Issue

Vol. 13 (2021)

Wire-in-Wire TiO2/C Nanofibers Free-Standing Anodes for Li-Ion and K-Ion Batteries with Long Cycling Stability and High Capacity

https://doi.org/10.1007/s40820-021-00632-4
Die Su
National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Yi Pei
Department of Materials Science and Engineering, University of Washington, Seattle, WA 98195‑2120, USA
Li Liu
National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Zhixiao Liu
College of Materials Science and Engineering, Hunan University, Changsha 410082, People’s Republic of China
Junfang Liu
National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Min Yang
National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Jiaxing Wen
National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Jing Dai
National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Huiqiu Deng
School of Physics and Electronics, Hunan University, Changsha 410082, People’s Republic of China
Guozhong Cao
Department of Materials Science and Engineering, University of Washington, Seattle, WA 98195‑2120, USA

Corresponding Author: Guozhong Cao

gzcao@uw.edu

Nano-Micro Letters, Vol. 13 (2021), Article Number: 107

Abstract

Wearable and portable mobile phones play a critical role in the market, and one of the key technologies is the flexible electrode with high specific capacity and excellent mechanical flexibility. Herein, a wire-in-wire TiO2/C nanofibers (TiO2 ww/CN) film is synthesized via electrospinning with selenium as a structural inducer. The interconnected carbon network and unique wire-in-wire nanostructure cannot only improve electronic conductivity and induce effective charge transports, but also bring a superior mechanic flexibility. Ultimately, TiO2 ww/CN film shows outstanding electrochemical performance as free-standing electrodes in Li/K ion batteries. It shows a discharge capacity as high as 303 mAh g−1 at 5 A g−1 after 6000 cycles in Li half-cells, and the unique structure is well-reserved after long-term cycling. Moreover, even TiO2 has a large diffusion barrier of K+, TiO2 ww/CN film demonstrates excellent performance (259 mAh g−1 at 0.05 A g−1 after 1000 cycles) in K half-cells owing to extraordinary pseudocapacitive contribution. The Li/K full cells consisted of TiO2 ww/CN film anode and LiFePO4/Perylene-3,4,9,10-tetracarboxylic dianhydride cathode possess outstanding cycling stability and demonstrate practical application from lighting at least 19 LEDs. It is, therefore, expected that this material will find broad applications in portable and wearable Li/K-ion batteries.


Highlights:


1 The unique wire-in-wire structure endows TiO2/C nanofibers film with superior mechanical flexibility.
2 The wire-in-wire TiO2/C nanofibers (TiO2 ww/CN) film shows outstanding electrochemical performances as free-standing anodes for Li/K-ion batteries and full cells.
3 The TiO2 ww/CN film shows an extremely high pseudocapacitance contribution ratio in K-ion batteries.

Keywords

Free-standing TiO2/C nanofiber Li-ion battery K-ion battery First-principles calculation Full cells
Su, Die, Yi Pei, Li Liu, Zhixiao Liu, Junfang Liu, Min Yang, Jiaxing Wen, Jing Dai, Huiqiu Deng, and Guozhong Cao. 2021. “Wire-in-Wire TiO2/C Nanofibers Free-Standing Anodes for Li-Ion and K-Ion Batteries With Long Cycling Stability and High Capacity”. Nano-Micro Letters 13 (April):107. https://doi.org/10.1007/s40820-021-00632-4.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. C. Lu, Z. Sun, L. Yu, X. Lian, Y. Yi et al., Enhanced kinetics harvested in heteroatom dual-doped graphitic hollow architectures toward high rate printable potassium-ion batteries. Adv. Energy Mater. 10, 2001161 (2020). https://doi.org/10.1002/aenm.202001161
  2. Y. Zhang, Y. Ouyang, L. Liu, J. Xia, S. Nie et al., Synthesis and characterization of Na0.44MnO2 nanorods/graphene composite as cathode materials for sodium-ion batteries. J. Cent. South Univ. 26, 1510–1520 (2019). https://doi.org/10.1007/s11771-019-4107-6
  3. R. Guo, X. Liu, B. Wen, F. Liu, J. Meng et al., Engineering mesoporous structure in amorphous carbon boosts potassium storage with high initial coulombic efficiency. Nano-Micro Lett. 12, 148 (2020). https://doi.org/10.1007/s40820-020-00481-7
  4. J. Wang, L. Fan, Z. Liu, S. Chen, Q. Zhang et al., In situ alloying strategy for exceptional potassium ion batteries. ACS Nano 13, 3703–3713 (2019). https://doi.org/10.1021/acsnano.9b00634
  5. L. Fan, R. Ma, J. Wang, H. Yang, B. Lu, An ultrafast and highly stable potassium-organic battery. Adv. Mater. 30, 1805486 (2018). https://doi.org/10.1021/acsnano.9b00634
  6. J. Xia, L. Liu, S. Jamil, J. Xie, H. Yan et al., Free-standing SnS/C nanofiber anodes for ultralong cycle-life lithium-ion batteries and sodium-ion batteries. Energy Storage Mater. 17, 1–11 (2019). https://doi.org/10.1016/j.ensm.2018.08.005
  7. L. Wang, G. Yang, J. Wang, S. Wang, C. Wang et al., In situ fabrication of branched TiO2/C nanofibers as binder-free and free-standing anodes for high-performance sodium-ion batteries. Small 15, 1901584 (2019). https://doi.org/10.1002/smll.201901584
  8. W.-C. Chang, J.-H. Wu, K.-T. Chen, H.-Y. Tuan, Red phosphorus potassium-ion battery anodes. Adv. Sci. 6, 1801354 (2019). https://doi.org/10.1002/advs.201801354
  9. I. Sultana, M.M. Rahman, T. Ramireddy, Y. Chen, A.M. Glushenkov, High capacity potassium-ion battery anodes based on black phosphorus. J. Mater. Chem. A 5, 23506–23512 (2017). https://doi.org/10.1039/c7ta02483e
  10. H. Luo, M. Chen, J. Cao, M. Zhang, S. Tan et al., Cocoon silk-derived, hierarchically porous carbon as anode for highly robust potassium-ion hybrid capacitors. Nano-Micro Lett. 12, 113 (2020). https://doi.org/10.1007/s40820-020-00454-w
  11. S. Nie, L. Liu, J. Liu, J. Xie, Y. Zhang et al., Nitrogen-doped TiO2-C composite nanofibers with high-capacity and long-cycle life as anode materials for sodium-ion batteries. Nano-Micro Lett. 10, 71 (2018). https://doi.org/10.1007/s40820-018-0225-1
  12. S. Rehman, J. Liu, Z. Fang, J. Wang, R. Ahmed et al., Heterostructured TiO2/C/Co from ZIF-67 frameworks for microwave-absorbing nanomaterials. ACS Appl. Nano Mater. 2, 4451–4461 (2019). https://doi.org/10.1021/acsanm.9b00841
  13. S. Nie, L. Liu, J. Liu, J. Xia, Y. Zhang et al., TiO2-Sn/C composite nanofibers with high-capacity and long-cycle life as anode materials for sodium ion batteries. J. Alloys Compd. 772, 314–323 (2019). https://doi.org/10.1016/j.jallcom.2018.09.044
  14. S. Huang, L. Zhang, X. Lu, L. Liu, X. Liu et al., Tunable pseudocapacitance in 3D TiO2−δ nanomembranes enabling superior lithium storage performance. ACS Nano 11, 821–830 (2017). https://doi.org/10.1021/acsnano.6b07274
  15. S. Chu, Y. Zhong, R. Cai, Z. Zhang, S. Wei et al., Mesoporous and nanostructured TiO2 layer with ultra-high loading on nitrogen-doped carbon foams as flexible and free-standing electrodes for lithium-ion batteries. Small 12, 6724–6734 (2016). https://doi.org/10.1002/smll.201602179
  16. G. Ren, M. Hoque, J. Liu, J. Warzywoda, Z. Fan, Perpendicular edge oriented graphene foam supporting orthogonal TiO2(B) nanosheets as freestanding electrode for lithium ion battery. Nano Energy 21, 162–171 (2016). https://doi.org/10.1016/j.nanoen.2016.01.010
  17. Y. Shi, D. Yang, R. Yu, Y. Liu, J. Qu et al., Efficient photocatalytic reduction approach for synthesizing chemically bonded N-doped TiO2/reduced graphene oxide hybrid as a freestanding electrode for high-performance Lithium storage. ACS Appl. Energy Mater. 1, 4186–4195 (2018). https://doi.org/10.1021/acsaem.8b00836
  18. Y. Li, C. Yang, F. Zheng, Q. Pan, Y. Liu et al., Design of TiO2eC hierarchical tubular heterostructures for high performance potassium ion batteries. Nano Energy 59, 582–590 (2019). https://doi.org/10.1016/j.nanoen.2019.03.002
  19. K.G. Reeves, J. Ma, M. Fukunishi, M. Salanne, S. Komaba et al., Insights into Li+, Na+, and K+ intercalation in lepidocrocite-type layered TiO2 structures. ACS Appl. Energy Mater. 1, 2078–2086 (2018). https://doi.org/10.1021/acsaem.8b00170
  20. Y. Fang, R. Hu, B. Liu, Y. Zhang, K. Zhu et al., MXene-derived TiO2/reduced graphene oxide composite with an enhanced capacitive capacity for Li-ion and K-ion batteries. J. Mater. Chem. A 7, 5363–5372 (2019). https://doi.org/10.1039/c8ta12069b
  21. G. Kresse, J. Hafner, Ab initio molecular dynamics for open-shell transition metals. Phys. Rev. B 48, 13115–13118 (1993). https://doi.org/10.1103/PhysRevB.48.13115
  22. G. Kresse, J. Furthmuller, Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 6, 15–50 (1996). https://doi.org/10.1016/0927-0256(96)00008-0
  23. P.E. Blochl, Projector augmented-wave method. Phys. Rev. B 50, 17953–17979 (1994). https://doi.org/10.1103/PhysRevB.50.17953
  24. J.P. Perdew, K. Burke, M. Ernzerhof, Generalized gradient approximation made simple. Phys. Rev. Lett. 77, 3865–3868 (1996). https://doi.org/10.1103/PhysRevLett.77.3865
  25. L. Shao, S. Quan, Y. Liu, Z. Guo, Z. Wang, A novel “gel–sol” strategy to synthesize TiO2 nanorod combining reduced graphene oxide composites. Mater. Lett. 107, 307–310 (2013). https://doi.org/10.1016/j.matlet.2013.06.050
  26. Y.-L. Huang, S.-M. Yuen, C.-C.M. Ma, C.-Y. Chuang, K.-C. Yu et al., Morphological, electrical, electromagnetic interference (EMI) shielding, and tribological properties of functionalized multi-walled carbon nanotube/poly methyl methacrylate (PMMA) composites. Compos. Sci. Technol. 69, 1991–1996 (2009). https://doi.org/10.1016/j.compscitech.2009.05.006
  27. H. Wang, Q. Wu, D. Cao, X. Lu, J. Wang et al., Synthesis of SnSb-embedded carbon-silica fibers via electrospinning: effect of TEOS on structural evolutions and electrochemical properties. Mater. Today Energy 1, 24–32 (2016). https://doi.org/10.1016/j.compscitech.2009.05.006
  28. X. Lu, H. Wang, Z. Wang, Y. Jiang, D. Cao et al., Room-temperature synthesis of colloidal SnO2 quantum dot solution and ex-situ deposition on carbon nanotubes as anode materials for lithium ion batteries. J. Alloys Compd. 680, 109–115 (2016). https://doi.org/10.1016/j.jallcom.2016.04.128
  29. D. Su, L. Liu, Z. Liu, J. Dai, J. Wen et al., Electrospun Ta-doped TiO2/C nanofibers as high-capacity and long-cycling anode materials for Li-ion and K-ion batteries. J. Mater. Chem. A 8, 20666–20676 (2020). https://doi.org/10.1039/D0TA06327D
  30. H. Fan, H. Yu, Y. Zhang, J. Guo, Z. Wang et al., 1D to 3D hierarchical iron selenide hollow nanocubes assembled from FeSe2@ C core-shell nanorods for advanced sodium ion batteries. Energy Storage Mater. 10, 48–55 (2018). https://doi.org/10.1016/j.ensm.2017.08.006
  31. H. Lin, M. Li, X. Yang, D. Yu, Y. Zeng et al., Nanosheets-assembled CuSe crystal pillar as a stable and high-power anode for sodium-ion and potassium-ion batteries. Adv. Energy Mater. 9, 1900323 (2019). https://doi.org/10.1002/aenm.201900323
  32. D. Su, J. Liu, Y. Pei, L. Liu, S. Nie et al., Electrospun Na doped Li2TiSiO5/C nanofibers with outstanding lithium-storage performance. Appl. Surf. Sci. 541, 148388 (2021). https://doi.org/10.1016/j.apsusc.2020.148388
  33. L. Su, J. Hei, X. Wu, L. Wang, Z. Zhou, Ultrathin layered hydroxide cobalt acetate nanoplates face-to-face anchored to graphene nanosheets for high-efficiency lithium storage. Adv. Funct. Mater. 27, 1605544 (2017). https://doi.org/10.1002/adfm.201605544
  34. J. Liu, D. Su, L. Liu, Z. Liu, S. Nie et al., Boosting the charge transfer of Li2TiSiO5 using nitrogen-doped carbon nanofibers: towards high-rate, long-life lithium-ion batteries. Nanoscale 12, 19702–19710 (2020). https://doi.org/10.1039/d0nr04618c
  35. D. Ying, R. Ding, Y. Huang, W. Shi, Q. Xu et al., An intercalation pseudocapacitance-driven perovskite NaNbO3 anode with superior kinetics and stability for advanced lithium-based dual-ion batteries. J. Mater. Chem. A 7, 18257–18266 (2019). https://doi.org/10.1039/C9TA06438A
  36. Q. Xu, R. Ding, W. Shi, D. Ying, Y. Huang et al., Perovskite KNi0.1Co0.9F3 as a pseudocapacitive conversion anode for high-performance nonaqueous Li-ion capacitors and dual-ion batteries. J. Mater. Chem. A 7, 8315–8326 (2019). https://doi.org/10.1039/C9TA00493A
  37. H. Yang, R. Xu, Y. Gong, Y. Yao, L. Gu et al., An interpenetrating 3D porous reticular Nb2O5@carbon thin film for superior sodium storage. Nano Energy 48, 448–455 (2018). https://doi.org/10.1016/j.nanoen.2018.04.006
  38. J. Ni, W. Wang, C. Wu, H. Liang, J. Maier et al., Energy storage: highly reversible and durable Na sorage in niobium pentoxide through optimizing structure, composition, and nanoarchitecture. Adv. Mater. 29, 1605607 (2017). https://doi.org/10.1002/adma.201770063
  39. X. Yan, Y. Li, M. Li, Y. Jin, F. Du et al., Ultrafast lithium storage in TiO2–bronze nanowires/N-doped graphene nanocomposites. J. Mater. Chem. A 3, 4180–4187 (2015). https://doi.org/10.1039/C4TA06361A
  40. Y. Jiang, S. Chen, D. Mu, Z. Zhao, C. Li et al., Flexible TiO2/SiO2/C film anodes for lithium-ion batteries. Chemsuschem 11, 2040–2044 (2018). https://doi.org/10.1002/cssc.201800560
  41. Y. Yue, D. Juarez-Robles, Y. Chen, L. Ma, W.C. Kuo et al., Hierarchical structured Cu/Ni/TiO2 nanocomposites as electrodes for lithium-ion batteries. ACS Appl. Mater. Interfaces 9, 28695–28703 (2017). https://doi.org/10.1021/acsami.7b10158
  42. C. Zhang, S. Liu, Y. Qi, F. Cui, X. Yang, Conformal carbon coated TiO2 aerogel as superior anode for lithium-ion batteries. Chem. Eng. J. 351, 825–831 (2018). https://doi.org/10.1016/j.cej.2018.06.125
  43. S. Anwer, Y. Huang, J. Liu, J. Liu, M. Xu et al., Nature-inspired Na2Ti3O7 nanosheets-formed three-dimensional microflowers architecture as a high-performance anode material for rechargeable sodium-ion batteries. ACS Appl. Mater. Interfaces 9, 11669–11677 (2017). https://doi.org/10.1021/acsami.7b01519
  44. D. Xu, C. Chen, J. Xie, A hierarchical N/S-codoped carbon anode fabricated facilely from cellulose/polyaniline microspheres for high-performance sodium-ion batteries. Adv. Energy Mater. 6, 1501929 (2016). https://doi.org/10.1002/aenm.201501929
  45. E. Liu, J. Wang, C. Shi, N. Zhao, C. He et al., Anomalous interfacial lithium storage in graphene/TiO2 for lithium ion batteries. ACS Appl. Mater. Interfaces 6, 18147–18151 (2014). https://doi.org/10.1021/am5050423
  46. Z. Bi, M.P. Paranthaman, B. Guo, R.R. Unocic, H.M. Meyer III. et al., High performance Cr, N-codoped mesoporous TiO2 microspheres for lithium-ion batteries. J. Mater. Chem. A 2, 1818–1824 (2014). https://doi.org/10.1039/c3ta14535b
  47. Y. Li, Y. Huang, Y. Zheng, R. Huang, J. Yao, Facile and efficient synthesis of α-Fe2O3 nanocrystals by glucose-assisted thermal decomposition method and its application in lithium ion batteries. J. Power Sources 416, 62–71 (2019). https://doi.org/10.1016/j.jpowsour.2019.01.080
  48. J. Sun, L. Guo, X. Sun, J. Zhang, L. Hou et al., One-dimensional nanostructured pseudocapacitive materials: design, synthesis and applications in supercapacitors. Batteries Supercaps 2, 820–841 (2019). https://doi.org/10.1002/batt.201900021
  49. C. Wang, J. Zhang, X. Wang, C. Lin, X. Zhao, Hollow rutile cuboid arrays grown on carbon fiber cloth as a flexible electrode for sodium-ion batteries. Adv. Funct. Mater. 30, 2002629 (2020). https://doi.org/10.1002/adfm.202002629
  50. C. Wang, X. Wang, C. Lin, X. Zhao, Lithium titanate cuboid arrays grown on carbon fiber cloth for high-rate fexible Lithium-ion batteries. Small 15, 1902183 (2019). https://doi.org/10.1002/smll.201902183
  51. C. Wang, X. Wang, C. Lin, S. Xiu, Spherical vanadium phosphate particles grown on carbon fiber cloth as flexible anode for high-rate Li-ion batteries. Chem. Eng. J. 15, 123981 (2020). https://doi.org/10.1016/j.cej.2019.123981
  52. Z. Wang, J. Sha, E. Liu, C. He, C. Shi et al., A large ultrathin anatase TiO2 nanosheet/reduced graphene oxide composite with enhanced lithium storage capability. J. Mater. Chem. A 2, 8893–8901 (2014). https://doi.org/10.1039/c4ta00574k
  53. Y. Yuan, F. Chen, S. Yin, L. Wang, M. Zhu et al., Foam-like, 3-dimension mesoporous N-doped carbon-assembling TiO2 nanoparticles (P25) as high-performance anode material for lithium-ion batteries. J. Power Sources 420, 38–45 (2019). https://doi.org/10.1016/j.jpowsour.2019.02.094
  54. N.Ž Knežević, E. Ruiz-Hernández, W.E. Hennink, M. Vallet-Regí, Magnetic mesoporous silica-based core/shell nanoparticles for biomedical applications. RSC Adv. 3, 9584–9593 (2013). https://doi.org/10.1039/c3ra23127e
  55. A. Auer, E. Portenkirchner, T. Götsch, C. Valero-Vidal, S. Penne et al., Preferentially oriented TiO2 nanotubes as anode material for Li-ion batteries: insight into Li-ion storage and Lithiation kinetics. ACS Appl. Mater. Interfaces 9, 36828–36836 (2017). https://doi.org/10.1021/acsami.7b11388
  56. K. Zhu, Y. Luo, F. Zhao, J. Hou, X. Wang et al., Free-standing, binder-free titania/super-aligned carbon nanotube anodes for flexible and fast-charging Li-ion batteries. ACS Sustain. Chem. Eng. 6, 3426–3433 (2018). https://doi.org/10.1021/acssuschemeng.7b03671
Read More
Author biographies are not available.
Statistic
Read Counter : 8947 Download : 6687

Most read articles by the same author(s)