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Vol. 14 (2022)

Metal–Organic Framework Materials for Electrochemical Supercapacitors

https://doi.org/10.1007/s40820-022-00910-9
Ziwei Cao
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People’s Republic of China
Roya Momen
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People’s Republic of China
Shusheng Tao
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People’s Republic of China
Dengyi Xiong
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People’s Republic of China
Zirui Song
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People’s Republic of China
Xuhuan Xiao
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People’s Republic of China
Wentao Deng
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People’s Republic of China
Hongshuai Hou
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People’s Republic of China
Sedat Yasar
Department of Chemistry, Faculty of Science, Inonu University, 44280 Battalgazi, Malatya, Turkey
Sedar Altin
Physics Department, Inonu University, 44280 Malatya, Turkey
Faith Bulut
Physics Department, Inonu University, 44280 Malatya, Turkey
Guoqiang Zou
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People’s Republic of China
Xiaobo Ji
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People’s Republic of China

Corresponding Author: Guoqiang Zou

gq-zou@csu.edu.cn

Nano-Micro Letters, Vol. 14 (2022), Article Number: 181

Abstract

Exploring new materials with high stability and capacity is full of challenges in sustainable energy conversion and storage systems. Metal–organic frameworks (MOFs), as a new type of porous material, show the advantages of large specific surface area, high porosity, low density, and adjustable pore size, exhibiting a broad application prospect in the field of electrocatalytic reactions, batteries, particularly in the field of supercapacitors. This comprehensive review outlines the recent progress in synthetic methods and electrochemical performances of MOF materials, as well as their applications in supercapacitors. Additionally, the superiorities of MOFs-related materials are highlighted, while major challenges or opportunities for future research on them for electrochemical supercapacitors have been discussed and displayed, along with extensive experimental experiences.


Highlights:


1 The classification of metal–organic frameworks (MOFs) is summarized: MOFs can be divided into one, two and three dimensions based on the skeletal structure, MOFs can be divided into isoreticular metal organic frameworks, zeolitic imidazolate frameworks, and so on according to the ligand.
2 The preparation methods of MOFs are reviewed, which can be divided into traditional one pot method and the emerging preparation methods.
3 The application of MOF materials, MOF composite materials, and MOFs-derived materials in supercapacitor is emphasized.

Keywords

Metal–organic frameworks (MOFs) Electrochemistry Supercapacitors Electrode materials
Cao, Ziwei, Roya Momen, Shusheng Tao, Dengyi Xiong, Zirui Song, Xuhuan Xiao, Wentao Deng, Hongshuai Hou, Sedat Yasar, Sedar Altin, Faith Bulut, Guoqiang Zou, and Xiaobo Ji. 2022. “Metal–Organic Framework Materials for Electrochemical Supercapacitors”. Nano-Micro Letters 14 (September):181. https://doi.org/10.1007/s40820-022-00910-9.
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