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Vol. 16 (2024)

Constructed Mott–Schottky Heterostructure Catalyst to Trigger Interface Disturbance and Manipulate Redox Kinetics in Li-O2 Battery

https://doi.org/10.1007/s40820-024-01476-4
Yongji Xia
State Key Lab of Physical Chemistry of Solid Surface, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University, Xiamen 361005, People’s Republic of China
Le Wang
State Key Lab of Physical Chemistry of Solid Surface, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University, Xiamen 361005, People’s Republic of China
Guiyang Gao
State Key Lab of Physical Chemistry of Solid Surface, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University, Xiamen 361005, People’s Republic of China
Tianle Mao
State Key Lab of Physical Chemistry of Solid Surface, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University, Xiamen 361005, People’s Republic of China
Zhenjia Wang
State Key Lab of Physical Chemistry of Solid Surface, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University, Xiamen 361005, People’s Republic of China
Xuefeng Jin
State Key Lab of Physical Chemistry of Solid Surface, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University, Xiamen 361005, People’s Republic of China
Zheyu Hong
State Key Lab of Physical Chemistry of Solid Surface, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University, Xiamen 361005, People’s Republic of China
Jiajia Han
State Key Lab of Physical Chemistry of Solid Surface, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University, Xiamen 361005, People’s Republic of China
Dong‑Liang Peng
State Key Lab of Physical Chemistry of Solid Surface, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University, Xiamen 361005, People’s Republic of China
Guanghui Yue
State Key Lab of Physical Chemistry of Solid Surface, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University, Xiamen 361005, People’s Republic of China

Corresponding Author: Guanghui Yue

yuegh@xmu.edu.cn

Nano-Micro Letters, Vol. 16 (2024), Article Number: 258

Abstract

Lithium-oxygen batteries (LOBs) with high energy density are a promising advanced energy storage technology. However, the slow cathodic redox kinetics during cycling causes the discharge products to fail to decompose in time, resulting in large polarization and battery failure in a short time. Therefore, a self-supporting interconnected nanosheet array network NiCo2O4/MnO2 with a Mott–Schottky heterostructure on titanium paper (TP-NCO/MO) is ingeniously designed as an efficient cathode catalyst material for LOBs. This heterostructure can accelerate electron transfer and influence the charge transfer process during adsorption of intermediate by triggering the interface disturbance at the heterogeneous interface, thus accelerating oxygen reduction and oxygen evolution kinetics and regulating product decomposition, which is expected to solve the above problems. The meticulously designed unique structural advantages enable the TP-NCO/MO cathode catalyst to exhibit an astounding ultra-long cycle life of 800 cycles and an extraordinarily low overpotential of 0.73 V. This study utilizes a simple method to cleverly regulate the morphology of the discharge products by constructing a Mott–Schottky heterostructure, providing important reference for the design of efficient catalysts aimed at optimizing the adsorption of reaction intermediates.


Highlights:
1 A carbon free self supported Mott-Schottky heterostructure was constructed as an efficient cathode catalyst for lithium oxygen batteries, achieving homogeneous contact between the two materials for strong interfacial interactions.
2 The heterostructure triggered interfacial perturbations and band structure changes, which accelerated oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) kinetics, resulting in an extremely long cycle life of 800 cycles and an extremely low overpotential of 0.73 V.
3 Combined with advanced characterization techniques and density functional theory calculations, the underlying mechanism behind the boosted ORR/OER activities and the electrocatalytic mechanism were revealed.

Keywords

Mott–Schottky heterostructure Lithium-oxygen batteries Electrocatalysts Electrodeposition
Xia, Yongji, Le Wang, Guiyang Gao, Tianle Mao, Zhenjia Wang, Xuefeng Jin, Zheyu Hong, Jiajia Han, Dong‑Liang Peng, and Guanghui Yue. 2024. “Constructed Mott–Schottky Heterostructure Catalyst to Trigger Interface Disturbance and Manipulate Redox Kinetics in Li-O2 Battery”. Nano-Micro Letters 16 (July):258. https://doi.org/10.1007/s40820-024-01476-4.
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