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Vol. 12 (2020)

Hierarchical Self-assembly of Well-Defined Louver-Like P-Doped Carbon Nitride Nanowire Arrays with Highly Efficient Hydrogen Evolution

https://doi.org/10.1007/s40820-020-0399-1
Bo Li
Department of Applied Physics, College of Physics and Electronics, and College of Materials Science and Engineering, and State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People’s Republic of China
Yuan Si
Department of Applied Physics, College of Physics and Electronics, and College of Materials Science and Engineering, and State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People’s Republic of China
Qian Fang
Department of Applied Physics, College of Physics and Electronics, and College of Materials Science and Engineering, and State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People’s Republic of China
Ying Shi
Department of Physics and Tsinghua‑Foxconn Nanotechnology Research Center, Tsinghua University, Beijing 100084, People’s Republic of China
Wei‑Qing Huang
Department of Applied Physics, College of Physics and Electronics, and College of Materials Science and Engineering, and State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People’s Republic of China
Wangyu Hu
Department of Applied Physics, College of Physics and Electronics, and College of Materials Science and Engineering, and State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People’s Republic of China
Anlian Pan
Department of Applied Physics, College of Physics and Electronics, and College of Materials Science and Engineering, and State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People’s Republic of China
Xiaoxing Fan
College of Physics, Liaoning University, Shenyang 110036, People’s Republic of China
Gui‑Fang Huang
Department of Applied Physics, College of Physics and Electronics, and College of Materials Science and Engineering, and State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People’s Republic of China

Corresponding Author: Gui‑Fang Huang

gfhuang@hnu.edu.cn

Nano-Micro Letters, Vol. 12 (2020), Article Number: 52

Abstract

Self-assembled nanostructure arrays integrating the advantages of the intrinsic characters of nanostructure as well as the array stability are appealing in advanced materials. However, the precise bottom-up synthesis of nanostructure arrays without templates or substrates is quite challenging because of the general occurrence of homogeneous nucleation and the difficult manipulation of noncovalent interactions. Herein, we first report the precisely manipulated synthesis of well-defined louver-like P-doped carbon nitride nanowire arrays (L-PCN) via a supramolecular self-assembly method by regulating the noncovalent interactions through hydrogen bond. With this strategy, CN nanowires align in the outer frame with the separation and spatial location achieving ultrastability and outstanding photoelectricity properties. Significantly, this self-assembly L-PCN exhibits a superior visible light-driven hydrogen evolution activity of 1872.9 μmol h−1 g−1, rendering a ~ 25.6-fold enhancement compared to bulk CN, and high photostability. Moreover, an apparent quantum efficiency of 6.93% is achieved for hydrogen evolution at 420 ± 15 nm. The experimental results and first-principles calculations demonstrate that the remarkable enhancement of photocatalytic activity of L-PCN can be attributed to the synergetic effect of structural topology and dopant. These findings suggest that we are able to design particular hierarchical nanostructures with desirable performance using hydrogen-bond engineering.


Highlights:


1 The self-assembled louver-like P-doped carbon nitride (L-PCN) nanowires is firstly constructed.
2 L-PCN nanowires show efficient charge transport, as demonstrated by experimental and theoretical approach.
3 L-PCN nanowires exhibit significantly boosted HER activity of 1,872.9 μmol h−1 g−1 (λ > 420 nm).

Keywords

Self-assembly Carbon nitride P-doped Nanowire arrays Hydrogen evolution
Li, Bo, Yuan Si, Qian Fang, Ying Shi, Wei‑Qing Huang, Wangyu Hu, Anlian Pan, Xiaoxing Fan, and Gui‑Fang Huang. 2020. “Hierarchical Self-Assembly of Well-Defined Louver-Like P-Doped Carbon Nitride Nanowire Arrays With Highly Efficient Hydrogen Evolution”. Nano-Micro Letters 12 (February):52. https://doi.org/10.1007/s40820-020-0399-1.
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References
  1. T. Aida, E.W. Meijer, S.I. Stupp, Functional supramolecular polymers. Science 335(6070), 813–817 (2012). https://doi.org/10.1126/science.1205962
  2. X. Wang, P.Y. Gao, Y.Y. Yang, H.X. Guo, D.C. Wu, Dynamic and programmable morphology and size evolution via a living hierarchical self-assembly strategy. Nat. Commun. 9, 2772 (2018). https://doi.org/10.1038/s41467-018-05142-3
  3. L. Adler-Abramovich, E. Gazit, The physical properties of supramolecular peptide assemblies: from building block association to technological applications. Chem. Soc. Rev. 43(20), 6881–6893 (2014). https://doi.org/10.1039/c4cs00164h
  4. M.G. Kibria, F.A. Chowdhury, S. Zhao, B. AlOtaibi, M.L. Trudeau, H. Guo, Z. Mi, Visible light-driven efficient overall water splitting using p-type metal-nitride nanowire arrays. Nat. Commun. 6, 8 (2015). https://doi.org/10.1038/ncomms7797
  5. L. Lv, Z.X. Yang, K. Chen, C.D. Wang, Y.J. Xiong, 2D layered double hydroxides for oxygen evolution reaction: from fundamental design to application. Adv. Energy Mater. 9(17), 1803358 (2019). https://doi.org/10.1002/aenm.201803358
  6. Y. Zhang, Q. Liao, X.G. Wang, J.N.A. Yao, H.B. Fu, Lattice-matched epitaxial growth of organic heterostructures for integrated optoelectronic application. Angew. Chem. Int. Ed. 56(13), 3616–3620 (2017). https://doi.org/10.1002/anie.201700447
  7. J. Yao, H. Yan, C.M. Lieber, A nanoscale combing technique for the large-scale assembly of highly aligned nanowires. Nat. Nanotechnol. 8(5), 329–335 (2013). https://doi.org/10.1038/nnano.2013.55
  8. M.P. Zhuo, J.J. Wu, X.D. Wang, Y.C. Tao, Y. Yuan, L.S. Liao, Hierarchical self-assembly of organic heterostructure nanowires. Nat. Commun. 10, 9 (2019). https://doi.org/10.1038/s41467-019-11731-7
  9. S. Kawasaki, R. Takahashi, T. Yamamoto, M. Kobayashi, H. Kumigashira et al., Photoelectrochemical water splitting enhanced by self-assembled metal nanopillars embedded in an oxide semiconductor photoelectrode. Nat. Commun. 7, 6 (2016). https://doi.org/10.1038/ncomms11818
  10. S. Guo, Z. Deng, M. Li, B. Jiang, C. Tian, Q. Pan, H. Fu, Phosphorus-doped carbon nitride tubes with a layered micro-nanostructure for enhanced visible-light photocatalytic hydrogen evolution. Angew. Chem. Int. Ed. 55(5), 1830–1834 (2016). https://doi.org/10.1002/ange.201508505
  11. H.L. Sun, Y. Chen, J. Zhao, Y. Liu, Photocontrolled reversible conversion of nanotube and nanoparticle mediated by -cyclodextrin dimers. Angew. Chem. Int. Ed. 54(32), 9376–9380 (2015). https://doi.org/10.1002/anie.201503614
  12. Y. Kim, W. Li, S. Shin, M. Lee, Development of toroidal nanostructures by self-assembly: rational designs and applications. Acc. Chem. Res. 46(12), 2888–2897 (2013). https://doi.org/10.1021/ar400027c
  13. H.C. Sun, J.G. Li, L. Lv, Z.S. Li, X. Ao et al., Engineering hierarchical CoSe/NiFe layered-double-hydroxide nanoarrays as high efficient bifunctional electrocatalyst for overall water splitting. J. Power Sources 425, 138–146 (2019). https://doi.org/10.1016/j.jpowsour.2019.04.014
  14. B. Zhang, F.Z. Wang, C.Q. Zhu, Q. Li, J.N. Song, M.J. Zheng, L. Ma, W.Z. Shen, A facile self-assembly synthesis of hexagonal Zno nanosheet films and their photoelectrochemical properties. Nano-Micro Lett. 8(2), 137–142 (2016). https://doi.org/10.1007/s40820-015-0068-y
  15. S.P. Wang, W. Lin, X.L. Wang, T.Y. Cen, H.J. Xie et al., Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles. Nat. Commun. 10, 12 (2019). https://doi.org/10.1038/s41467-019-09363-y
  16. S. Kunwar, M. Sui, Q. Zhang, P. Pandey, M.Y. Li, J. Lee, Various silver nanostructures on sapphire using plasmon self-assembly and dewetting of thin films. Nano-Micro Lett. 9(2), 17 (2017). https://doi.org/10.1007/s40820-016-0120-6
  17. X. Wang, K. Maeda, A. Thomas, K. Takanabe, G. Xin, J.M. Carlsson, K. Domen, M. Antonietti, A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat. Mater. 8(1), 76–80 (2009). https://doi.org/10.1038/NMAT2317
  18. W. Wu, Z. Ruan, J. Li, Y. Li, Y. Jiang et al., In situ preparation and analysis of bimetal Co-doped mesoporous graphitic carbon nitride with enhanced photocatalytic activity. Nano-Micro Lett. 11, 10 (2019). https://doi.org/10.1007/s40820-018-0236-y
  19. Y.R. Li, T.T. Kong, S.H. Shen, Artificial photosynthesis with polymeric carbon nitride: when meeting metal nanoparticles, single atoms, and molecular complexes. Small 15(32), 1900772 (2019). https://doi.org/10.1002/smll.201900772
  20. K. Xiao, L. Chen, R.T. Chen, T. Heil, S.D.C. Lemus et al., Artificial light-driven ion pump for photoelectric energy conversion. Nat. Commun. 10, 74 (2019). https://doi.org/10.1038/s41467-018-08029-5
  21. S. Cao, J. Low, J. Yu, M. Jaroniec, Polymeric photocatalysts based on graphitic carbon nitride. Adv. Mater. 27(13), 2150–2176 (2015). https://doi.org/10.1002/adma.201500033
  22. Y.J. Fu, C.A. Liu, M.L. Zhang, C. Zhu, H. Li et al., Photocatalytic H2O2 and H2 generation from living chlorella vulgaris and carbon micro particle comodified g-C3N4. Adv. Energy Mater. 8(34), 1802525 (2018). https://doi.org/10.1002/aenm.201802525
  23. B. Li, Y. Si, B.X. Zhou, Q. Fang, Y.Y. Li et al., Doping-induced hydrogen-bond engineering in polymeric carbon nitride to significantly boost the photocatalytic H2 evolution performance. ACS Appl. Mater. Interfaces 11(19), 17341–17349 (2019). https://doi.org/10.1021/acsami.8b22366
  24. S. Yang, Y. Gong, J. Zhang, L. Zhan, L. Ma et al., Exfoliated graphitic carbon nitride nanosheets as efficient catalysts for hydrogen evolution under visible light. Adv. Mater. 25(17), 2452–2456 (2013). https://doi.org/10.1002/adma.201204453
  25. Y. Kang, Y. Yang, L.C. Yin, X. Kang, L. Wang, G. Liu, H.M. Cheng, Selective breaking of hydrogen bonds of layered carbon nitride for visible light photocatalysis. Adv. Mater. 28(30), 6471–6477 (2016). https://doi.org/10.1002/adma.201601567
  26. Z. Lin, X. Wang, Nanostructure engineering and doping of conjugated carbon nitride semiconductors for hydrogen photosynthesis. Angew. Chem. Int. Ed. 25(6), 1779–1782 (2013). https://doi.org/10.1002/anie.201209017
  27. Y. Zhou, L. Zhang, J. Liu, X. Fan, B. Wang et al., Brand new P-doped g-C3N4: enhanced photocatalytic activity for H2 evolution and Rhodamine B degradation under visible light. J. Mater. Chem. A 3(7), 3862–3867 (2015). https://doi.org/10.1039/c4ta05292g
  28. Y. Zhang, T. Mori, J. Ye, M. Antonietti, Phosphorus-doped carbon nitride solid: enhanced electrical conductivity and photocurrent generation. J. Am. Chem. Soc. 132(18), 6294–6295 (2010). https://doi.org/10.1021/ja101749y
  29. R.J. Ran, T.Y. Ma, G. Gao, X. Du, S. Qiao, Porous P-doped graphitic carbon nitride nanosheets for synergistically enhanced visible-light photocatalytic H2 production. Energy Environ. Sci. 8(12), 3708–3717 (2015). https://doi.org/10.1039/c5ee02650d
  30. Q.X. Liu, C.M. Zeng, Z.H. Xie, L.H. Ai, Y.Y. Liu et al., Cobalt@ nitrogen-doped bamboo-structured carbon nanotube to boost photocatalytic hydrogen evolution on carbon nitride. Appl. Catal. B Environ. 254, 443–451 (2019). https://doi.org/10.1016/j.apcatb.2019.04.098
  31. K. Liu, Y.T. Kang, Z.Q. Wang, X. Zhang, 25th anniversary article: reversible and adaptive functional supramolecular materials: “Noncovalent interaction” matters. Adv. Mater. 25(39), 5530–5548 (2013). https://doi.org/10.1002/adma201302015
  32. M. Shalom, S. Inal, C. Fettkenhauer, D. Neher, M. Antonietti, Improving carbon nitride photocatalysis by supramolecular preorganization of monomers. J. Am. Chem. Soc. 135(19), 7118–7121 (2013). https://doi.org/10.1021/ja402521s
  33. G. Ge, X.W. Guo, C.S. Song, Z.K. Zhao, Reconstructing supramolecular aggregates to nitrogen-deficient g-C3N4 bunchy tubes with enhanced photocatalysis for H2 production. ACS Appl. Mater. Interfaces 10(22), 18746–18753 (2018). https://doi.org/10.1021/acsami.8b04227
  34. Z.W. Tong, D. Yang, Y.Y. Sun, Y.H. Nan, Z.Y. Jiang, Tubular g-C3N4 isotype heterojunction: enhanced visible-light photocatalytic activity through cooperative manipulation of oriented electron and hole transfer. Small 12(30), 4093–4101 (2016). https://doi.org/10.1002/smll.201601660
  35. N.A. Wasio, R.C. Quardokus, R.P. Forrest, C.S. Lent, S.A. Corcelli, J.A. Christie, K.W. Henderson, S.A. Kandel, Self-assembly of hydrogen-bonded two-dimensional quasicrystals. Nature 507(7490), 86–89 (2014). https://doi.org/10.1038/nature12993
  36. M. Shalom, M. Guttentag, C. Fettkenhauer, S. Inal, D. Neher, A. Llobet, M. Antonietti, In situ formation of heterojunctions in modified graphitic carbon nitride: synthesis and noble metal free photocatalysis. Chem. Mater. 26(19), 5812–5818 (2014). https://doi.org/10.1021/cm503258z
  37. Y.Y. Li, Y. Si, B.X. Zhou, W.Q. Huang, W.Y. Hu, A.L. Pan, X.X. Fan, G.F. Huang, Strategy to boost catalytic activity of polymeric carbon nitride: synergistic effect of controllable in situ surface engineering and morphology. Nanoscale 11(35), 16393–16405 (2019). https://doi.org/10.1039/c9nr05413h
  38. B.X. Zhou, S.S. Ding, B.J. Zhang, L. Xu, R.S. Chen et al., Dimensional transformation and morphological control of graphitic carbon nitride from water-based supramolecular assembly for photocatalytic hydrogen evolution: from 3D to 2D and 1D nanostructures. Appl. Catal. B Environ. 254, 321–328 (2019). https://doi.org/10.1016/j.apcatb.2019.05.015
  39. Y. Ishida, L. Chabanne, M. Antonietti, M. Shalom, Morphology control and photocatalysis enhancement by the one-pot synthesis of carbon nitride from preorganized hydrogen-bonded supramolecular precursors. Langmuir 30(2), 447–451 (2014). https://doi.org/10.1021/la404101h
  40. L.S. Zhang, N. Ding, M. Hashimoto, K. Iwasaki, N. Chikamori et al., Sodium-doped carbon nitride nanotubes for efficient visible light-driven hydrogen production. Nano Res. 11(4), 2295–2309 (2018). https://doi.org/10.1007/s12274-017-1853-3
  41. Y.T. Gao, F. Hou, S. Hu, B.G. Wu, Y. Wang, H.Q. Zhang, B.J. Jiang, H.G. Fu, Graphene quantum-dot-modified hexagonal tubular carbon nitride for visible-light photocatalytic hydrogen evolution. Chemcatchem 10(6), 1330–1335 (2018). https://doi.org/10.1002/cctc.201701823
  42. B. Liu, L.Q. Ye, R. Wang, J.F. Yang, Y.X. Zhang, R. Guan, L.H. Tian, X.B. Chen, Phosphorus-doped graphitic carbon nitride nanotubes with amino-rich surface for efficient CO2 capture, enhanced photocatalytic activity, and product selectivity. ACS Appl. Mater. Interfaces 10(4), 4001–4009 (2018). https://doi.org/10.1021/acsami.7b17503
  43. G. Kresse, J. Furthmuller, Efficiency of ab initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 6(1), 15–50 (1996). https://doi.org/10.1016/0927-0256(96)00008-0
  44. G. Kresse, J. Furthmuller, Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B Condens. Matter 54(16), 11169–11186 (1996). https://doi.org/10.1103/PhysRevB.54.11169
  45. J.P. Perdew, K. Burke, M. Ernzerhof, Generalized gradient approximation made simple. Phys. Rev. Lett. 77(18), 3865–3868 (1996). https://doi.org/10.1103/PhysRevLett.77.3865
  46. S. Grimme, Semiempirical GGA-type density functional constructed with a long-range dispersion correction. J. Comput. Chem. 27(15), 1787–1799 (2006). https://doi.org/10.1002/jcc.20495
  47. J. Heyd, G.E. Scuseria, M. Ernzerhof, Hybrid functionals based on a screened coulomb potential. J. Chem. Phys. 118(18), 8207–8215 (2003). https://doi.org/10.1063/1.1564060
  48. J. Paier, M. Marsman, K. Hummer, G. Kresse, I.C. Gerber, J.G. Angyan, Screened hybrid density functionals applied to solids. J. Chem. Phys. 124(15), 154709 (2006). https://doi.org/10.1063/1.2187006
  49. Q. Liang, Z. Li, Z.H. Huang, F. Kang, Q.H. Yang, Holey graphitic carbon nitride nanosheets with carbon vacancies for highly improved photocatalytic hydrogen production. Adv. Funct. Mater. 25(44), 6885–6892 (2016). https://doi.org/10.1002/adfm.201503221
  50. Y.F. Li, R.X. Jin, Y. Xing, J.Q. Li, S.Y. Song, X.C. Liu, M. Li, R.C. Jin, Macroscopic foam-like holey ultrathin g-C3N4 nanosheets for drastic improvement of visible-light photocatalytic activity. Adv. Energy Mater. 6(24), 5 (2016). https://doi.org/10.1002/aenm.201601273
  51. X. Ao, W. Zhang, Z.S. Li, J.G. Li, L. Soule et al., Markedly enhanced oxygen reduction activity of single-atom Fe catalysts via integration with Fe nanoclusters. ACS Nano 13(10), 11853–11862 (2019). https://doi.org/10.1021/acsnano.9b05913
  52. Y.C. Bao, K.Z. Chen, AgCl/Ag/g-C3N4 hybrid composites: preparation, visible light-driven photocatalytic activity and mechanism. Nano-Micro Lett. 8(2), 182–192 (2016). https://doi.org/10.1007/s40820-015-0076-y
  53. F. Raziq, Y. Qu, M. Humayun, A. Zada, H.T. Yu, L.Q. Jing, Synthesis of SnO2/B-P codoped g-C3N4 nanocomposites as efficient cocatalyst-free visible-light photocatalysts for CO2 conversion and pollutant degradation. Appl. Catal. B Environ. 201, 486–494 (2017). https://doi.org/10.1016/j.apcatb.2016.08.057
  54. S. Zhang, S. Song, P.C. Gu, R. Ma, D.L. Wei et al., Visible-light-driven activation of persulfate over cyano and hydroxyl group co-modified mesoporous g-C3N4 for boosting bisphenol a degradation. J. Mater. Chem. A 7(10), 5552–5560 (2019). https://doi.org/10.1039/c9ta00339h
  55. J. Zhang, M. Zhang, G. Zhang, X. Wang, Synthesis of carbon nitride semiconductors in sulfur flux for water photoredox catalysis. ACS Catal. 2(2), 940–948 (2012). https://doi.org/10.1021/cs300167b
  56. H. Yu, R. Shi, Y. Zhao, T. Bian, Y. Zhao et al., Alkali-assisted synthesis of nitrogen deficient graphitic carbon nitride with tunable band structures for efficient visible-light-driven hydrogen evolution. Adv. Mater. 29(16), 1605148 (2017). https://doi.org/10.1002/adma.201605148
  57. C.H. Liu, F. Wang, J. Zhang, K. Wang, Y.Y. Qiu, Q. Liang, Z.D. Chen, Efficient photoelectrochemical water splitting by g-C3N4/TiO2 nanotube array heterostructures. Nano-Micro Lett. 10(2), 37 (2018). https://doi.org/10.1007/s40820-018-0192-6
  58. K. Li, W.D. Zhang, Creating graphitic carbon nitride based donor-π-acceptor-π-donor structured catalysts for highly photocatalytic hydrogen evolution. Small 14(12), 1703599 (2018). https://doi.org/10.1002/smll.201703599
  59. Y.P. Zhu, T.Z. Ren, Z.Y. Yuana, Mesoporous phosphorus-doped g-C3N4 nanostructured flowers with superior photocatalytic hydrogen evolution performance. ACS Appl. Mater. Interfaces 7(30), 16850–16856 (2015). https://doi.org/10.1021/acsami.5b04947
  60. S.E. Guo, Y.Q. Tang, Y. Xie, C.G. Tian, Q.M. Feng, W. Zhou, B.J. Jiang, P-doped tubular g-C3N4 with surface carbon defects: universal synthesis and enhanced visible-light photocatalytic hydrogen production. Appl. Catal. B Environ. 218, 664–671 (2017). https://doi.org/10.1016/j.apcatb.2017.07.022
  61. M. Wu, J. Zhang, B.B. He, H.W. Wang, R. Wang, Y.S. Gong, In-situ construction of coral-like porous P-doped g-C3N4 tubes with hybrid 1D/2D architecture and high efficient photocatalytic hydrogen evolution. Appl. Catal. B Environ. 241, 159–166 (2019). https://doi.org/10.1016/j.apcatb.2018.09.037
  62. J. Liu, Y. Liu, N. Liu, Y. Han, X. Zhang et al., Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway. Science 46(23), 970–974 (2015). https://doi.org/10.1126/science.aaa3145
  63. Z.Y. Zhang, J.D. Huang, M.Y. Zhang, L. Yuan, B. Dong, Ultrathin hexagonal SnS2 nanosheets coupled with g-C3N4 nanosheets as 2D/2D heterojunction photocatalysts toward high photocatalytic activity. Appl. Catal. B Environ. 163, 298–305 (2015). https://doi.org/10.1016/j.apcatb.2014.08.013
  64. W. Xing, C. Li, G. Chen, Z. Han, Y. Zhou, Y. Hu, Q. Meng, Incorporating a novel metal-free interlayer into g-C3N4 framework for efficiency enhanced photocatalytic H2 evolution activity. Appl. Catal. B Environ. 203, 65–71 (2017). https://doi.org/10.1016/j.apcatb.2016.09.075
  65. S. Chu, Y. Wang, Y. Guo, J.Y. Feng, C.C. Wang, W.J. Luo, X.X. Fan, Z.G. Zou, Band structure engineering of carbon nitride: in search of a polymer photocatalyst with high photooxidation property. ACS Catal. 3(5), 912–919 (2013). https://doi.org/10.1021/cs4000624
  66. J.G. Li, Y. Gu, H.C. Sun, L. Lv, Z.S. Li et al., Engineering the coupling interface of rhombic dodecahedral NiCoP/C@FeOOH nanocages toward enhanced water oxidation. Nanoscale 11(42), 19959–19968 (2019). https://doi.org/10.1039/c9nr07967j
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