Issue

Vol. 6 No. 4 (2014)

CoFe2O4-Graphene Nanocomposites Synthesized through An Ultrasonic Method with Enhanced Performances as Anode Materials for Li-ion Batteries

https://doi.org/10.1007/s40820-014-0003-7
Yinglin Xiao
School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Xiaomin Li
School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Jiantao Zai
School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Kaixue Wang
School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Yong Gong
School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Bo Li
School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Qianyan Han
School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Xuefeng Qian
School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China

Corresponding Author: Xuefeng Qian

xfqian@sjtu.edu.cn

Nano-Micro Letters, Vol. 6 No. 4 (2014), Article Number: 307-315

Abstract

CoFe2O4-graphene nanosheets (CoFe2O4-GNSs) were synthesized through an ultrasonic method, and their electrochemical performances as Li-ion battery electrode were improved by annealing processes. The nanocomposites obtained at 350 °C maintained a high specific capacity of 1,257 mAh g−1 even after 200 cycles at 0.1 A g−1. Furthermore, the obtained materials also have better rate capability, and it can be maintained to 696, 495, 308, and 254 mAh g−1 at 1, 2, 5, and 10 A g−1, respectively. The enhancements realized in the reversible capacity and cyclic stability can be attributed to the good improvement in the electrical conductivity achieved by annealing at appropriate temperature, and the electrochemical nature of CoFe2O4 and GNSs during discharge–charge processes.

Keywords

Cobalt ferrite Graphene Anode materials Lithium ion battery
Xiao, Yinglin, Xiaomin Li, Jiantao Zai, Kaixue Wang, Yong Gong, Bo Li, Qianyan Han, and Xuefeng Qian. 2014. “CoFe2O4-Graphene Nanocomposites Synthesized through An Ultrasonic Method With Enhanced Performances As Anode Materials for Li-Ion Batteries”. Nano-Micro Letters 6 (4):307-15. https://doi.org/10.1007/s40820-014-0003-7.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. Z. Li, T. Zhao, X. Zhan, D. Gao, Q. Xiao, G. Lei, High capacity three-dimensional ordered macroporous CoFe2O4 as anode material for lithium ion batteries. Electrochim. Acta 55(15), 4594–4598 (2010). doi:10.1016/j.electacta.2010.03.015
  2. Z. Wang, D. Luan, S. Madhavi, Y. Hu, X.W. David Lou, Assembling carbon-coated α-Fe2O3 hollow nanohorns on the CNT backbone for superior lithium storage capability. Energy Enviro. Sci. 5(1), 5252–5256 (2012). doi:10.1039/c1ee02831f
  3. J. Zai, C. Yu, Q. Zou, L. Tao, K. Wang, Q. Han, B. Li, Y. Xiao, X. Qian, R. Qi, Magnetite modified graphene nanosheets with improved rate performance and cyclic stability for Li ion battery anodes. RSC Adv. 2(10), 4397–4403 (2012). doi:10.1039/c2ra20319g
  4. R. Yi, F. Dai, M.L. Gordin, S. Chen, D. Wang, Microsized Si-C composite with interconnected nanoscale building blocks as high-performance anodes for practical application in lithium-ion batteries. Adv. Energy Mater. 3(3), 295–300 (2013). doi:10.1002/aenm.201200857
  5. J. Zai, X. Qian, K. Wang, C. Yu, L. Tao, Y. Xiao, J. Chen, 3D-hierarchical SnS2 micro/nano-structures: controlled synthesis, formation mechanism and lithium ion storage performances. CrystEngComm. 14(4), 1364–1375 (2012). doi:10.1039/c1ce05950e
  6. M.F. Hassan, Z. Guo, Z. Chen, H. Liu, α-Fe2O3 as an anode material with capacity rise and high rate capability for lithium-ion batteries. Mater. Res. Bull. 46(6), 858–864 (2011). doi:10.1016/j.materresbull.2011.02.011
  7. Y. Huang, X.-L. Huang, J.-S. Lian, D. Xu, L.-M. Wang, X.-B. Zhang, Self-assembly of ultrathin porous NiO nanosheets/graphene hierarchical structure for high-capacity and high-rate lithium storage. J. Mater. Chem. 22(7), 2844–2847 (2012). doi:10.1039/c2jm15865e
  8. Y. Zhao, J. Li, Y. Ding, L. Guan, Single-walled carbon nanohorns coated with Fe2O3 as a superior anode material for lithium ion batteries. Chem. Commun. 47(26), 7416–7418 (2011). doi:10.1039/c1cc12171e
  9. Y. Liu, X. Zhao, F. Li, D. Xia, Facile synthesis of MnO/C anode materials for lithium-ion batteries. Electrochim. Acta 56(18), 6448–6452 (2011). doi:10.1016/j.electacta.2011.04.133
  10. J.-G. Kang, Y.-D. Ko, J.-G. Park, D.-W. Kim, Origin of capacity fading in nano-sized Co3O4 electrodes: electrochemical impedance spectroscopy study. Nanoscale Res. Lett. 3(10), 390–394 (2008). doi:10.1007/s11671-008-9176-7
  11. G. Wang, Y. Chen, K. Konstantinov, M. Lindsay, H. Liu, S. Dou, Investigation of cobalt oxides as anode materials for Li-ion batteries. J. Power Sources 109(1), 142–147 (2002). doi:10.1016/S0378-7753(02)00052-6
  12. L. Liu, Y. Li, S. Yuan, M. Ge, M. Ren, C. Sun, Z. Zhou, Nanosheet-based NiO microspheres: controlled solvothermal synthesis and lithium storage performances. J. Phys. Chem. C 114(1), 251–255 (2009). doi:10.1021/jp909014w
  13. I. Issac, M. Scheuermann, S.M. Becker, E.G. Bardají, C. Adelhelm, D. Wang, C. Kübel, S. Indris, Nanocrystalline Ti2/3Sn1/3O2 as anode material for Li-ion batteries. J. Power Sources 196(22), 9689–9695 (2011). doi:10.1016/j.jpowsour.2011.07.046
  14. W. Li, G. Zhang, J. Li, Y. Lai, NiFe2O4-based cermet inert anodes for aluminum electrolysis. JOM 61(5), 39–43 (2009). doi:10.1007/s11837-009-0068-9
  15. L. Tao, J. Zai, K. Wang, H. Zhang, M. Xu, J. Shen, Y. Su, X. Qian, Co3O4 nanorods/graphene nanosheets nanocomposites for lithium ion batteries with improved reversible capacity and cycle stability. J. Power Sources 202(15), 230–235 (2012). doi:10.1016/j.jpowsour.2011.10.131
  16. Y. Ding, Y. Yang, H. Shao, Synthesis and characterization of nanostructured CuFe2O4 anode material for lithium ion battery. Solid State Ionics 217(8), 27–33 (2012). doi:10.1016/j.ssi.2012.04.021
  17. Z. Yuan, F. Huang, J. Sun, Y. Zhou, An amorphous nanosized tin-zinc composite oxide as a high capacity anode material for lithium ion batteries. Chem. Lett. 31(3), 408–409 (2002). doi:10.1246/cl.2002.408
  18. Y. Zhao, J. Li, Y. Ding, L. Guan, Enhancing the lithium storage performance of iron oxide composites through partial substitution with Ni2+ or Co2+. J. Mater. Chem. 21(47), 19101–19105 (2011). doi:10.1039/c1jm13263f
  19. D. Wang, R. Kou, D. Choi, Z. Yang, Z. Nie, J. Li, L.V. Saraf, D. Hu, J. Zhang, G.L. Graff, Ternary self-assembly of ordered metal oxide-graphene nanocomposites for electrochemical energy storage. ACS Nano 4(3), 1587–1595 (2010). doi:10.1021/nn901819n
  20. J. Zhu, Y.K. Sharma, Z. Zeng, X. Zhang, M. Srinivasan, S. Mhaisalkar, H. Zhang, H.H. Hng, Q. Yan, Cobalt oxide nanowall arrays on reduced graphene oxide sheets with controlled phase, grain size, and porosity for Li-ion battery electrodes. J. Phys. Chem. C 115(16), 8400–8406 (2011). doi:10.1021/jp2002113
  21. G. Zhou, D.W. Wang, F. Li, L. Zhang, N. Li, Z.S. Wu, L. Wen, G.Q. Lu, H.M. Cheng, Graphene-wrapped Fe3O4 anode material with improved reversible capacity and cyclic stability for lithium ion batteries. Chem. Mater. 22(18), 5306–5313 (2010). doi:10.1021/cm101532x
  22. Z. Chen, L. Gao, Synthesis and magnetic properties of CoFe2O4 nanoparticles by using PEG as surfactant additive. Mater. Sci. Eng. B 141(1–2), 82–86 (2007). doi:10.1016/j.mseb.2007.06.003
  23. P. Lavela, J. Tirado, CoFe2O4 and NiFe2O4 synthesized by sol–gel procedures for their use as anode materials for Li ion batteries. J. Power Sources 172(1), 379–387 (2007). doi:10.1016/j.jpowsour.2007.07.055
  24. H. Xia, D. Zhu, Y. Fu, X. Wang, CoFe2O4-graphene nanocomposite as a high-capacity anode material for lithium-ion batteries. Electrochim. Acta 83, 166–174 (2012). doi:10.1016/j.electacta.2012.08.027
  25. S. Liu, J. Xie, C. Fang, G. Cao, T. Zhu, X. Zhao, Self-assembly of a CoFe2O4/graphene sandwich by a controllable and general route: towards a high-performance anode for Li-ion batteries. J. Mater. Chem. 22(37), 19738–19743 (2012). doi:10.1039/c2jm34019d
  26. W.T.L. Lim, Z. Zhong, A. Borgna, An effective sonication-assisted reduction approach to synthesize highly dispersed Co nanoparticles on SiO2. Chem. Phys. Lett. 471(1–3), 122–127 (2009). doi:10.1016/j.cplett.2009.02.041
  27. R. Yi, F. Dai, M.L. Gordin, H. Sohn, D. Wang, Influence of silicon nanoscale building blocks size and carbon coating on the performance of micro-sized Si-C composite Li-ion anodes. Adv. Energy Mater. 3(11), 1507–1515 (2013). doi:10.1002/aenm.201300496
  28. L. Tang, Y. Wang, Y. Li, H. Feng, J. Lu, J. Li, Preparation, structure, and electrochemical properties of reduced graphene sheet films. Adv. Funct. Mater. 19(17), 2782–2789 (2009). doi:10.1002/adfm.200900377
  29. H. Wang, C. Zhang, Z. Liu, L. Wang, P. Han, H. Xu, K. Zhang, S. Dong, J. Yao, G. Cui, Nitrogen-doped graphene nanosheets with excellent lithium storage properties. J. Mater. Chem. 21(14), 5430–5434 (2011). doi:10.1039/c1jm00049g
  30. J. Zhu, T. Zhu, X. Zhou, Y. Zhang, X.W. Lou, X. Chen, H. Zhang, H.H. Hng, Q. Yan, Facile synthesis of metal oxide/reduced graphene oxide hybrids with high lithium storage capacity and stable cyclability. Nanoscale 3, 1084–1089 (2011). doi:10.1039/c0nr00744g
  31. J. Liu, Z. Lin, T. Liu, Z. Yin, X. Zhou, S. Chen, L. Xie, F. Boey, H. Zhang, W. Huang, Multilayer stacked low-temperature-reduced graphene oxide films: preparation, characterization, and application in polymer memory devices. Small 6(14), 1536–1542 (2010). doi:10.1002/smll.201000328
  32. S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S.T. Nguyen, R.S. Ruoff, Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45(7), 1558–1565 (2007). doi:10.1016/j.carbon.2007.02.034
  33. C.-M. Chen, J.-Q. Huang, Q. Zhang, W.-Z. Gong, Q.-H. Yang, M.-Z. Wang, Y.-G. Yang, Annealing a graphene oxide film to produce a free standing high conductive graphene film. Carbon 50(2), 659–667 (2012). doi:10.1016/j.carbon.2011.09.022
  34. S. Mao, H. Pu, J. Chen, Graphene oxide and its reduction: modeling and experimental progress. RSC Adv. 2(7), 2643–2662 (2012). doi:10.1039/c2ra00663d
  35. W. Chiu, S. Radiman, R. Abd-Shukor, M. Abdullah, P. Khiew, Tunable coercivity of CoFe2O4 nanoparticles via thermal annealing treatment. J. Alloy. Compd. 459(1–2), 291–297 (2008). doi:10.1016/j.jallcom.2007.04.215
  36. J.M. Kim, W.G. Hong, S.M. Lee, S.J. Chang, Y. Jun, B.H. Kim, H.J. Kim, Energy storage of thermally reduced graphene oxide. Int. J. Hydrog. Energy 39(8), 3799–3804 (2014). doi:10.1016/j.ijhydene.2013.12.144
  37. J.B. Silva, W.D. Brito, N.D. Mohallem, Influence of heat treatment on cobalt ferrite ceramic powders. Mater. Sci. Eng. B 112(2–3), 182–187 (2004). doi:10.1016/j.mseb.2004.05.029
  38. L. Ji, Z. Tan, T.R. Kuykendall, S. Aloni, S. Xun, E. Lin, V. Battaglia, Y. Zhang, Fe3O4 nanoparticle-integrated graphene sheets for high-performance half and full lithium ion cells. Phys. Chem. Chem. Phys. 13(15), 7170–7177 (2011). doi:10.1039/c1cp20455f
  39. Y. Mai, D. Zhang, Y. Qiao, C. Gu, X. Wang, J. Tu, MnO/reduced graphene oxide sheet hybrid as an anode for Li-ion batteries with enhanced lithium storage performance. J. Power Sources 216, 201–207 (2012). doi:10.1016/j.jpowsour.2012.05.084
  40. K. Shu, C. Wang, M. Wang, C. Zhao, G.G. Wallace, Graphene cryogel papers with enhanced mechanical strength for high performance lithium battery anodes. J. Mater. Chem. A 2(5), 1325–1331 (2014). doi:10.1039/c3ta13660d
  41. S. Yin, Y. Zhang, J. Kong, C. Zou, C.M. Li, X. Lu, J. Ma, F.Y.C. Boey, X. Chen, Assembly of graphene sheets into hierarchical structures for high-performance energy storage. ACS Nano 5(5), 3831–3838 (2011). doi:10.1021/nn2001728
  42. F.-W. Yuan, H.-J. Yang, H.-Y. Tuan, Alkanethiol-passivated Ge nanowires as high-performance anode materials for lithium-ion batteries: the role of chemical surface functionalization. ACS Nano 6(11), 9932–9942 (2012). doi:10.1021/nn303519g
  43. H. Zhao, Z. Zheng, K.W. Wong, S. Wang, B. Huang, D. Li, Fabrication and electrochemical performance of nickel ferrite nanoparticles as anode material in lithium ion batteries. Electrochem. Commun. 9(10), 2606–2610 (2007). doi:10.1016/j.elecom.2007.08.007
  44. Z.-S. Wu, W. Ren, L. Wen, L. Gao, J. Zhao, Z. Chen, G. Zhou, F. Li, H.-M. Cheng, Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance. ACS Nano 4(6), 3187–3194 (2010). doi:10.1021/nn100740x
  45. J.S. Chen, X.W. Lou, Anatase TiO2 nanosheet: an ideal host structure for fast and efficient lithium insertion/extraction. Electrochem. Commun. 11(12), 2332–2335 (2009). doi:10.1016/j.elecom.2009.10.024
  46. S. Laruelle, S. Grugeon, P. Poizot, M. Dolle, L. Dupont, J. Tarascon, On the origin of the extra electrochemical capacity displayed by MO/Li cells at low potential. J. Electrochem. Soc. 149(5), A627–A634 (2002). doi:10.1149/1.1467947
  47. T. Wei, F. Wang, J. Yan, J. Cheng, Z. Fan, H. Song, Microspheres composed of multilayer graphene as anode material for lithium-ion batteries. J. Electroanal. Chem. 653(1–2), 45–49 (2011). doi:10.1016/j.jelechem.2011.01.010
  48. H. Liu, G. Wang, J. Liu, S. Qiao, H. Ahn, Highly ordered mesoporous NiO anode material for lithium ion batteries with an excellent electrochemical performance. J. Mater. Chem. 21(9), 3046–3052 (2011). doi:10.1039/c0jm03132a
  49. S. Yang, H. Song, X. Chen, Electrochemical performance of expanded mesocarbon microbeads as anode material for lithium-ion batteries. Electrochem. Commun. 8(1), 137–142 (2006). doi:10.1016/j.elecom.2005.10.035
  50. Y. Xiao, J. Zai, L. Tao, B. Li, Q. Han, C. Yu, X. Qian, MnFe2O4-graphene nanocomposites with enhanced performances as anode materials for Li-ion batteries. Phys. Chem. Chem. Phys. 15(11), 3939–3945 (2013). doi:10.1039/c3cp50220a
  51. J. Zai, K. Wang, Y. Su, X. Qian, J. Chen, High stability and superior rate capability of three-dimensional hierarchical SnS2 microspheres as anode material in lithium ion batteries. J. Power Sources 196(7), 3650–3654 (2011). doi:10.1016/j.jpowsour.2010.12.057
Read More
Author biographies are not available.
Download this PDF file
PDF SUPPLEMENTARY MATERIAL
Statistic
Read Counter : 2733 Download : 2073

Most read articles by the same author(s)