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Vol. 12 (2020)

Confining TiO2 Nanotubes in PECVD-Enabled Graphene Capsules Toward Ultrafast K-Ion Storage: In Situ TEM/XRD Study and DFT Analysis

https://doi.org/10.1007/s40820-020-00460-y
Jingsheng Cai
College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou 215006, Jiangsu, People’s Republic of China
Ran Cai
SEU‑FEI Nano‑Pico Center, Key Laboratory of MEMS of Ministry of Education, Southeast University, Nanjing 210096, People’s Republic of China
Zhongti Sun
College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou 215006, Jiangsu, People’s Republic of China
Xiangguo Wang
College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou 215006, Jiangsu, People’s Republic of China
Nan Wei
College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou 215006, Jiangsu, People’s Republic of China
Feng Xu
SEU‑FEI Nano‑Pico Center, Key Laboratory of MEMS of Ministry of Education, Southeast University, Nanjing 210096, People’s Republic of China
Yuanlong Shao
College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou 215006, Jiangsu, People’s Republic of China
Peng Gao
Beijing Graphene Institute (BGI), Beijing 100095, People’s Republic of China
Shixue Dou
Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong, NSW 2522, Australia
Jingyu Sun
College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou 215006, Jiangsu, People’s Republic of China

Corresponding Author: Jingyu Sun

sunjy86@suda.edu.cn

Nano-Micro Letters, Vol. 12 (2020), Article Number: 123

Abstract

Titanium dioxide (TiO2) has gained burgeoning attention for potassium-ion storage because of its large theoretical capacity, wide availability, and environmental benignity. Nevertheless, the inherently poor conductivity gives rise to its sluggish reaction kinetics and inferior rate capability. Here, we report the direct graphene growth over TiO2 nanotubes by virtue of chemical vapor deposition. Such conformal graphene coatings effectively enhance the conductive environment and well accommodate the volume change of TiO2 upon potassiation/depotassiation. When paired with an activated carbon cathode, the graphene-armored TiO2 nanotubes allow the potassium-ion hybrid capacitor full cells to harvest an energy/power density of 81.2 Wh kg−1/3746.6 W kg−1. We further employ in situ transmission electron microscopy and operando X-ray diffraction to probe the potassium-ion storage behavior. This work offers a viable and versatile solution to the anode design and in situ probing of potassium storage technologies that is readily promising for practical applications.


Highlights:


1 G-TiO2 was fabricated via direct CVD route by growing few-layered graphene capsules over TiO2 nanotubes.
2 K-ion hybrid capacitors based on the G-TiO2 anode and AC cathode synergized high energy and high power density.

Keywords

TiO2 Potassium storage In situ TEM Plasma-enhanced CVD Graphene
Cai, Jingsheng, Ran Cai, Zhongti Sun, Xiangguo Wang, Nan Wei, Feng Xu, Yuanlong Shao, Peng Gao, Shixue Dou, and Jingyu Sun. 2020. “Confining TiO2 Nanotubes in PECVD-Enabled Graphene Capsules Toward Ultrafast K-Ion Storage: In Situ TEM/XRD Study and DFT Analysis”. Nano-Micro Letters 12 (June):123. https://doi.org/10.1007/s40820-020-00460-y.
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References
  1. Y.M. Chiang, Building a better battery. Science 330(6010), 1485–1486 (2010). https://doi.org/10.1126/science.1198591
  2. N. Kim, S. Chae, J. Ma, M. Ko, J. Cho, Fast-charging high-energy lithium-ion batteries via implantation of amorphous silicon nanolayer in edge-plane activated graphite anodes. Nat. Commun. 8, 812 (2017). https://doi.org/10.1038/s41467-017-00973-y
  3. C.Y. Zhao, Y. Cai, K.L. Yin, H.Z. Li, D. Shen et al., Carbon-bonded, oxygen-deficient TiO2 nanotubes with hybridized phases for superior Na-ion storage. Chem. Eng. J. 350(15), 201–208 (2018). https://doi.org/10.1016/j.cej.2018.05.194
  4. J.T. Xu, Y.H. Dou, Z.X. Wei, J.M. Ma, Y.H. Deng, Y.T. Li, H.K. Liu, S.X. Dou, Recent progress in graphite intercalation compounds for rechargeable metal (Li, Na, K, Al)-ion batteries. Adv. Sci. 4(10), 1700146 (2017). https://doi.org/10.1002/advs.201700146
  5. X. Zhao, F.Y. Gong, Y.D. Zhao, B. Huang, D. Qian, H.E. Wang, W.H. Zhang, Z.J. Yang, Encapsulating NiS nanocrystal into nitrogen-doped carbon framework for high performance sodium/potassium-ion storage. Chem. Eng. J. 392(15), 123675 (2020). https://doi.org/10.1016/j.cej.2019.123675
  6. Z.L. Jian, W. Luo, X.L. Ji, Carbon electrodes for K-ion batteries. J. Am. Chem. Soc. 137(36), 11566–11567 (2015). https://doi.org/10.1021/jacs.5b06809
  7. B.J. Yang, J.T. Chen, L.Y. Liu, P.J. Ma, B. Liu, J.W. Lang, Y. Tang, X.B. Yan, 3D nitrogen-doped framework carbon for high-performance potassium ion hybrid capacitor. Energy Storage Mater. 23, 522–529 (2019). https://doi.org/10.1016/j.ensm.2019.04.008
  8. J.L. Yang, X. Xiao, W.B. Gong, L. Zhao, G.H. Li et al., Size-independent fast ion intercalation in two-dimensional titania nanosheets for alkali-metal-ion batteries. Angew. Chem. Int. Ed. 58(26), 8740–8745 (2019). https://doi.org/10.1002/anie.201902478
  9. J.F. Ni, S.D. Fu, Y.F. Yuan, L. Ma, Y. Jiang, L. Li, J. Lu, Boosting sodium storage in TiO2 nanotube arrays through surface phosphorylation. Adv. Mater. 30(6), 1704337 (2018). https://doi.org/10.1002/adma.201704337
  10. Z.Y. Le, F. Liu, P. Nie, X.R. Li, X.Y. Liu et al., Pseudocapacitive sodium storage in mesoporous single-crystal-like TiO2-graphene nanocomposite enables high-performance sodium-ion capacitors. ACS Nano 11(3), 2952–2960 (2017). https://doi.org/10.1021/acsnano.6b08332
  11. N.N. Wang, C.X. Chu, X. Xu, Y. Du, J. Yang, Z.C. Bai, S.X. Dou, Comprehensive new insights and perspectives into Ti-based anodes for next-generation alkaline metal (Na+, K+) ion batteries. Adv. Energy Mater. 8(27), 1801888 (2018). https://doi.org/10.1002/aenm.201801888
  12. B. Chen, Y.H. Meng, F.X. Xie, F. He, C.N. He, K. Davey, N.Q. Zhao, S.Z. Qiao, 1D sub-nanotubes with anatase/bronze TiO2 nanocrystal wall for high-rate and long-life sodium-ion batteries. Adv. Mater. 30(46), 1804116 (2018). https://doi.org/10.1002/adma.201804116
  13. Y.P. Li, C.H. Yang, F.H. Zheng, Q.C. Pan, Y.Z. Liu et al., Design of TiO2eC hierarchical tubular heterostructures for high performance potassium ion batteries. Nano Energy 59, 582–590 (2019). https://doi.org/10.1016/j.nanoen.2019.03.002
  14. Y.X. Tang, Y.Y. Zhang, J.Y. Deng, J.Q. Wei, H.L. Tam et al., Mechanical force-driven growth of elongated bending TiO2-based nanotubular materials for ultrafast rechargeable lithium ion batteries. Adv. Mater. 26(35), 6111–6118 (2014). https://doi.org/10.1002/adma.201402000
  15. X.G. Wang, Q.C. Li, L. Zhang, Z.L. Hu, L.H. Yu et al., Caging Nb2O5 nanowires in PECVD-derived graphene capsules toward bendable sodium-ion hybrid supercapacitors. Adv. Mater. 30(26), 1800963 (2018). https://doi.org/10.1002/adma.201800963
  16. H. Kim, J.C. Kim, M. Bianchini, D.H. Seo, J.R. Garcia, G. Ceder, Recent progress and perspective in electrode materials for K-ion batteries. Adv. Energy Mater. 8(9), 1702384 (2018). https://doi.org/10.1002/aenm.201702384
  17. G. Kresse, J. Furthmüller, Efficiency of ab initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 6(1), 15–50 (1996). https://doi.org/10.1016/0927-0256(96)00008-0
  18. P.E. Blöchl, Projector augmented-wave method. Phys. Rev. B 50(24), 17953–17979 (1994). https://doi.org/10.1103/PhysRevB.50.17953
  19. J.P. Perdew, K. Burke, M. Ernzerhof, Generalized gradient approximation made simple. Phys. Rev. Lett. 77(18–28), 3865–3868 (1996). https://doi.org/10.1103/PhysRevLett.77.3865
  20. S. Grimme, Semiempirical GGA-type density functional constructed with a long-range dispersion correction. J. Comput. Chem. 27(15), 1787–1799 (2006). https://doi.org/10.1002/jcc.20495
  21. L. Ferrighi, M. Datteo, G. Fazio, C.D. Valentin, Catalysis under cover: enhanced reactivity at the interface between (doped) graphene and anatase TiO2. J. Am. Chem. Soc. 138(23), 7365–7376 (2016). https://doi.org/10.1021/jacs.6b02990
  22. Y.X. Tang, Y.Y. Zhang, J.Y. Deng, D.P. Qi, W.R. Leow et al., Unravelling the correlation between the aspect ratio of nanotubular structures and their electrochemical performance to achieve high-rate and long-life lithium-ion batteries. Angew. Chem. Int. Ed. 53(49), 13488–13492 (2014). https://doi.org/10.1002/anie.201406719
  23. J.L. Li, W. Qin, J.P. Xie, H. Lei, Y.Q. Zhu et al., Sulphur-doped reduced graphene oxide sponges as high-performance free-standing anodes for K-ion storage. Nano Energy 53, 415–424 (2018). https://doi.org/10.1016/j.nanoen.2018.08.075
  24. H. Ren, R.B. Yu, J. Qi, L.J. Zhang, Q. Jin, D. Wang, Hollow multishelled heterostructured anatase/TiO2(B) with superior rate capability and cycling performance. Adv. Mater. 31(10), 1805754 (2019). https://doi.org/10.1002/adma.201805754
  25. J.S. Cai, J.Y. Huang, M.Z. Ge, J. Iocozzia, Z.Q. Lin, K.Q. Zhang, Y.K. Lai, Immobilization of Pt nanoparticles via rapid and reusable electropolymerization of dopamine on TiO2 nanotube arrays for reversible SERS substrates and nonenzymatic glucose sensors. Small 13(19), 1604240 (2017). https://doi.org/10.1002/smll.201604240
  26. J.Y. Sun, Y.B. Chen, M.K. Priydarshi, T. Gao, X.J. Song, Y.F. Zhang, Z.F. Liu, Graphene glass from direct CVD routes: production and applications. Adv. Mater. 28(46), 10333 (2016). https://doi.org/10.1002/adma.201602247
  27. J.Y. Sun, T. Gao, X.J. Song, Y.F. Zhao, Y.W. Lin et al., Direct growth of high-quality graphene on high-κ dielectric SrTiO3 substrates. J. Am. Chem. Soc. 136(18), 6574–6577 (2014). https://doi.org/10.1021/ja5022602
  28. Y.K. Wang, R.F. Zhang, J. Chen, H. Wu, S.Y. Lu et al., Enhancing catalytic activity of titanium oxide in lithium-sulfur batteries by band engineering. Adv. Energy Mater. 9(24), 1900953 (2019). https://doi.org/10.1002/aenm.201900953
  29. T.Y. Lei, Y.M. Xie, X.F. Wang, S.Y. Miao, J. Xiong, C.L. Yan, TiO2 feather duster as effective polysulfides restrictor for enhanced electrochemical kinetics in lithium-sulfur batteries. Small 13(37), 1701013 (2017). https://doi.org/10.1002/smll.201701013
  30. Y. Cai, H.-E. Wang, X. Zhao, F. Huang, C. Wang et al., Walnut-like porous core/shell TiO2 with hybridized phases enabling fast and stable lithium storage. ACS Appl. Mater. Interfaces 9(12), 10652–10663 (2017). https://doi.org/10.1021/acsami.6b16498
  31. H.-E. Wang, K.L. Yin, N. Qin, X. Zhao, F.-J. Xia et al., Oxygen-deficient titanium dioxide as a functional host for lithium–sulfur batteries. J. Mater. Chem. A 7, 10346–10353 (2019). https://doi.org/10.1039/C9TA01598A
  32. F. Giordano, A. Abate, J.P.C. Baena, M. Saliba, T. Matsui et al., Enhanced electronic properties in mesoporous TiO2 via lithium doping for high-efficiency perovskite solar cells. Nat. Commun. 7, 10379 (2016). https://doi.org/10.1038/ncomms10379
  33. J. Zheng, Y. Yang, X.L. Fan, G.B. Ji, X. Ji et al., Extremely stable antimony-carbon composite anodes for potassium-ion batteries. Energy Environ. Sci. 12, 615–623 (2019). https://doi.org/10.1039/C8EE02836B
  34. J.Y. Shin, J.H. Joo, D. Samuelis, J. Maier, Oxygen-deficient TiO2-δ nanoparticles via hydrogen reduction for high rate capability lithium batteries. Chem. Mater. 24(3), 543–551 (2012). https://doi.org/10.1021/cm2031009
  35. P.H. Li, W. Wang, S. Gong, F. Lv, H.X. Huang et al., Hydrogenated Na2Ti3O7 epitaxially grown on flexible N-doped carbon sponge for potassium-ion batteries. ACS Appl. Mater. Interfaces 10(44), 37974–37980 (2018). https://doi.org/10.1021/acsami.8b11354
  36. J. Han, M.W. Xu, Y.B. Niu, G.N. Li, M.Q. Wang, Y. Zhang, M. Jia, C.M. Li, Exploration of K2Ti8O17 as an anode material for potassium-ion batteries. Chem. Commun. 52, 11274–11276 (2016). https://doi.org/10.1039/C6CC05102B
  37. B.B. Tian, W. Tang, K. Leng, Z.X. Chen, S.J.R. Tan et al., Phase transformations in TiS2 during K intercalation. ACS Energy Lett. 2(8), 1835–1840 (2017). https://doi.org/10.1021/acsenergylett.7b00529
  38. P.C. Lian, Y.F. Dong, Z.S. Wu, S.H. Zheng, X.H. Wang et al., Alkalized Ti3C2 MXene nanoribbons with expanded interlayer spacing for high-capacity sodium and potassium ion batteries. Nano Energy 40, 1–8 (2017). https://doi.org/10.1016/j.nanoen.2017.08.002
  39. Y.F. Dong, Z.S. Wu, S.H. Zheng, X.H. Wang, J.Q. Qin, S. Wang, X.Y. Shi, X.H. Bao, Ti3C2 MXene-derived sodium/potassium titanate nanoribbons for high-performance sodium/potassium ion batteries with enhanced capacities. ACS Nano 11(15), 4792–4800 (2017). https://doi.org/10.1021/acsnano.7b01165
  40. G. Fang, Z. Wu, J. Zhou, C. Zhu, X. Cao et al., Observation of pseudocapacitive effect and fast ion diffusion in bimetallic sulfides as an advanced sodium-ion battery anode. Adv. Energy Mater. 8(19), 1703155 (2018). https://doi.org/10.1002/aenm.201703155
  41. X.Y. Tao, J.G. Wang, C. Liu, H.T. Wang, H.B. Yao et al., Balancing surface adsorption and diffusion of lithium-polysulfides on nonconductive oxides for lithium-sulfur battery design. Nat. Commun. 7, 11203 (2016). https://doi.org/10.1038/ncomms11203
  42. J. Sun, H.W. Lee, M. Pasta, H.T. Yuan, G.Y. Zheng, Y.M. Sun, Y.Z. Li, Y. Cui, A phosphorene-graphene hybrid material as a high-capacity anode for sodium-ion batteries. Nat. Nanotechnol. 10, 980–985 (2015). https://doi.org/10.1038/nnano.2015.194
  43. Q.M. Su, G.H. Du, J. Zhang, Y.J. Zhong, B.S. Xu, Y.H. Yang, S.M. Neupane, K. Kadel, W.Z. Li, Visualizing individual nitrogen dopants in monolayer graphene. Science 333(6045), 999–1003 (2011). https://doi.org/10.1126/science.1208759
  44. M.T. Xia, T.T. Liu, N. Peng, R.T. Zheng, X. Cheng, H.J. Zhu, H.X. Yu, M. Shui, J. Shu, Lab-scale in situ X-ray diffraction technique for different battery systems: designs, applications, and perspectives. Small Methods 3(7), 1900119 (2019). https://doi.org/10.1002/smtd.201900119
  45. H. Wei, E.F. Rodriguez, A.F. Hollenkamp, A.I. Bhatt, D.H. Chen, R.A. Caruso, High reversible pseudocapacity in mesoporous yolk-shell anatase TiO2/TiO2(B) microspheres used as anodes for Li-ion batteries. Adv. Funct. Mater. 27(46), 1703270 (2017). https://doi.org/10.1002/adfm.201703270
  46. V. Augustyn, J. Come, M.A. Lowe, J.W. Kim, P.L. Taberna, S.H. Tolbert, H.D. Abruña, P. Simon, B. Dunn, High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance. Nat. Mater. 12, 518–522 (2013). https://doi.org/10.1038/nmat3601
  47. Z.Y. Zhang, M.L. Li, Y. Gao, Z.X. Wei, M.N. Zhang et al., Fast potassium storage in hierarchical Ca0.5Ti2(PO4)3@C microspheres enabling high-performance potassium-ion capacitors. Adv. Funct. Mater. 28(36), 1802684 (2018). https://doi.org/10.1002/adfm.201802684
  48. J. Wang, J. Polleux, J. Lim, B. Dunn, Pseudocapacitive contributions to electrochemical energy storage in TiO2 (anatase) nanoparticles. J. Phys. Chem. C 111(40), 14925–14931 (2007). https://doi.org/10.1021/jp074464w
  49. J.T. Chen, B.J. Yang, H.X. Li, P.J. Ma, J.W. Lang, X.B. Yan, Candle soot: onion-like carbon, an advanced anode material for a potassium-ion hybrid capacitor. J. Mater. Chem. A 7, 9247–9252 (2019). https://doi.org/10.1039/C9TA01653H
  50. J.Y. Hwang, S.T. Myung, Y.K. Sun, Recent progress in rechargeable potassium batteries. Adv. Funct. Mater. 28(43), 1802938 (2018). https://doi.org/10.1002/adfm.201802938
  51. A. Comte, Y. Reynier, C. Vincens, C. Leys, P. Azaïs, First prototypes of hybrid potassium-ion capacitor (KIC): an innovative, cost-effective energy storage technology for transportation applications. J. Power Sour. 363(30), 34–43 (2017). https://doi.org/10.1016/j.jpowsour.2017.07.005
  52. Z.Q. Xu, M.Q. Wu, Z. Chen, C. Chen, J. Yang, T.T. Feng, E. Paek, D. Mitlin, Direct structure-performance comparison of all-carbon potassium and sodium ion capacitors. Adv. Sci. 6(12), 1802272 (2019). https://doi.org/10.1002/advs.201802272
  53. L. Fan, K. Lin, J. Wang, R. Ma, B. Lu, A nonaqueous potassium-based battery-supercapacitor hybrid device. Adv. Mater. 30(20), 1800804 (2018). https://doi.org/10.1002/adma.201800804
  54. J.T. Chen, B.J. Yang, H.J. Hou, H.X. Li, L. Liu, L. Zhang, X.B. Yan, Potassium-ion batteries: disordered, large interlayer spacing, and oxygen-rich carbon nanosheets for potassium ion hybrid capacitor. Adv. Energy Mater. 9(19), 1803894 (2019). https://doi.org/10.1002/aenm.201970069
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