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Vol. 12 (2020)

Hollow Bio-derived Polymer Nanospheres with Ordered Mesopores for Sodium-Ion Battery

https://doi.org/10.1007/s40820-020-0370-1
Yan Ai
State Key Laboratory of Precision Spectroscopy and Department of Materials, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, People’s Republic of China
Yuxiu You
Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Facai Wei
State Key Laboratory of Precision Spectroscopy and Department of Materials, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, People’s Republic of China
Xiaolin Jiang
State Key Laboratory of Precision Spectroscopy and Department of Materials, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, People’s Republic of China
Zhuolei Han
State Key Laboratory of Precision Spectroscopy and Department of Materials, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, People’s Republic of China
Jing Cui
State Key Laboratory of Precision Spectroscopy and Department of Materials, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, People’s Republic of China
Hao Luo
State Key Laboratory of Precision Spectroscopy and Department of Materials, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, People’s Republic of China
Yucen Li
State Key Laboratory of Precision Spectroscopy and Department of Materials, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, People’s Republic of China
Zhixin Xu
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Shunqi Xu
Center for Advancing Electronics Dresden (cfaed) and Department of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany
Jun Yang
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Qinye Bao
State Key Laboratory of Precision Spectroscopy and Department of Materials, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, People’s Republic of China
Chengbin Jing
State Key Laboratory of Precision Spectroscopy and Department of Materials, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, People’s Republic of China
Jianwei Fu
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450052, People’s Republic of China
Jiangong Cheng
State Key Lab of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, People’s Republic of China
Shaohua Liu
State Key Laboratory of Precision Spectroscopy and Department of Materials, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, People’s Republic of China

Corresponding Author: Shaohua Liu

shliu@phy.ecnu.edu.cn

Nano-Micro Letters, Vol. 12 (2020), Article Number: 31

Abstract

Bio-inspired hierarchical self-assembly provides elegant and powerful bottom-up strategies for the creation of complex materials. However, the current self-assembly approaches for natural bio-compounds often result in materials with limited diversity and complexity in architecture as well as microstructure. Here, we develop a novel coordination polymerization-driven hierarchical assembly of micelle strategy, using phytic acid-based natural compounds as an example, for the spatially controlled fabrication of metal coordination bio-derived polymers. The resultant ferric phytate polymer nanospheres feature hollow architecture, ordered meso-channels of ~ 12 nm, high surface area of 401 m2 g−1, and large pore volume of 0.53 cm3 g−1. As an advanced anode material, this bio-derivative polymer delivers a remarkable reversible capacity of 540 mAh g−1 at 50 mA g−1, good rate capability, and cycling stability for sodium-ion batteries. This study holds great potential of the design of new complex bio-materials with supramolecular chemistry.


Highlights:


1 A novel coordination polymerization-driven hierarchical assembly approach for spatially controlled fabrication of phytic acid-based bio-derivatives was developed.
2 The resultant ferric phytate bio-derived polymer featured hollow nanosphere architecture, ordered meso-channels, high surface area, and large pore volume, as anode material, delivering a remarkable electrochemical performance.

Keywords

Self-assembly Biomimetic synthesis Mesoporous polymer Ferric phytate Sodium-ion battery
Ai, Yan, Yuxiu You, Facai Wei, Xiaolin Jiang, Zhuolei Han, Jing Cui, Hao Luo, Yucen Li, Zhixin Xu, Shunqi Xu, Jun Yang, Qinye Bao, Chengbin Jing, Jianwei Fu, Jiangong Cheng, and Shaohua Liu. 2020. “Hollow Bio-Derived Polymer Nanospheres With Ordered Mesopores for Sodium-Ion Battery”. Nano-Micro Letters 12 (January):31. https://doi.org/10.1007/s40820-020-0370-1.
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