Issue

Vol. 13 (2021)

MoS2-Decorated/Integrated Carbon Fiber: Phase Engineering Well-Regulated Microwave Absorber

https://doi.org/10.1007/s40820-021-00646-y
Jing Yan
MOE Key Laboratory of Material Physics and Chemistry Under Extraodinary Conditions School of Chemistry and Chemical Engineering, Ministry of Education, Northwestern Polytechnical University, Xi’an 710072, People’s Republic of China
Ying Huang
MOE Key Laboratory of Material Physics and Chemistry Under Extraodinary Conditions School of Chemistry and Chemical Engineering, Ministry of Education, Northwestern Polytechnical University, Xi’an 710072, People’s Republic of China
Xiangyong Zhang
School of Materials Science and Engineering, Central South University, Changsha 410083, People’s Republic of China
Xin Gong
Institute of Flexible Electronics, Northwestern Polytechnical University, Xi’an 710072, People’s Republic of China
Chen Chen
MOE Key Laboratory of Material Physics and Chemistry Under Extraodinary Conditions School of Chemistry and Chemical Engineering, Ministry of Education, Northwestern Polytechnical University, Xi’an 710072, People’s Republic of China
Guangdi Nie
Industrial Research Institute of Nonwovens and Technical Textiles, College of Textiles and Clothing, Qingdao University, Qingdao 266071, People’s Republic of China
Xudong Liu
MOE Key Laboratory of Material Physics and Chemistry Under Extraodinary Conditions School of Chemistry and Chemical Engineering, Ministry of Education, Northwestern Polytechnical University, Xi’an 710072, People’s Republic of China
Panbo Liu
MOE Key Laboratory of Material Physics and Chemistry Under Extraodinary Conditions School of Chemistry and Chemical Engineering, Ministry of Education, Northwestern Polytechnical University, Xi’an 710072, People’s Republic of China

Corresponding Author: Ying Huang

yingh@nwpu.edu.cn

Nano-Micro Letters, Vol. 13 (2021), Article Number: 114

Abstract

Phase engineering is an important strategy to modulate the electronic structure of molybdenum disulfide (MoS2). MoS2-based composites are usually used for the electromagnetic wave (EMW) absorber, but the effect of different phases on the EMW absorbing performance, such as 1T and 2H phase, is still not studied. In this work, micro-1T/2H MoS2 is achieved via a facile one-step hydrothermal route, in which the 1T phase is induced by the intercalation of guest molecules and ions. The EMW absorption mechanism of single MoS2 is revealed by presenting a comparative study between 1T/2H MoS2 and 2H MoS2. As a result, 1T/2H MoS2 with the matrix loading of 15% exhibits excellent microwave absorption property than 2H MoS2. Furthermore, taking the advantage of 1T/2H MoS2, a flexible EMW absorbers that ultrathin 1T/2H MoS2 grown on the carbon fiber also performs outstanding performance only with the matrix loading of 5%. This work offers necessary reference to improve microwave absorption performance by phase engineering and design a new type of flexible electromagnetic wave absorption material to apply for the portable microwave absorption electronic devices.


Highlights:


1 A facile one‐step hydrothermal method for producing gram‐scale 1T@2H-MoS2 by imbedding the guest molecules and ions was developed.
2 The influence of different MoS2 phase for electromagnetic absorbing properties was explored by analyzing electromagnetic parameters of 1T/2H MoS2 and 2H MoS2 with 50%, 40%, 30%, 20%, 15%, and 10% filler loading.
3 Taking the advantage of 1T/2H MoS2, the flexible CF@1T/2H MoS2 was also synthesized to mind the request of flexible portable microwave absorption electronic devices.

Keywords

Phase engineering Electromagnetic wave absorber 1T/2H MoS2 2H MoS2 Flexible film
Yan, Jing, Ying Huang, Xiangyong Zhang, Xin Gong, Chen Chen, Guangdi Nie, Xudong Liu, and Panbo Liu. 2021. “MoS2-Decorated/Integrated Carbon Fiber: Phase Engineering Well-Regulated Microwave Absorber”. Nano-Micro Letters 13 (April):114. https://doi.org/10.1007/s40820-021-00646-y.
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