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Vol. 9 No. 2 (2017)

Research Progress in Improving the Cycling Stability of High-Voltage LiNi0.5Mn1.5O4 Cathode in Lithium-Ion Battery

https://doi.org/10.1007/s40820-016-0123-3
XiaoLong Xu
The College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, People’s Republic of China
SiXu Deng
The College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, People’s Republic of China
Hao Wang
The College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, People’s Republic of China
JingBing Liu
The College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, People’s Republic of China
Hui Yan
The College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, People’s Republic of China

Corresponding Author: Hao Wang

haowang@bjut.edu.cn

Nano-Micro Letters, Vol. 9 No. 2 (2017), Article Number: 22

Abstract

High-voltage lithium-ion batteries (HVLIBs) are considered as promising devices of energy storage for electric vehicle, hybrid electric vehicle, and other high-power equipment. HVLIBs require their own platform voltages to be higher than 4.5 V on charge. Lithium nickel manganese spinel LiNi0.5Mn1.5O4 (LNMO) cathode is the most promising candidate among the 5 V cathode materials for HVLIBs due to its flat plateau at 4.7 V. However, the degradation of cyclic performance is very serious when LNMO cathode operates over 4.2 V. In this review, we summarize some methods for enhancing the cycling stability of LNMO cathodes in lithium-ion batteries, including doping, cathode surface coating, electrolyte modifying, and other methods. We also discuss the advantages and disadvantages of different methods.

Keywords

High-voltage cathode LiNi0.5Mn1.5O4 Lithium-ion battery Cycling stability Platform voltage
Xu, XiaoLong, SiXu Deng, Hao Wang, JingBing Liu, and Hui Yan. 2017. “Research Progress in Improving the Cycling Stability of High-Voltage LiNi0.5Mn1.5O4 Cathode in Lithium-Ion Battery”. Nano-Micro Letters 9 (2):22. https://doi.org/10.1007/s40820-016-0123-3.
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