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Vol. 14 (2022)

One-Dimensional Magnetic FeCoNi Alloy Toward Low-Frequency Electromagnetic Wave Absorption

https://doi.org/10.1007/s40820-022-00920-7
Bintong Yang
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Materials Science, Fudan University, Shanghai 200438, People’s Republic of China
Jiefeng Fang
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Materials Science, Fudan University, Shanghai 200438, People’s Republic of China
Chunyang Xu
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Materials Science, Fudan University, Shanghai 200438, People’s Republic of China
Hui Cao
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Materials Science, Fudan University, Shanghai 200438, People’s Republic of China
Ruixuan Zhang
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Materials Science, Fudan University, Shanghai 200438, People’s Republic of China
Biao Zhao
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Materials Science, Fudan University, Shanghai 200438, People’s Republic of China
Mengqiu Huang
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Materials Science, Fudan University, Shanghai 200438, People’s Republic of China
Xiangyu Wang
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Materials Science, Fudan University, Shanghai 200438, People’s Republic of China
Hualiang Lv
Willian G. Lowrie Department of Chemical and Biomolecular Engineering, The Ohio State University, Columbus, OH 43210, USA
Renchao Che
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Materials Science, Fudan University, Shanghai 200438, People’s Republic of China

Corresponding Author: Renchao Che

rcche@fudan.edu.cn

Nano-Micro Letters, Vol. 14 (2022), Article Number: 170

Abstract

Rational designing of one-dimensional (1D) magnetic alloy to facilitate electromagnetic (EM) wave attenuation capability in low-frequency (2–6 GHz) microwave absorption field is highly desired but remains a significant challenge. In this study, a composite EM wave absorber made of a FeCoNi medium-entropy alloy embedded in a 1D carbon matrix framework is rationally designed through an improved electrospinning method. The 1D-shaped FeCoNi alloy embedded composite demonstrates the high-density and continuous magnetic network using off-axis electronic holography technique, indicating the excellent magnetic loss ability under an external EM field. Then, the in-depth analysis shows that many factors, including 1D anisotropy and intrinsic physical features of the magnetic medium-entropy alloy, primarily contribute to the enhanced EM wave absorption performance. Therefore, the fabricated EM wave absorber shows an increasing effective absorption band of 1.3 GHz in the low-frequency electromagnetic field at an ultrathin thickness of 2 mm. Thus, this study opens up a new method for the design and preparation of high-performance 1D magnetic EM absorbers.


Highlights:


1 A novel FeCoNi carbon fiber (FeCoNi/CF) is obtained through an improved electrospinning technology, which greatly endows the fiber with strong magnetic property.
2 The FeCoNi/CF exhibits an enhanced electromagnetic loss capability due to the construction of one-dimensional magnetic FeCoNi alloy.
3 The designed one-dimensional FeCoNi/CF exhibits excellent performance, with a broad effective absorption band of 1.3 GHz in the low-frequency electromagnetic field at an ultrathin thickness of 2 mm, which provides a great potential for practical application in the future.

Keywords

Medium-entropy magnetic alloy One-dimension Off-axis electronic holography technique Improved electrospinning Lower-frequency electromagnetic wave absorption
Yang, Bintong, Jiefeng Fang, Chunyang Xu, Hui Cao, Ruixuan Zhang, Biao Zhao, Mengqiu Huang, Xiangyu Wang, Hualiang Lv, and Renchao Che. 2022. “One-Dimensional Magnetic FeCoNi Alloy Toward Low-Frequency Electromagnetic Wave Absorption”. Nano-Micro Letters 14 (August):170. https://doi.org/10.1007/s40820-022-00920-7.
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