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Vol. 2 No. 4 (2010)

Poly(Glycidyl Methacrylates)-grafted Zinc Oxide Nanowire by Surface-initiated Atom Transfer Radical Polymerization

https://doi.org/10.1007/BF03353856
Bao Zhang
Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, National Key Laboratory of Nano/Micro Fabrication Technology, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China
Nantao Hu
Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, National Key Laboratory of Nano/Micro Fabrication Technology, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China
Yanfang Wang
Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, National Key Laboratory of Nano/Micro Fabrication Technology, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China
Zi Wang
Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, National Key Laboratory of Nano/Micro Fabrication Technology, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China
Ying Wang
Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, National Key Laboratory of Nano/Micro Fabrication Technology, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China
Eric S. Kong
Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, National Key Laboratory of Nano/Micro Fabrication Technology, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China
Yafei Zhang
Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, National Key Laboratory of Nano/Micro Fabrication Technology, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Corresponding Author: Yafei Zhang

yfzhang@sjtu.edu.cn

Nano-Micro Letters, Vol. 2 No. 4 (2010), Article Number: 285-289

Abstract

Poly(glycidyl methacrylates) (PGMA) was grafted from zinc oxide (ZnO) nanowires via surface-initiated atom transfer radical polymerization (SI-ATRP) technique. Firstly, the ZnO nanowires were synthesized by the one-pot hydrothermal technique. Subsequently, the ZnO was functionalized with 3-aminopropyl triethoxysilane, which was converted to macroinitiator by the esterification of them with 2-bromopropionyl bromide. PGMA grafted ZnO nanowires (PGMA-ZnO) were then synthesized in an ATRP of the GMA with CuCl/2, 2`-bipyridine as the catalyst system. Kinetics studies revealed an approximate linear increase in weight of polymer with reaction time, indicating that the polymerization process owned some “living” character. The structure and composition of PGMA-ZnO were characterized with scanning electron microscope (SEM), energy-dispersive X-ray (EDX) spectrometer, fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA).

Keywords

ATRP Glycidyl methacrylates Surface-initiated Zinc oxide nanowires
Zhang, Bao, Nantao Hu, Yanfang Wang, Zi Wang, Ying Wang, Eric S. Kong, and Yafei Zhang. 2011. “Poly(Glycidyl Methacrylates)-Grafted Zinc Oxide Nanowire by Surface-Initiated Atom Transfer Radical Polymerization”. Nano-Micro Letters 2 (4):285-89. https://doi.org/10.1007/BF03353856.
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