Issue

Vol. 15 (2023)

Progression in the Oxidation Stability of MXenes

https://doi.org/10.1007/s40820-023-01069-7
Razium A. Soomro
State Key Laboratory of Organic‑Inorganic Composites, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, People’s Republic of China
Peng Zhang
State Key Laboratory of Organic‑Inorganic Composites, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, People’s Republic of China
Baomin Fan
College of Chemical and Materials Engineering, Beijing Technology and Business University, Beijing 100048, People’s Republic of China
Yi Wei
State Key Laboratory of Organic‑Inorganic Composites, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, People’s Republic of China
Bin Xu
State Key Laboratory of Organic‑Inorganic Composites, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, People’s Republic of China

Corresponding Author: Bin Xu

xubin@mail.buct.edu.cn

Nano-Micro Letters, Vol. 15 (2023), Article Number: 108

Abstract

MXenes are under the spotlight due to their versatile physicochemical characteristics. Since their discovery in 2011, significant advancements have been achieved in their synthesis and application sectors. However, the spontaneous oxidation of MXenes, which is critical to its processing and product lifespan, has gotten less attention due to its chemical complexity and poorly understood oxidation mechanism. This perspective focuses on the oxidation stability of MXenes and addresses the most recent advancements in understanding and the possible countermeasures to limit the spontaneous oxidation of MXenes. A section is dedicated to the presently accessible methods for monitoring oxidation, with a discussion on the debatable oxidation mechanism and coherently operating factors that contribute to the complexity of MXenes oxidation. The current potential solutions for mitigating MXenes oxidation and the existing challenges are also discussed with prospects to prolong MXene’s shelf-life storage and expand their application scope.


Highlights:


1 The progression of MXene's oxidation stability, the techniques available to monitor the phenomenon as well as the variables that contribute to its oxidation rate are discussed.
2 Comprehensive aspects of the oxidation process in various storage settings and the debated oxidation mechanism along with the most effective antioxidation strategies are addressed in conjunction with current challenges to the air stability of MXenes.

Keywords

MXenes Oxidation stability Antioxidation strategies Shelf-life of MXenes
Soomro, Razium A., Peng Zhang, Baomin Fan, Yi Wei, and Bin Xu. 2023. “Progression in the Oxidation Stability of MXenes”. Nano-Micro Letters 15 (April):108. https://doi.org/10.1007/s40820-023-01069-7.
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