Issue

Vol. 12 (2020)

Bismuth-Based Free-Standing Electrodes for Ambient-Condition Ammonia Production in Neutral Media

https://doi.org/10.1007/s40820-020-00444-y
Ying Sun
Institute of Clean Energy Chemistry, Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, People’s Republic of China
Zizhao Deng
Institute of Clean Energy Chemistry, Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, People’s Republic of China
Xi‑Ming Song
Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, People’s Republic of China
Hui Li
Institute of Clean Energy Chemistry, Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, People’s Republic of China
Zihang Huang
Institute of Clean Energy Chemistry, Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, People’s Republic of China
Qin Zhao
Institute of Clean Energy Chemistry, Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, People’s Republic of China
Daming Feng
Institute of Clean Energy Chemistry, Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, People’s Republic of China
Wei Zhang
Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, People’s Republic of China
Zhaoqing Liu
School of Chemistry and Chemical Engineering, Guangzhou Key Laboratory for Environmentally Functional Materials and Technology, Guangzhou University, Guangzhou 510006, People’s Republic of China
Tianyi Ma
Discipline of Chemistry, University of Newcastle, Callaghan, NSW 2308, Australia

Corresponding Author: Tianyi Ma

Tianyi.Ma@newcastle.edu.au

Nano-Micro Letters, Vol. 12 (2020), Article Number: 133

Abstract

Electrocatalytic nitrogen reduction reaction is a carbon-free and energy-saving strategy for efficient synthesis of ammonia under ambient conditions. Here, we report the synthesis of nanosized Bi2O3 particles grown on functionalized exfoliated graphene (Bi2O3/FEG) via a facile electrochemical deposition method. The obtained free-standing Bi2O3/FEG achieves a high Faradaic efficiency of 11.2% and a large NH3 yield of 4.21 ± 0.14 μgNH3 h−1 cm−2 at − 0.5 V versus reversible hydrogen electrode in 0.1 M Na2SO4, better than that in the strong acidic and basic media. Benefiting from its strong interaction of Bi 6p band with the N 2p orbitals, binder-free characteristic, and facile electron transfer, Bi2O3/FEG achieves superior catalytic performance and excellent long-term stability as compared with most of the previous reported catalysts. This study is significant to design low-cost, high-efficient Bi-based electrocatalysts for electrochemical ammonia synthesis.


Highlights:


1 The Bi2O3 nanoplates homogeneously decorated free-standing exfoliated graphene (Bi2O3/FEG) was prepared by a facile electrochemical deposition method.
2 The Bi2O3/FEG first used as nitrogen reduction electrocatalyst exhibits excellent electrocatalysis performance and stability for nitrogen reduction reaction in neutral media.
3 The superior electrocatalytic nitrogen reduction activity is attributed to the strong interaction of the Bi 6p band with the N 2p orbitals, binder-free nature of the electrodes, and facile electron transfer through the graphene nanosheets.

Keywords

N2 reduction Bi2O3 nanoplate Electrocatalysis Free-standing
Sun, Ying, Zizhao Deng, Xi‑Ming Song, Hui Li, Zihang Huang, Qin Zhao, Daming Feng, Wei Zhang, Zhaoqing Liu, and Tianyi Ma. 2020. “Bismuth-Based Free-Standing Electrodes for Ambient-Condition Ammonia Production in Neutral Media”. Nano-Micro Letters 12 (June):133. https://doi.org/10.1007/s40820-020-00444-y.
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References
  1. Z.Q. Wang, K. Zheng, S.L. Liu, Z.C. Dai, Y. Xu, X.N. Li, H.J. Wang, L. Wang, Electrocatalytic nitrogen reduction to ammonia by Fe2O3 nanorod array on carbon cloth. ACS Sustain. Chem. Eng. 13, 11754–11759 (2019). https://doi.org/10.1021/acssuschemeng.9b01991
  2. H. Cheng, L.X. Ding, G.F. Chen, L.L. Zhang, J. Xue, H.H. Wang, Nitrogen reduction reaction: molybdenum carbide nanodots enable efficient electrocatalytic nitrogen fixation under ambient conditions. Adv. Mater. 46, 1870350 (2018). https://doi.org/10.1002/adma.201870350
  3. V. Rosca, M. Duca, M.T. de Groot, M.T.M. Koper, Nitrogen cycle electrocatalysis. Chem. Rev. 6, 2209–2244 (2009). https://doi.org/10.1021/cr8003696
  4. C.D. Lv, C.S. Yan, G. Chen, Y. Ding, J.X. Sun, Y.S. Zhou, G.H. Yu, An amorphous noble-metal-free electrocatalyst that enables nitrogen fixation under ambient conditions. Angew. Chem. Int. Ed. 21, 6073–6076 (2018). https://doi.org/10.1002/anie.201801538
  5. C.J.M. Van der Ham, M.T.M. Koper, D.G.H. Hetterscheid, Challenges in reduction of dinitrogen by proton and electron transfer. Chem. Soc. Rev. 15, 5183–5191 (2014). https://doi.org/10.1039/C4CS00085D
  6. H.V. Doan, H.A. Hamzah, P.K. Prabhakaran, C. Petrillo, V.P. Ting, Hierarchical metal–organic frameworks with macroporosity: synthesis, achievements, and challenges. Nano-Micro Lett. 11, 54 (2019). https://doi.org/10.1007/s40820-019-0286-9
  7. H.J. Wang, H.J. Yu, Z.Q. Wang, Y.H. Li, Y. Xu, X.N. Li, H.R. Xue, L. Wang, Electrochemical fabrication of porous Au film on Ni foam for nitrogen reduction to ammonia. Small 6, 1804769 (2019). https://doi.org/10.1002/smll.201804769
  8. G.F. Chen, X.R. Cao, S.Q. Wu, X.Y. Zeng, L.X. Ding, M. Zhu, H.H. Wang, Ammonia electrosynthesis with high selectivity under ambient conditions via a Li+ incorporation strategy. J. Am. Chem. Soc. 29, 9771–9774 (2017). https://doi.org/10.1021/jacs.7b04393
  9. M.M. Shi, D. Bao, B.R. Wulan, Y.H. Li, Y.F. Zhang, J.M. Yan, Q. Jiang, Au sub-nanoclusters on TiO2 toward highly efficient and selective electrocatalyst for N2 conversion to NH3 at ambient conditions. Adv. Mater. 17, 1606550 (2017). https://doi.org/10.1002/adma.201606550
  10. M. Bat-Erdene, G.R. Xu, M. Batmunkh, A.S.R. Bati, J.J. White et al., Surface oxidized two-dimensional antimonene nanosheets for electrochemical ammonia synthesis under ambient conditions. J. Mater. Chem. A 9, 4735–4739 (2020). https://doi.org/10.1039/C9TA13485A
  11. Y.F. Li, T.S. Li, X.J. Zhu, A.A. Alshehri, K.A. Alzahrani, S.Y. Lu, X.P. Sun, DyF3: an efficient electrocatalyst for N2 fixation to NH3 under ambient conditions. Chem. Asian J. 4, 487–489 (2020). https://doi.org/10.1002/asia.201901624
  12. M.G. Wu, J.Q. Liao, L.X. Yu, R.T. Lv, P. Li et al., 2020 Roadmap on carbon materials for energy storage and conversion. Chem. Asian J. 15(7), 995–1013 (2020). https://doi.org/10.1002/asia.201901802
  13. X.H. Guo, Y.P. Zhu, T.Y. Ma, Lowering reaction temperature: electrochemical ammonia synthesis by coupling various electrolytes and catalysts. J. Energy Chem. 6, 1107–1116 (2017). https://doi.org/10.1016/j.jechem.2017.09.012
  14. C.Y. Ling, X.W. Bai, Y.X. Ouyang, A.J. Du, J.L. Wang, Single molybdenum atom anchored on N-doped carbon as a promising electrocatalyst for nitrogen reduction into ammonia at ambient conditions. J. Phys. Chem. C 29, 16842–16847 (2018). https://doi.org/10.1021/acs.jpcc.8b05257
  15. T.W. He, S.K. Matta, A.J. Du, Single tungsten atom supported on N-doped graphyne as a high-performance electrocatalyst for nitrogen fixation under ambient conditions. Phys. Chem. Chem. Phys. 3, 1546–1551 (2019). https://doi.org/10.1039/C8CP06978F
  16. Y. Yao, H.J. Wang, X.Z. Yuan, H. Li, M.H. Shao, Electrochemical nitrogen reduction reaction on ruthenium. ACS Energy Lett. 6, 1336–1341 (2019). https://doi.org/10.1021/acsenergylett.9b00699
  17. H.J. Wang, Y.H. Li, C.J. Li, K. Deng, Z.Q. Wang, Y. Xu, X.N. Li, H.R. Xue, L. Wang, One-pot synthesis of bi-metallic PdRu tripods as an efficient catalyst for electrocatalytic nitrogen reduction to ammonia. J. Mater. Chem. A 2, 801–805 (2019). https://doi.org/10.1039/C8TA09482A
  18. D.S. Yang, T. Chen, Z.J. Wang, Electrochemical reduction of aqueous nitrogen (N2) at a low overpotential on (110)-oriented Mo nanofilm. J. Mater. Chem. A 36, 18967–18971 (2017). https://doi.org/10.1039/C7TA06139K
  19. H.T. Du, X.X. Guo, R.M. Kong, F.L. Qu, Cr2O3 nanofiber: a high-performance electrocatalyst toward artificial N2 fixation to NH3 under ambient conditions. Chem. Commun. 91, 12848–12851 (2018). https://doi.org/10.1039/C8CC07186A
  20. K. Chu, Y.P. Liu, J. Wang, H. Zhang, NiO nanodots on graphene for efficient electrochemical N2 reduction to NH3. ACS Appl. Energy Mater. 3, 2288–2295 (2019). https://doi.org/10.1021/acsaem.9b00102
  21. T. Xu, D.W. Ma, C.B. Li, Q. Liu, S.Y. Lu, A.M. Asiri, C. Yang, X.P. Sun, Ambient electrochemical NH3 synthesis from N2 and water enabled by ZrO2 nanoparticles. Chem. Commun. 25, 3673–3676 (2020). https://doi.org/10.1039/C9CC10087C
  22. X.H. Li, X. Ren, X.J. Liu, J.X. Zhao, X. Sun et al., A MoS2 nanosheet–reduced graphene oxide hybrid: an efficient electrocatalyst for electrocatalytic N2 reduction to NH3 under ambient conditions. J. Mater. Chem. A 6, 2524–2528 (2019). https://doi.org/10.1039/C8TA10433F
  23. P.X. Li, W.Z. Fu, P.Y. Zhuang, Y.D. Cao, C. Tang et al., Amorphous Sn/crystalline SnS2 nanosheets via in situ electrochemical reduction methodology for highly efficient ambient N2 fixation. Small 40, 1902535 (2019). https://doi.org/10.1002/smll.201902535
  24. H.Y. Jin, L.Q. Li, X. Liu, C. Tang, W.J. Xu et al., Nitrogen vacancies on 2D layered W2N3: a stable and efficient active site for nitrogen reduction reaction. Adv. Mater. 32, 1902709 (2019). https://doi.org/10.1002/adma.201902709
  25. G.F. Chen, S.Y. Ren, L.L. Zhang, H. Cheng, Y.R. Luo, K.H. Zhu, L.X. Ding, H.H. Wang, Nitrogen reduction reactions: advances in electrocatalytic N2 reduction—strategies to tackle the selectivity challenge. Small Methods 6, 1970016 (2019). https://doi.org/10.1002/smtd.201970016
  26. J.H. Montoya, C. Tsai, A. Vojvodic, J.K. Nørskov, The challenge of electrochemical ammonia synthesis: a new perspective on the role of nitrogen scaling relations. Chemsuschem 13, 2180–2186 (2015). https://doi.org/10.1002/cssc.201500322
  27. Z. Wang, F. Gong, L. Zhang, R. Wang, L. Ji et al., Electrocatalytic hydrogenation of N2 to NH3 by MnO: experimental and theoretical investigations. Adv. Sci. 1, 1801182 (2019). https://doi.org/10.1002/advs.201801182
  28. Y. Wang, M.M. Shi, D. Bao, F.L. Meng, Q. Zhang et al., Generating defect-rich bismuth for enhancing the rate of nitrogen electroreduction to ammonia. Angew. Chem. Int. Ed. 28, 9464–9469 (2019). https://doi.org/10.1002/anie.201903969
  29. Y.C. Hao, Y. Guo, L.W. Chen, M. Shu, X.Y. Wang et al., Promoting nitrogen electroreduction to ammonia with bismuth nanocrystals and potassium cations in water. Nat. Catal. 5, 448–456 (2019). https://doi.org/10.1038/s41929-019-0241-7
  30. F.Y. Wang, X. Lv, X.J. Zhu, J. Du, S.Y. Lu et al., Bi nanodendrites for efficient electrocatalytic N2 fixation to NH3 under ambient conditions. Chem. Commun. 14, 2107–2110 (2020). https://doi.org/10.1039/C9CC09803H
  31. L.Q. Li, C. Tang, B.Q. Xia, H.Y. Jin, Y. Zheng, S.Z. Qiao, Two-dimensional mosaic bismuth nanosheets for highly selective ambient electrocatalytic nitrogen reduction. ACS Catal. 4, 2902–2908 (2019). https://doi.org/10.1021/acscatal.9b00366
  32. Y. Peng, M. Yan, Q.G. Chen, C.M. Fan, H.Y. Zhou, A.W. Xu, Novel one-dimensional Bi2O3–Bi2WO6 p–n hierarchical heterojunction with enhanced photocatalytic activity. J. Mater. Chem. A 22, 8517–8524 (2014). https://doi.org/10.1039/C4TA00274A
  33. H.J. Lu, Q. Hao, T. Chen, L.H. Zhang, D.M. Chen, C. Ma, W.Q. Yao, Y.F. Zhu, A high-performance Bi2O3/Bi2SiO5 p–n heterojunction photocatalyst induced by phase transition of Bi2O3. Appl. Catal. B-Environ. (2018). https://doi.org/10.1016/j.apcatb.2018.05.069
  34. S. Sanna, V. Esposito, J.W. Andreasen, J. Hjelm, W. Zhang et al., Enhancement of the chemical stability in confined δ-Bi2O3. Nat. Mater. 5, 500–504 (2015). https://doi.org/10.1038/nmat4266
  35. Y. Song, X. Cai, X.X. Xu, X.X. Liu, Integration of nickel–cobalt double hydroxide nanosheets and polypyrrole films with functionalized partially exfoliated graphite for asymmetric supercapacitors with improved rate capability. J. Mater. Chem. A 28, 14712–14720 (2015). https://doi.org/10.1039/C5TA02810H
  36. J.H. Cao, K.X. Wang, J.Y. Chen, C.J. Lei, B. Yang, Z.J. Li, L.C. Lei, Y. Hou, K. Ostrikov, Nitrogen-doped carbon-encased bimetallic selenide for high-performance water electrolysis. Nano-Micro Lett. 11, 67 (2019). https://doi.org/10.1007/s40820-019-0299-4
  37. Y.L. Yang, Y. Tang, H.M. Jiang, Y.M. Chen, P.Y. Wan et al., 2020 Roadmap on gas-involved photo- and electro-catalysis. Chin. Chem. Lett. 12, 2089–2109 (2019). https://doi.org/10.1016/j.cclet.2019.10.041
  38. Y.W. Cheng, H.B. Zhang, C.V. Varanasi, J. Liu, Improving the performance of cobalt–nickel hydroxide-based self-supporting electrodes for supercapacitors using accumulative approaches. Energy Environ. Sci. 11, 3314–3321 (2013). https://doi.org/10.1039/C3EE41143E
  39. D. Chen, L.H. Tang, J.H. Li, Graphene-based materials in electrochemistry. Chem. Soc. Rev. 8, 3157–3180 (2010). https://doi.org/10.1039/B923596E
  40. S. Mukherjee, Z. Ren, G. Singh, Beyond graphene anode materials for emerging metal ion batteries and supercapacitors. Nano-Micro Lett. 10, 70 (2018). https://doi.org/10.1007/s40820-018-0224-2
  41. Y. Sun, W. Zhang, J. Tong, Y. Zhang, S.Y. Wu et al., Significant enhancement of visible light photocatalytic activity of the hybrid B12-PIL/rGO in the presence of Ru(bpy)2+3 for DDT dehalogenation. RSC Adv. 31, 19197–19204 (2017). https://doi.org/10.1039/C7RA02062G
  42. Y.L. Yang, M.G. Wu, X.W. Zhu, H. Xu, S. Ma et al., 2020 Roadmap on two-dimensional nanomaterials for environmental catalysis. Chin. Chem. Lett. 12, 2065–2088 (2019). https://doi.org/10.1016/j.cclet.2019.11.001
  43. Y.B. Xu, Y. Song, Z.G. Zhang, A binder-free fluidizable Mo/HZSM-5 catalyst for non-oxidative methane dehydroaromatization in a dual circulating fluidized bed reactor system. Catal. Today (2017). https://doi.org/10.1016/j.cattod.2016.03.037
  44. C.H. Jiang, Z.X. Ye, H.T. Ye, Z.M. Zou, Li4Ti5O12@carbon cloth composite with improved mass loading achieved by a hierarchical polypyrrole interlayer assisted hydrothermal process for robust free-standing sodium storage. Appl. Surf. Sci. (2020). https://doi.org/10.1016/j.apsusc.2019.144464
  45. J.C. Liu, H. Li, M. Batmunkh, X. Xiao, Y. Sun, Q. Zhao, X. Liu, Z.H. Huang, T.Y. Ma, Structural engineering to maintain the superior capacitance of molybdenum oxides at ultrahigh mass loadings. J. Mater. Chem. A 41, 23941–23948 (2019). https://doi.org/10.1039/C9TA04835A
  46. B. Yu, H. Li, J. White, S. Donne, J.B. Yi et al., Tuning the catalytic preference of ruthenium catalysts for nitrogen reduction by atomic dispersion. Adv. Funct. Mater. 6, 1905665 (2020). https://doi.org/10.1002/adfm.201905665
  47. S.B. Liu, X.F. Lu, J. Xiao, X. Wang, X.W. Lou, Bi2O3 nanosheets grown on multi-channel carbon matrix to catalyze efficient CO2 electroreduction to HCOOH. Angew. Chem. Int. Ed. 39, 13828–13833 (2019). https://doi.org/10.1002/anie.201907674
  48. Q. Qin, M. Oschatz, Overcoming chemical inertness under ambient conditions: a critical view on recent developments in ammonia synthesis via electrochemical N2 reduction by asking five questions. ChemElectroChem 4, 878–889 (2020). https://doi.org/10.1002/celc.201901970
  49. D. Bao, Q. Zhang, F.L. Meng, H.X. Zhong, M.M. Shi et al., Electrochemical reduction of N2 under ambient conditions for artificial N2 fixation and renewable energy storage using N2/NH3 cycle. Adv. Mater. 3, 1604799 (2017). https://doi.org/10.1002/adma.201604799
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