et al., In situ synthesis of flexible hierarchical TiO2 nanofibrous membranes with enhanced photocatalytic activity. J. Mater. Chem. A 3(44), 22136–22144 (2015). https://doi.org/10.1039/C5TA05442G
  136. K. Yuan, D. Han, J. Liang, W. Zhao, M. Li et al., Microwave induced in situ formation of SiC nanowires on SiCNO ceramic aerogels with excellent electromagnetic wave absorption performance. J. Adv. Ceram. 10(5), 1140–1151 (2021). https://doi.org/10.1007/s40145-021-0510-1
  137. D.A. Kritskaya, E.F. Abdrashitov, V.C. Bokun, A.N. Ponomarev, A study of pore formation and methanol vapor permeability in stretched polytetrafluoroethylene films used as a precursor of composite ion-exchange membranes. Pet. Chem. 58(4), 309–316 (2018). https://doi.org/10.1134/s0965544118040059
  138. S. Haouari, D. Rodrigue, A low-cost porous polymer membrane for gas permeation. Materials 15(10), 3537 (2022). https://doi.org/10.3390/ma15103537
  139. D. Kim, B.T. Duy Nguyen, S.H. Kim, J. Kim, J.F. Kim, New Sherwood correlations for hollow fiber membrane contactor modules: Comparison of porous and nonporous asymmetric membranes. J. Membr. Sci. 723, 123939 (2025). https://doi.org/10.1016/j.memsci.2025.123939
  140. Z. Dai, S. Pradeep, J. Zhu, W. Xie, H.F. Barton et al., Freestanding metal organic framework-based multifunctional membranes fabricated via pseudomorphic replication toward liquid- and gas-hazards abatement. Adv. Mater. Interfaces 8(22), 2101178 (2021). https://doi.org/10.1002/admi.202101178
  141. J. Hu, Z. Zhong, F. Zhang, W. Xing, W. Jin et al., High-efficiency, synergistic ZnO-coated SiC photocatalytic filter with antibacterial properties. Ind. Eng. Chem. Res. 55(23), 6661–6670 (2016). https://doi.org/10.1021/acs.iecr.6b00988
  142. F. Wang, Y. Si, J. Yu, B. Ding, Tailoring nanonets-engineered superflexible nanofibrous aerogels with hierarchical cage-like architecture enables renewable antimicrobial air filtration. Adv. Funct. Mater. 31(49), 2107223 (2021). https://doi.org/10.1002/adfm.202107223
  143. R. Osovsky, D. Kaplan, I. Nir, H. Rotter, S. Elisha et al., Decontamination of adsorbed chemical warfare agents on activated carbon using hydrogen peroxide solutions. Environ. Sci. Technol. 48(18), 10912–10918 (2014). https://doi.org/10.1021/es502981y
  144. S.S. Kiani, A. Farooq, M. Ahmad, N. Irfan, M. Nawaz et al., Impregnation on activated carbon for removal of chemical warfare agents (CWAs) and radioactive content. Environ. Sci. Pollut. Res. Int. 28(43), 60477–60494 (2021). https://doi.org/10.1007/s11356-021-15973-1
  145. C. Ramakrishna, T. Gopi, S.C. Shekar, A.K. Gupta, R. Krishna, Vapor phase catalytic degradation studies of diethyl sulfide with MnO/Zeolite-13X catalysts in presence of air. Environ. Prog. Sustain. Energy 37(5), 1705–1712 (2018). https://doi.org/10.1002/ep.12858
  146. D. Tušek, D. Ašperger, I. Bačić, L. Ćurković, J. Macan, Environmentally acceptable sorbents of chemical warfare agent simulants. J. Mater. Sci. 52(5), 2591–2604 (2017). https://doi.org/10.1007/s10853-016-0552-x
  147. Y. Liao, F. Yang, Y. Si, J. Yu, B. Ding, Nanoflake-engineered zirconic fibrous aerogels with parallel-arrayed conduits for fast nerve agent degradation. Nano Lett. 21(20), 8839–8847 (2021). https://doi.org/10.1021/acs.nanolett.1c03246
  148. Z. Yan, X. Liu, B. Ding, J. Yu, Y. Si, Interfacial engineered superelastic metal-organic framework aerogels with van-der-Waals barrier channels for nerve agents decomposition. Nat. Commun. 14(1), 2116 (2023). https://doi.org/10.1038/s41467-023-37693-5
  149. H. Liu, S. Qiang, F. Wu, X.-D. Zhu, X. Liu et al., Scalable synthesis of flexible single-atom monolithic catalysts for high-efficiency, durable CO oxidation at low temperature. ACS Nano 17(19), 19431–19440 (2023). https://doi.org/10.1021/acsnano.3c07888
  150. Y. Liao, J. Song, Y. Si, J. Yu, B. Ding, Superelastic and photothermal RGO/Zr-doped TiO2 nanofibrous aerogels enable the rapid decomposition of chemical warfare agents. Nano Lett. 22(11), 4368–4375 (2022). https://doi.org/10.1021/acs.nanolett.2c00776
  151. A. Larasati, G.D. Fowler, N.J.D. Graham, Insights into chemical regeneration of activated carbon for water treatment. J. Environ. Chem. Eng. 9(4), 105555 (2021). https://doi.org/10.1016/j.jece.2021.105555
  152. L.N. Shiyan, K.I. Machekhina, E.N. Gryaznova, Study the properties of activated carbon and oxyhydroxide aluminum as sorbents for removal humic substances from natural waters. IOP Conf. Ser. Mater. Sci. Eng. 110(1), 012097 (2016). https://doi.org/10.1088/1757-899X/110/1/012097
  153. R.K. Nekouei, F. Pahlevani, M. Assefi, S. Maroufi, V. Sahajwalla, Selective isolation of heavy metals from spent electronic waste solution by macroporous ion-exchange resins. J. Hazard. Mater. 371, 389–396 (2019). https://doi.org/10.1016/j.jhazmat.2019.03.013
  154. Y.E. Ghoussoub, H.M. Fares, J.D. Delgado, L.R. Keller, J.B. Schlenoff, Antifouling ion-exchange resins. ACS Appl. Mater. Interfaces 10(48), 41747–41756 (2018). https://doi.org/10.1021/acsami.8b12865
  155. D. Malwal, P. Gopinath, Fabrication and applications of ceramic nanofibers in water remediation: a review. Crit. Rev. Environ. Sci. Technol. 46(5), 500–534 (2016). https://doi.org/10.1080/10643389.2015.1109913
  156. J. Kim, J. Lee, J.-H. Ha, I.-H. Song, Effect of silica on flexibility of yttria-stabilized zirconia nanofibers for developing water purification membranes. Ceram. Int. 45(14), 17696–17704 (2019). https://doi.org/10.1016/j.ceramint.2019.05.337
  157. X. Dong, L. Cao, Y. Si, B. Ding, H. Deng, Cellular structured CNTs@SiO2 nanofibrous aerogels with vertically aligned vessels for salt-resistant solar desalination. Adv. Mater. 32(34), 1908269 (2020). https://doi.org/10.1002/adma.201908269
  158. X. Dong, Y. Si, C. Chen, B. Ding, H. Deng, Reed leaves inspired silica nanofibrous aerogels with parallel-arranged vessels for salt-resistant solar desalination. ACS Nano 15(7), 12256–12266 (2021). https://doi.org/10.1021/acsnano.1c04035
  159. F. Zhang, Y. Si, J. Yu, B. Ding, Sub-nanoporous engineered fibrous aerogel molecular sieves with nanogating channels for reversible molecular separation. Small 18(25), 2202173 (2022). https://doi.org/10.1002/smll.202202173
  160. M.-J. Chang, W.-Y. Zhu, J. Liu, G. Bai, X. Li et al., Fabrication of elastic SiO2 aerogels with prominent mechanical strength and stability reinforced by SiO2 nanofibers and polyurethane for oil adsorption. Sep. Purif. Technol. 341, 126914 (2024). https://doi.org/10.1016/j.seppur.2024.126914
  161. F. Wang, J. Dai, L. Huang, Y. Si, J. Yu et al., Biomimetic and superelastic silica nanofibrous aerogels with rechargeable bactericidal function for antifouling water disinfection. ACS Nano 14(7), 8975–8984 (2020). https://doi.org/10.1021/acsnano.0c03793
  162. B. Ren, J. Liu, Y. Rong, L. Wang, Y. Lu et al., Nanofibrous aerogel bulk assembled by cross-linked SiC/SiOx core-shell nanofibers with multifunctionality and temperature-invariant hyperelasticity. ACS Nano 13(10), 11603–11612 (2019). https://doi.org/10.1021/acsnano.9b05406
  163. H. Liu, F. Wu, X.-Y. Liu, J. Yu, Y.-T. Liu et al., Multiscale synergetic bandgap/structure engineering in semiconductor nanofibrous aerogels for enhanced solar evaporation. Nano Lett. 23(24), 11907–11915 (2023). https://doi.org/10.1021/acs.nanolett.3c04059
  164. Y. Wang, Z. Li, W. Fu, Y. Sun, Y. Dai, Core–sheath CeO2/SiO2 nanofibers as nanoreactors for stabilizing sinter-resistant Pt, enhanced catalytic oxidation and water remediation. Adv. Fiber Mater. 4(5), 1278–1289 (2022). https://doi.org/10.1007/s42765-022-00177-0
  165. Q. Fu, Y. Si, C. Duan, Z. Yan, L. Liu et al., Highly carboxylated, cellular structured, and underwater superelastic nanofibrous aerogels for efficient protein separation. Adv. Funct. Mater. 29(13), 1808234 (2019). https://doi.org/10.1002/adfm.201808234
  166. T. Pirzada, Z. Ashrafi, W. Xie, S.A. Khan, Cellulose silica hybrid nanofiber aerogels: from Sol–gel electrospun nanofibers to multifunctional aerogels. Adv. Funct. Mater. 30(5), 1907359 (2020). https://doi.org/10.1002/adfm.201907359
  167. Z. Yu, T. Fan, Y. Liu, B. Yang, L. Wang et al., Nanofiber aerogel with layered array with structure coupled photothermal/magnetothermal effect for continuous seawater desalination. Chem. Eng. J. 499, 155969 (2024). https://doi.org/10.1016/j.cej.2024.155969
  168. Q. Zhang, G. Yi, Z. Fu, H. Yu, S. Chen et al., Vertically aligned Janus MXene-based aerogels for solar desalination with high efficiency and salt resistance. ACS Nano 13(11), 13196–13207 (2019). https://doi.org/10.1021/acsnano.9b06180
  169. D. Yu, L. Liu, B. Ding, J. Yu, Y. Si, Spider-Web-Inspired SiO2/Ag nanofibrous aerogels with superelastic and conductive networks for electroporation water disinfection. Chem. Eng. J. 461, 141908 (2023). https://doi.org/10.1016/j.cej.2023.141908
  170. H. Wang, X. Mi, Y. Li, S. Zhan, 3D graphene-based macrostructures for water treatment. Adv. Mater. 32(3), e1806843 (2020). https://doi.org/10.1002/adma.201806843
  171. A. Gopinath, K. Kadirvelu, Strategies to design modified activated carbon fibers for the decontamination of water and air. Environ. Chem. Lett. 16(4), 1137–1168 (2018). https://doi.org/10.1007/s10311-018-0740-9
  172. J. Kim, M.M. Benjamin, Modeling a novel ion exchange process for arsenic and nitrate removal. Water Res. 38(8), 2053–2062 (2004). https://doi.org/10.1016/j.watres.2004.01.012
  173. I.V. Vlassiouk, A scalable graphene-based membrane. Nat. Nanotechnol. 12(11), 1022–1023 (2017). https://doi.org/10.1038/nnano.2017.184
  174. M.R. Landsman, R. Sujanani, S.H. Brodfuehrer, C.M. Cooper, A.G. Darr et al., Water treatment: are membranes the Panacea? Annu. Rev. Chem. Biomol. Eng. 11, 559–585 (2020). https://doi.org/10.1146/annurev-chembioeng-111919-091940
  175. Y. Su, T. Fan, W. Cui, Y. Li, S. Ramakrishna et al., Advanced electrospun nanofibrous materials for efficient oil/water separation. Adv. Fiber Mater. 4(5), 938–958 (2022). https://doi.org/10.1007/s42765-022-00158-3
  176. P. Sahoo, A.A. Ramachandran, P.K. Sow, A comprehensive review of fundamentals and future trajectories in oil-water separation system designs with superwetting materials. J. Environ. Manag. 370, 122641 (2024). https://doi.org/10.1016/j.jenvman.2024.122641
  177. N.Y. Abu-Thabit, M.H. Abu Elella, A.K. Azad, E. Ratemi, A.S. Hakeem, Superwetting metal mesh membranes for oil/water separation: a comprehensive review. Sep. Purif. Technol. 363, 132016 (2025). https://doi.org/10.1016/j.seppur.2025.132016
  178. X. Liu, Z. Liu, X. Wang, Y. Gao, J. Zhang et al., Superhydrophobic nanofibrous sponge with hierarchically layered structure for efficient harsh environmental oil-water separation. J. Hazard. Mater. 440, 129790 (2022). https://doi.org/10.1016/j.jhazmat.2022.129790
  179. Y. Si, Q. Fu, X. Wang, J. Zhu, J. Yu et al., Superelastic and superhydrophobic nanofiber-assembled cellular aerogels for effective separation of oil/water emulsions. ACS Nano 9(4), 3791–3799 (2015). https://doi.org/10.1021/nn506633b
  180. X. Wang, Z. Liu, X. Liu, Y. Su, J. Wang et al., Ultralight and multifunctional PVDF/SiO2@GO nanofibrous aerogel for efficient harsh environmental oil–water separation and crude oil absorption. Carbon 193, 77–87 (2022). https://doi.org/10.1016/j.carbon.2022.03.028
  181. Q. Fu, L. Liu, Y. Si, J. Yu, B. Ding, Shapeable, underwater superelastic, and highly phosphorylated nanofibrous aerogels for large-capacity and high-throughput protein separation. ACS Appl. Mater. Interfaces 11(47), 44874–44885 (2019). https://doi.org/10.1021/acsami.9b15760
  182. K.W. Tan, C.M. Yap, Z. Zheng, C.Y. Haw, P.S. Khiew et al., State-of-the-art advances, development, and challenges of metal oxide semiconductor nanomaterials for photothermal solar steam generation. Adv. Sustain. Syst. 6(4), 2100416 (2022). https://doi.org/10.1002/adsu.202100416
  183. Y. Liu, M. Zhang, Z. Shen, N. Li, X. Mo et al., Design of honeycomb-imitated composite hydrophobic aerogel and applications for multifunctional water cleaning. Sep. Purif. Technol. 359, 130341 (2025). https://doi.org/10.1016/j.seppur.2024.130341
  184. X. Zhao, H. Zhang, K.-Y. Chan, X. Huang, Y. Yang et al., Tree-inspired structurally graded aerogel with synergistic water, salt, and thermal transport for high-salinity solar-powered evaporation. Nano-Micro Lett. 16(1), 222 (2024). https://doi.org/10.1007/s40820-024-01448-8
  185. Y. Lu, R. Zhou, N. Wang, Y. Yang, Z. Zheng et al., Engineer nanoscale defects into selective channels: MOF-enhanced Li+ separation by porous layered double hydroxide membrane. Nano-Micro Lett. 15(1), 147 (2023). https://doi.org/10.1007/s40820-023-01101-w
  186. D.T. Lee, J. Zhao, C.J. Oldham, G.W. Peterson, G.N. Parsons, UiO-66-NH2 metal-organic framework (MOF) nucleation on TiO2, ZnO, and Al2O3 atomic layer deposition-treated polymer fibers: role of metal oxide on MOF growth and catalytic hydrolysis of chemical warfare agent simulants. ACS Appl. Mater. Interfaces 9(51), 44847–44855 (2017). https://doi.org/10.1021/acsami.7b15397
  187. J.E. Mondloch, M.J. Katz, W.C. Isley, P. Ghosh, P. Liao et al., Destruction of chemical warfare agents using metal–organic frameworks. Nat. Mater. 14(5), 512–516 (2015). https://doi.org/10.1038/nmat4238
  188. I. Del Castillo-Velilla, I. Romero-Muñiz, C. Marini, C. Montoro, A.E. Platero-Prats, Copper single-site engineering in MOF-808 membranes for improved water treatment. Nanoscale 16(13), 6627–6635 (2024). https://doi.org/10.1039/d3nr05821b
  189. V. Rahmanian, M.Z. Ahmad Ebrahim, S. Razavi, M. Abdelmigeed, E. Barbieri et al., Vapor phase synthesis of metal–organic frameworks on a nanofibrous aerogel creates enhanced functionality. J. Mater. Chem. A 12(1), 214–226 (2024). https://doi.org/10.1039/D3TA05299K
  190. L. Cao, X. Yu, X. Yin, Y. Si, J. Yu et al., Hierarchically maze-like structured nanofiber aerogels for effective low-frequency sound absorption. J. Colloid Interface Sci. 597, 21–28 (2021). https://doi.org/10.1016/j.jcis.2021.03.172
  191. L. Cao, Y. Si, Y. Wu, X. Wang, J. Yu et al., Ultralight, superelastic and bendable lashing-structured nanofibrous aerogels for effective sound absorption. Nanoscale 11(5), 2289–2298 (2019). https://doi.org/10.1039/C8NR09288E
  192. Y. Feng, D. Zong, Y. Hou, X. Yin, S. Zhang et al., Gradient structured micro/nanofibrous sponges with superior compressibility and stretchability for broadband sound absorption. J. Colloid Interface Sci. 593, 59–66 (2021). https://doi.org/10.1016/j.jcis.2021.03.013
  193. W. Bai, D. Zong, X. Liu, F. Wang, X. Yin et al., Flame-retardant, ultralight, and superelastic electrospun fiber sponges for effective sound absorption. J. Text. Inst. 115(5), 724–732 (2024). https://doi.org/10.1080/00405000.2023.2201553
  194. D. Zong, L. Cao, Y. Li, X. Yin, Y. Si et al., Interlocked dual-network and superelastic electrospun fibrous sponges for efficient low-frequency noise absorption. Small Struct. 1(2), 2000004 (2020). https://doi.org/10.1002/sstr.202000004
  195. M. Yang, Z. Chen, L. Yang, Y. Ding, X. Chen et al., Hierarchically porous networks structure based on flexible SiO2 nanofibrous aerogel with excellent low frequency noise absorption. Ceram. Int. 49(1), 301–308 (2023). https://doi.org/10.1016/j.ceramint.2022.08.344
  196. L. Cao, H. Shan, D. Zong, X. Yu, X. Yin et al., Fire-resistant and hierarchically structured elastic ceramic nanofibrous aerogels for efficient low-frequency noise reduction. Nano Lett. 22(4), 1609–1617 (2022). https://doi.org/10.1021/acs.nanolett.1c04532
  197. D. Zong, W. Bai, X. Yin, J. Yu, S. Zhang et al., Gradient pore structured elastic ceramic nanofiber aerogels with cellulose nanonets for noise absorption. Adv. Funct. Mater. 33(31), 2301870 (2023). https://doi.org/10.1002/adfm.202301870
  198. Q. Song, F. Ye, L. Kong, Q. Shen, L. Han et al., Graphene and MXene nanomaterials: toward high-performance electromagnetic wave absorption in gigahertz band range. Adv. Funct. Mater. 30(31), 2000475 (2020). https://doi.org/10.1002/adfm.202000475
  199. Z. Guo, D. Lan, Z. Jia, Z. Gao, X. Shi et al., Multiple tin compounds modified carbon fibers to construct heterogeneous interfaces for corrosion prevention and electromagnetic wave absorption. Nano-Micro Lett. 17(1), 23 (2024). https://doi.org/10.1007/s40820-024-01527-w
  200. R. Islam, Y. Sood, H. Mudila, A. Ohlan, A. Kumar, Microwave absorbing properties of polypyrrole-based 2D nanocomposites. J. Mater. Chem. A 12(45), 31004–31027 (2024). https://doi.org/10.1039/d4ta05676k
  201. I. Abdalla, J. Cai, W. Lu, J. Yu, Z. Li et al., Recent progress on electromagnetic wave absorption materials enabled by electrospun carbon nanofibers. Carbon 213, 118300 (2023). https://doi.org/10.1016/j.carbon.2023.118300
  202. Y. Zhao, X. Zuo, Y. Guo, H. Huang, H. Zhang et al., Structural engineering of hierarchical aerogels comprised of multi-dimensional gradient carbon nanoarchitectures for highly efficient microwave absorption. Nano-Micro Lett. 13(1), 144 (2021). https://doi.org/10.1007/s40820-021-00667-7
  203. J. Cheng, Y. Jin, J. Zhao, Q. Jing, B. Gu et al., From VIB- to VB-group transition metal disulfides: structure engineering modulation for superior electromagnetic wave absorption. Nano-Micro Lett. 16(1), 29 (2023). https://doi.org/10.1007/s40820-023-01247-7
  204. L. Yue, B. Zhong, L. Xia, T. Zhang, Y. Yu et al., Three-dimensional network-like structure formed by silicon coated carbon nanotubes for enhanced microwave absorption. J. Colloid Interface Sci. 582, 177–186 (2021). https://doi.org/10.1016/j.jcis.2020.08.024
  205. L. Xu, X. Zhang, L. Huang, J. Yu, Y. Si et al., Janus dual self-strengthening structure of Bi2O3/Gd2O3 nanofibrous membranes for superior X-ray shielding. Small 19(40), 2303012 (2023). https://doi.org/10.1002/smll.202303012
  206. Y. Xia, Z. Zhang, K. Li, S. Zhao, G. Chen et al., Lightweight and high-strength SiC/MWCNTs nanofibrous aerogel derived from RGO/MWCNTs aerogel for microwave absorption. Chem. Eng. J. 486, 150417 (2024). https://doi.org/10.1016/j.cej.2024.150417
  207. F. Wu, P. Hu, F. Hu, Z. Tian, J. Tang et al., Multifunctional MXene/C aerogels for enhanced microwave absorption and thermal insulation. Nano-Micro Lett. 15(1), 194 (2023). https://doi.org/10.1007/s40820-023-01158-7
  208. C. Liu, J. Lin, N. Wu, C. Weng, M. Han et al., Perspectives for electromagnetic wave absorption with graphene. Carbon 223, 119017 (2024). https://doi.org/10.1016/j.carbon.2024.119017
  209. S. Sharma, S.R. Parne, S.S.S. Panda, S. Gandi, Progress in microwave absorbing materials: a critical review. Adv. Colloid Interface Sci. 327, 103143 (2024). https://doi.org/10.1016/j.cis.2024.103143
  210. Y. Cheng, X. Sun, Y. Yuan, S. Yang, Y. Ning et al., Flexible SiO2/rGO aerogel for wide-angle broadband microwave absorption. Carbon 217, 118580 (2024). https://doi.org/10.1016/j.carbon.2023.118580
  211. Y. Xia, W. Gao, C. Gao, A review on graphene-based electromagnetic functional materials: electromagnetic wave shielding and absorption. Adv. Funct. Mater. 32(42), 2204591 (2022). https://doi.org/10.1002/adfm.202204591
  212. L. Gai, Y. Wang, P. Wan, S. Yu, Y. Chen et al., Compositional and hollow engineering of silicon carbide/carbon microspheres as high-performance microwave absorbing materials with good environmental tolerance. Nano-Micro Lett. 16(1), 167 (2024). https://doi.org/10.1007/s40820-024-01369-6
  213. G. Shao, C. Ding, G. Yu, R. Xu, X. Huang, Bridged polysilsesquioxane-derived SiOCN ceramic aerogels for microwave absorption. J. Am. Ceram. Soc. 106(4), 2407–2419 (2023). https://doi.org/10.1111/jace.18937
  214. X. Sun, Y. Pu, F. Wu, J. He, G. Deng et al., 0D–1D-2D multidimensionally assembled Co9S8/CNTs/MoS2 composites for ultralight and broadband electromagnetic wave absorption. Chem. Eng. J. 423, 130132 (2021). https://doi.org/10.1016/j.cej.2021.130132
  215. X. Wang, Y. Yuan, X. Sun, R. Qiang, Y. Xu et al., Lightweight, flexible, and thermal insulating carbon/SiO2@CNTs composite aerogel for high-efficiency microwave absorption. Small 20(30), e2311657 (2024). https://doi.org/10.1002/smll.202311657
  216. J. Wang, S. Shi, Y. Yan, G. Wan, H. Zhai et al., Manganese oxides/graphene aerogels as lightweight microwave absorbers for extreme environment application. Chem. Eng. J. 493, 152277 (2024). https://doi.org/10.1016/j.cej.2024.152277
  217. J. Zhao, M. Li, X. Gao, Construction of SnO2 nanop cluster@PANI core-shell microspheres for efficient X-band electromagnetic wave absorption. J. Alloys Compd. 915, 165439 (2022). https://doi.org/10.1016/j.jallcom.2022.165439
  218. M. Qin, L. Zhang, X. Zhao, H. Wu, Defect induced polarization loss in multi-shelled spinel hollow spheres for electromagnetic wave absorption application. Adv. Sci. 8(8), 2004640 (2021). https://doi.org/10.1002/advs.202004640
  219. J.-P. Chen, Y.-F. Du, Z.-F. Wang, L.-L. Liang, H. Jia et al., Anchoring of SiC whiskers on the hollow carbon microspheres inducing interfacial polarization to promote electromagnetic wave attenuation capability. Carbon 175, 11–19 (2021). https://doi.org/10.1016/j.carbon.2020.12.073
  220. M. Wu, Y.D. Zhang, S. Hui, T.D. Xiao, S. Ge et al., Microwave magnetic properties of Co50/(SiO2)50 nanops. Appl. Phys. Lett. 80(23), 4404–4406 (2002). https://doi.org/10.1063/1.1484248
  221. B. Li, H. Tian, L. Li, W. Liu, J. Liu et al., Graphene-assisted assembly of electrically and magnetically conductive ceramic nanofibrous aerogels enable multifunctionality. Adv. Funct. Mater. 34(22), 2314653 (2024). https://doi.org/10.1002/adfm.202314653
  222. Y. Feng, Z. Li, X. Chen, Y. Pan, X. Zhao et al., Three-dimensional porous, flexible and lightweight reduced graphene oxide/Li0.35Zn0.3Fe2.35O4@SiO2 nanofibers aerogel for efficient microwave absorption. J. Alloys Compd. 988, 174273 (2024). https://doi.org/10.1016/j.jallcom.2024.174273
  223. Y. Wang, B. Li, Hard X-ray attosecond pulse reflection from realistic W/B4C multilayer structures. Nucl. Instrum. Meth. Phys. Res. Sect. A Accel. Spectrometers Detect. Assoc. Equip. 1001, 165233 (2021). https://doi.org/10.1016/j.nima.2021.165233
  224. A.M. Grishin, A. Jalalian, M.I. Tsindlekht, Gadolinia nanofibers as a multimodal bioimaging and potential radiation therapy agent. AIP Adv. 5(5), 057104 (2015). https://doi.org/10.1063/1.4919810
  225. L. Xu, J. Zhao, L. Huang, J. Yu, Y. Si et al., Bi2O3/Gd2O3 meta-aerogel with leaf-inspired nanotrap array enables efficient X-ray absorption. ACS Nano 17(23), 24080–24089 (2023). https://doi.org/10.1021/acsnano.3c09063
  226. B. Sun, T. Wang, C. Qin, M. Amjad Majeed, Z. Wang et al., Responsive aerogels of ultra-light flexibility and Fouling-Resistant characteristics to safeguarding X-ray exposure. Chem. Eng. J. 495, 153888 (2024). https://doi.org/10.1016/j.cej.2024.153888
  227. H. Peng, B. Cai, Y. Zhang, L. Gao, P.-Y. Zhao et al., Radar-terahertz-infrared compatible stealth coaxial silver Nanowire@Carbon nano-cable aerogel. Angew. Chem. Int. Ed. 64(10), e202421090 (2025). https://doi.org/10.1002/anie.202421090
  228. X. Liu, K. Pang, H. Yang, X. Guo, Intrinsically microstructured graphene aerogel exhibiting excellent mechanical performance and super-high adsorption capacity. Carbon 161, 146–152 (2020). https://doi.org/10.1016/j.carbon.2020.01.065
  229. X. Wang, Y. Lu, T. Zhu, S. Chang, W. Wang, CoFe2O4/N-doped reduced graphene oxide aerogels for high-performance microwave absorption. Chem. Eng. J. 388, 124317 (2020). https://doi.org/10.1016/j.cej.2020.124317
  230. Z. Hao, Z. Song, J. Huang, K. Huang, A. Panetta et al., The scaffold microenvironment for stem cell based bone tissue engineering. Biomater. Sci. 5(8), 1382–1392 (2017). https://doi.org/10.1039/c7bm00146k
  231. S.-J. Jiang, M.-H. Wang, Z.-Y. Wang, H.-L. Gao, S.-M. Chen et al., Radially porous nanocomposite scaffolds with enhanced capability for guiding bone regeneration in vivo. Adv. Funct. Mater. 32(18), 2110931 (2022). https://doi.org/10.1002/adfm.202110931
  232. L.F.B. Nogueira, M.A.E. Cruz, M.T. de Melo, B.C. Maniglia, F. Caroleo et al., Collagen/κ-carrageenan-based scaffolds as biomimetic constructs for in vitro bone mineralization studies. Biomacromol 24(3), 1258–1266 (2023). https://doi.org/10.1021/acs.biomac.2c01313
  233. L. Fang, X. Lin, R. Xu, L. Liu, Y. Zhang et al., Advances in the development of gradient scaffolds made of nano-micromaterials for musculoskeletal tissue regeneration. Nano-Micro Lett. 17(1), 75 (2024). https://doi.org/10.1007/s40820-024-01581-4
  234. G. Turnbull, J. Clarke, F. Picard, P. Riches, L. Jia et al., 3D bioactive composite scaffolds for bone tissue engineering. Bioact. Mater. 3(3), 278–314 (2018). https://doi.org/10.1016/j.bioactmat.2017.10.001
  235. N. Sezer, Z. Evis, M. Koç, Additive manufacturing of biodegradable magnesium implants and scaffolds: Review of the recent advances and research trends. J. Magnes. Alloys 9(2), 392–415 (2021). https://doi.org/10.1016/j.jma.2020.09.014
  236. C. Zhou, S. Su, J. Fan, J. Lin, X. Wang, Engineered electrospun poly(lactic-co-glycolic acid)/Si3N4 nanofiber scaffold promotes osteogenesis of mesenchymal stem cell. Front. Mater. 9, 991018 (2022). https://doi.org/10.3389/fmats.2022.991018
  237. W. Zhai, H. Lu, C. Wu, L. Chen, X. Lin et al., Stimulatory effects of the ionic products from Ca–Mg–Si bioceramics on both osteogenesis and angiogenesis in vitro. Acta Biomater. 9(8), 8004–8014 (2013). https://doi.org/10.1016/j.actbio.2013.04.024
  238. L. Weng, S.K. Boda, H. Wang, M.J. Teusink, F.D. Shuler et al., Novel 3D hybrid nanofiber aerogels coupled with BMP-2 peptides for cranial bone regeneration. Adv. Healthc. Mater. 7(10), 1701415 (2018). https://doi.org/10.1002/adhm.201701415
  239. L. Wang, Y. Qiu, Y. Guo, Y. Si, L. Liu et al., Smart, elastic, and nanofiber-based 3D scaffolds with self-deploying capability for osteoporotic bone regeneration. Nano Lett. 19(12), 9112–9120 (2019). https://doi.org/10.1021/acs.nanolett.9b04313
  240. B. Guo, R. Dong, Y. Liang, M. Li, Haemostatic materials for wound healing applications. Nat. Rev. Chem. 5(11), 773–791 (2021). https://doi.org/10.1038/s41570-021-00323-z
  241. X. Wang, Z. Yuan, M. Shafiq, G. Cai, Z. Lei et al., Composite aerogel scaffolds containing flexible silica nanofiber and tricalcium phosphate enable skin regeneration. ACS Appl. Mater. Interfaces 16(20), 25843–25855 (2024). https://doi.org/10.1021/acsami.4c03744
  242. J. Huang, Y. Zheng, W. Ma, Y. Han, J. Xue et al., SiO2-based inorganic nanofiber aerogel with rapid hemostasis and liver wound healing functions. Acta Biomater. 194, 483–497 (2025). https://doi.org/10.1016/j.actbio.2025.01.027
  243. X. Li, B. Dai, J. Guo, L. Zheng, Q. Guo et al., Nanop-cartilage interaction: pathology-based intra-articular drug delivery for osteoarthritis therapy. Nano-Micro Lett. 13(1), 149 (2021). https://doi.org/10.1007/s40820-021-00670-y
  244. J. Ren, Z. Zhang, S. Geng, Y. Cheng, H. Han et al., Molecular mechanisms of intracellular delivery of nanops monitored by an enzyme-induced proximity labeling. Nano-Micro Lett. 16(1), 103 (2024). https://doi.org/10.1007/s40820-023-01313-0
  245. Y. Zhang, J. Li, P. Habibovic, Magnetically responsive nanofibrous ceramic scaffolds for on-demand motion and drug delivery. Bioact. Mater. 15, 372–381 (2022). https://doi.org/10.1016/j.bioactmat.2022.02.028
  246. V. Uskoković, P.P. Lee, L.A. Walsh, K.E. Fischer, T.A. Desai, PEGylated silicon nanowire coated silica microps for drug delivery across intestinal epithelium. Biomaterials 33(5), 1663–1672 (2012). https://doi.org/10.1016/j.biomaterials.2011.11.010
  247. A.I. Martínez-Banderas, A. Aires, M. Quintanilla, J.A. Holguín-Lerma, C. Lozano-Pedraza et al., Iron-based core-shell nanowires for combinatorial drug delivery and photothermal and magnetic therapy. ACS Appl. Mater. Interfaces 11(47), 43976–43988 (2019). https://doi.org/10.1021/acsami.9b17512
  248. Y. Zhao, C. Cheng, X. Wang, Z. Yuan, B. Sun et al., Aspirin-loaded anti-inflammatory ZnO-SiO2 aerogel scaffolds for bone regeneration. ACS Appl. Mater. Interfaces 16(14), 17092–17108 (2024). https://doi.org/10.1021/acsami.3c17152
  249. Y. Zhang, J. Li, M. Soleimani, F. Giacomini, H. Friedrich et al., Biodegradable elastic sponge from nanofibrous biphasic calcium phosphate ceramic as an advanced material for regenerative medicine. Adv. Funct. Mater. 31(40), 2102911 (2021). https://doi.org/10.1002/adfm.202102911
  250. M. Zhang, J. Dai, S. Huang, D. Fang, Y. Liu et al., Pt/TiO2–x nanofibrous aerogel for effective nitrogen reduction: a simple strategy for simultaneous Pt formation and TiO2–x vacancy engineering. Chin. Chem. Lett. 33(2), 1001–1005 (2022). https://doi.org/10.1016/j.cclet.2021.08.069
  251. F. Zhang, J. Yu, Y. Si, B. Ding, Meta-aerogel ion motor for nanofluid osmotic energy harvesting. Adv. Mater. 35(38), e2302511 (2023). https://doi.org/10.1002/adma.202302511
  252. S.L. Foster, S.I.P. Bakovic, R.D. Duda, S. Maheshwari, R.D. Milton et al., Catalysts for nitrogen reduction to ammonia. Nat. Catal. 1(7), 490–500 (2018). https://doi.org/10.1038/s41929-018-0092-7
  253. V. Kyriakou, I. Garagounis, A. Vourros, E. Vasileiou, M. Stoukides, An electrochemical Haber-Bosch process. Joule 4(1), 142–158 (2020). https://doi.org/10.1016/j.joule.2019.10.006
  254. C.M. Goodwin, P. Lömker, D. Degerman, B. Davies, M. Shipilin et al., operando probing of the surface chemistry during the Haber-Bosch process. Nature 625(7994), 282–286 (2024). https://doi.org/10.1038/s41586-023-06844-5
  255. R.D. Cusick, Y. Kim, B.E. Logan, Energy capture from thermolytic solutions in microbial reverse-electrodialysis cells. Science 335(6075), 1474–1477 (2012). https://doi.org/10.1126/science.1219330
  256. F. Hong, C. Yan, Y. Si, J. He, J. Yu et al., Nickel ferrite nanops anchored onto silica nanofibers for designing magnetic and flexible nanofibrous membranes. ACS Appl. Mater. Interfaces 7(36), 20200–20207 (2015). https://doi.org/10.1021/acsami.5b05754
  257. X. Zhang, Y. Liu, Y. Si, J. Yu, B. Ding, Flexible and tough zirconia-based nanofibrous membranes for thermal insulation. Compos. Commun. 33, 101219 (2022). https://doi.org/10.1016/j.coco.2022.101219
  258. V.V. Rodaev, A.I. Tyurin, S.S. Razlivalova, V.V. Korenkov, Y.I. Golovin, Effect of zirconia nanofibers structure evolution on the hardness and Young’s modulus of their mats. Polymers 13(22), 3932 (2021). https://doi.org/10.3390/polym13223932
  259. X. Mao, Y. Bai, J. Yu, B. Ding, Flexible and highly temperature resistant polynanocrystalline zirconia nanofibrous membranes designed for air filtration. J. Am. Ceram. Soc. 99(8), 2760–2768 (2016). https://doi.org/10.1111/jace.14278
  260. L. Yao, W. Pan, J. Luo, X. Zhao, J. Cheng et al., Stabilizing nanocrystalline oxide nanofibers at elevated temperatures by coating nanoscale surface amorphous films. Nano Lett. 18(1), 130–136 (2018). https://doi.org/10.1021/acs.nanolett.7b03651
  261. X. Mao, J. Hong, Y.-X. Wu, Q. Zhang, J. Liu et al., An efficient strategy for reinforcing flexible ceramic membranes. Nano Lett. 21(22), 9419–9425 (2021). https://doi.org/10.1021/acs.nanolett.1c02657
  262. S. Li, X. Zhang, X. Cheng, G. Han, Y. Si et al., Flexible and compressive Al2O3/ZrO2/Y2O3 nanofibrous membranes for thermal insulation at 1400 ℃. Compos. Commun. 35, 101290 (2022). https://doi.org/10.1016/j.coco.2022.101290
  263. Y. Wang, W. Li, Y. Xia, X. Jiao, D. Chen, Electrospun flexible self-standing γ-alumina fibrous membranes and their potential as high-efficiency fine particulate filtration media. J. Mater. Chem. A 2(36), 15124–15131 (2014). https://doi.org/10.1039/C4TA01770F
  264. X. Song, K. Zhang, Y. Song, Z. Duan, Q. Liu et al., Morphology, microstructure and mechanical properties of electrospun alumina nanofibers prepared using different polymer templates: a comparative study. J. Alloys Compd. 829, 154502 (2020). https://doi.org/10.1016/j.jallcom.2020.154502
  265. J. Jiang, N. Ni, X. Zhao, F. Guo, X. Fan et al., Flexible and robust YAG-Al2O3 composite nanofibrous membranes enabled by a hybrid nanocrystalline-amorphous structure. J. Eur. Ceram. Soc. 40(6), 2463–2469 (2020). https://doi.org/10.1016/j.jeurceramsoc.2020.01.056
  266. J. Song, J. Dai, P. Zhang, Y. Liu, J. Yu et al., G-C3N4 encapsulated ZrO2 nanofibrous membrane decorated with CdS quantum dots: a hierarchically structured, self-supported electrocatalyst toward synergistic NH3 synthesis. Nano Res. 14(5), 1479–1487 (2021). https://doi.org/10.1007/s12274-020-3206-x
  267. W. Li, Y. Wang, B. Ji, X. Jiao, D. Chen, Flexible Pd/CeO2–TiO2 nanofibrous membrane with high efficiency ultrafine particulate filtration and improved CO catalytic oxidation performance. RSC Adv. 5(72), 58120–58127 (2015). https://doi.org/10.1039/C5RA09198E
  268. J. Song, X. Wang, J. Yan, J. Yu, G. Sun et al., Soft Zr-doped TiO2 nanofibrous membranes with enhanced photocatalytic activity for water purification. Sci. Rep. 7(1), 1636 (2017). https://doi.org/10.1038/s41598-017-01969-w
  269. Y. Hou, L. Cheng, Y. Zhang, Y. Yang, C. Deng et al., Enhanced flexibility and microwave absorption properties of HfC/SiC nanofiber mats. ACS Appl. Mater. Interfaces 10(35), 29876–29883 (2018). https://doi.org/10.1021/acsami.8b07980
  270. J. Chen, Y. Zhang, D. Yan, Y. Gou, Flexible ultrafine nearly stoichiometric polycrystalline SiC fibers with excellent oxidation resistance and superior thermal stability up to 1900 ℃. J. Eur. Ceram. Soc. 42(5), 1938–1946 (2022). https://doi.org/10.1016/j.jeurceramsoc.2021.12.049
  271. P. Yu, Z. Lin, Y. Mu, J. Yu, Highly flexible and strong SiC fibre mats prepared by electrospinning and hot-drawing. Adv. Appl. Ceram. 120(3), 144–155 (2021). https://doi.org/10.1080/17436753.2021.1904767
  272. X. Zhang, B. Wang, N. Wu, C. Han, Y. Wang, Multi-phase SiZrOC nanofibers with outstanding flexibility and stability for thermal insulation up to 1400 ℃. Chem. Eng. J. 410, 128304 (2021). https://doi.org/10.1016/j.cej.2020.128304
  273. X. Zhang, B. Wang, N. Wu, C. Han, C. Wu et al., Flexible and thermal-stable SiZrOC nanofiber membranes with low thermal conductivity at high-temperature. J. Eur. Ceram. Soc. 40(5), 1877–1885 (2020). https://doi.org/10.1016/j.jeurceramsoc.2020.01.037
  274. Z. Xu, F. Wu, K. Pan, Y. Liao, F. Wang et al., Ceramic aerogels constructed from dense, non-porous ceramic nanofibers with robust and elastic properties up to 1300 ℃. Ceram. Int. 50(4), 6381–6387 (2024). https://doi.org/10.1016/j.ceramint.2023.11.373
  275. F. Wang, L. Dou, J. Dai, Y. Li, L. Huang et al., In situ synthesis of biomimetic silica nanofibrous aerogels with temperature-invariant superelasticity over one million compressions. Angew. Chem. Int. Ed. 59(21), 8285–8292 (2020). https://doi.org/10.1002/anie.202001679
  276. X. Zhang, W. Huang, J. Yu, C. Zhao, Y. Si, Nacre-mimetic multi-mechanical synergistic ceramic aerogels with interfacial bridging and stress delocalization. Adv. Funct. Mater. 35(10), 2416857 (2025). https://doi.org/10.1002/adfm.202416857
  277. R. Zhang, Z.
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